Biochar Storage in the Built Environment

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Biochar Storage in the Built Environment v1.2 — Isometric
[G-G275-0, Conditional: Where an analytical method other than those in Table 2 is used, projects must justify its equivalence.]

Please note that this is not an exhaustive list of analytical methods for each property. If Project Proponents wish to use an alternative, appropriate method of analysis, they may justify its use in the PDD.

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Table 2: Requirements for physical characterization of biochar

Property

Threshold

Analytical Method

Description

Monitoring Frequency

Recommended or required?

Total Carbon Content

Standard Test Methods for Determination of Carbon, Hydrogen and Nitrogen in Analysis Samples of Coal and Carbon in Analysis Samples of Coal and Coke ASTM D5373 or Standard Test Method for Determination of Carbon, Hydrogen and Nitrogen in Analysis of Solid Biofuels EN ISO 16948:2015

The carbon content of applied biochar is necessary for the quantification of Corg and thus CO2eCO2e stored, in accordance with Section 7.0 Quantification of CO₂e Stored. See the Biochar Production and Storage Protocol for carbon content sampling guidance.

Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch.

Required

Inorganic Carbon Content (C[math: C_{inorg}])

Standard Test Method for Rapid Determination of Carbonate Content of Soils ASTM D4373-02 or Testing of Solid Fuels - Determination of the Carbonate Carbon Dioxide Content DIN 51726:2004-06

Measurement of inorganic carbon in biochar is required to accurately differentiate Corg from total carbon content, which may include both inorganic and organic forms. Only Corg is credited forcertified under this Protocol and Module.

Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch.

Required

mbiochar[math: mbiochar]

Direct mass measurement with calibrated weigh scales

The carbon content of applied biochar is necessary for the quantification of CO2e stored, in accordance with Section 7.0. See the Biochar Production and Storage Protocol for carbon content sampling guidance.

Measure every storage batch

Required

Moisture Content

Standard Test Methods for Determination of Moisture Content in Analysis Samples of Wood Charcoal ASTM D1762-84 or Standard Test Method for Determination of Moisture Content in Analysis of Chemical and Physical Tests of Soil Improvers BS EN 13040:2007

The moisture content of applied biochar is necessary for the quantification of CO2e stored, in accordance with the Biochar Production and Storage Protocol. Carbon content can be reported on a dry basis to account for differences in total biochar mass.

Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch

Required

Random Reflectance ([math: R₀])

> 2%101,342

White-light microscopy, eg ISO 7404-5:2009

Random reflectance is an indicator of aromaticity, aromatic ring unit size and condensation. A R₀ value greater than 2% has been proposed as a benchmark for quantifying the permanent pool of carbon in a biochar. The R₀ frequency distribution histogram can be used to decide what fraction of biochar above this benchmark can be classified as chemically inert 81.

Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch

Required

Reactive Organic Carbon and Residual Organic Carbon (C[math: C_{non-reactive}])

Thermogravimetric analysis e.g., Hawk, Rock-Eval® or equivalent. The sample is subjected to re-pyrolysis using a standardized heating procedure: it is first held isothermally at 300  °C, then heated at a rate of 25  °C per minute until reaching 650  °C. During this stage, the reactive organic carbon is volatilized and quantified. The remaining material, referred to as “residual organic carbon,” is subsequently measured by combustion at temperatures up to 850  °C.

Measurement of reactive organic carbon in biochar is important because this fraction represents the more labile, easily degradable component of organic carbon. Elevated levels of ROC can reduce biochar’s long-term carbon stability, as it is more susceptible to microbial decomposition and mineralization in soil. Random reflectance values are subsequently only applied to the residual, stable fraction of biochar.

Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch

Required

Ash Content

Standard Test Method for the Determination of Ash Content in Solid Biofuels ISO 18122:2022

Ash is the inorganic portion of biochar that will not volatilize even if combusted

Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 1 samples per storage batch

Required

Polycyclic Aromatic Hydrocarbons PAHs, sum of USEPA 16

Gas Chromatography coupled with Mass Spectrometry (GC-MS) and/or High Performance Liquid Chromatography analysis eg ISO 13859:2014 or BS EN 17503:2022

Polycyclic aromatic hydrocarbons are organic molecules with fused aromatic rings that can be formed during the pyrolysis process and retained in the biochar. They are chemically stable with a high sorption capacity, known carcinogens and are persistent pollutants that can travel in the environment chain.

Measure at project validation unless feedstock, reactor or process parameters change. Minimum number of 1 sample

Required

Heavy metals including As, Cr, Cd, Co, Cu, Hg, Ni, Pb, Sb, Zn, V

Elements As, Cd, Cr, Cu, Ni, Pb, Zn refer to EN ISO 17294-2 ICP - MS standard test method for determination of selected elements. Element Hg refer to ISO 16772:2004 standard test method for the determination of Mercury using cold - vapor atomic absorption spectrometry. Elements Sb, Co, V refer to EN 15411:2011 standard test method for the determination of trace elements

Concentration of heavy metals in biochar is dependent on the feedstock and the process used3538. Specific heavy metals have adverse effects and are selected for monitoring3639. High concentrations of heavy metals may result in bioaccumulation in biotic systems and increase toxicity in soils and the environment3740.

Measure at project validation unless feedstock, reactor or process parameters change. Minimum number of 1 sample

Required

7.0 Quantification of CO2eStorede Stored

7.1 Summary

This section details the calculation of net CO2 storage in biochar-amended built materials. The monitoring requirements are describedset in detailout in Section 8.0 Monitoring Requirements.

Accurate quantification of net CO2 stored requires a robust quantification of associated projectProject emissions within the project boundary. In the context of this Module, a Project refers to the point of CO2 capture and the point of CO2 storage. This Module defines the point of CO2 storage as the point of incorporation of biochar into a built material. Note that thisThis Module applies only applies to biochar that is considereddurable for 200 years.

This horizon is shorter than the Isometric 1,000-year default and is specific to bebiochar durablein forbuilt materials. Over 1,000 years.

[R-KPDH-0, Projectsthe must provide detailed descriptionsfate of projectthe boundariesbiochar through demolition, recycling, and end-of-life reprocessing is neither guaranteed nor observable for allthis Creditingpathway, activitiesand, for cementitious materials, encapsulation in the high-pH cement pore solution may leave the biochar more vulnerable to loss once the host material is later broken up.] The 200-year horizon reflects approximately the service life of the asset plus its first reuse, a period over which fate is documented rather than extrapolated. It is not a finding that the certified carbon degrades after 200 years, nor a claim that built materials are less durable in general.

Projects are required to provide detailed descriptions of projectProject boundaries for all Creditingactivities activitiesassociated with certificate issuance. Project boundaries must include all areas where removal mechanisms/ and processes may occur, removed carbon storage locations/ and forms, and potential reversal/ and loss pathways.

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7.2 Quantification of CO2eRemoval

The quantity of net CO2 removal for each Reporting Period,RP, can be calculated as follows:

[math: CO_2e_{Removal,\ RP} = CO_2e_{Stored,\ RP} - CO_2e_{Counterfactual,\ RP} - CO_2e_{Emissions,\ RP}]

(Equation 2)

Where:

Removal

7.2.1 Calculation of CO2eStored

[math: CO_CO_2e_{2estored,\text{Stored, RP}} = C_{\text{Biochar}biochar} \timescdot m_{\text{Biochar}biochar} \timescdot F_{\text{Durabledurable, Material}material} \timescdot \frac{44.01}{12.01}]

(Equation 32)

Where:

7.2.1.1 Calculation of Organic Carbon Content

This Module only Credits forcertifies the durably stored organic carbon fraction of biochar, which is used to calculate [math: CO_2e_CO_2​e_{StoredRemoval,RP​}]. While biochar associated inorganic carbon generally makes up a small fraction of total biochar carbon. However, the fate of biochar-associated inorganic carbon is much less predictable. Thus, [math: C_{Biocharbiochar}] is calculated using the following equation:

[math: C_{\text{biochar}} = \text{Total Carbon Content} - C_{\text{inorg}}]

(Equation 43)

Where:

Please refer to Section 8.3.1 of the Biochar Production and Storage Protocol for full guidelines on number of samples required for the measurement of biochar carbon content, [math: C_{biochar}].

7.2.1.2 Measurement of Mass of Biochar Incorporated

SeePlease refer to theSection relevant section8.4 of the Biochar Production and Storage Protocol for full guidelines on measurement of mass of biochar buriedapplied, [math: m_{Biocharbiochar}].

7.2.1.3 Calculation of FDurable[math: F_{durable, Materialmaterial}]

[math: F_{Durable, Materialdurable}]  is calculatedthe fraction of the incorporated biochar certified as durably stored over the 200-year horizon. This Module certifies the inertinite (recalcitrant) fraction of the biochar only, quantified by random reflectance and thermogravimetric analysis ([math: F_{durable}]).

[math: F_{Durabledurable, Materialmaterial} = F_{Inertinite}(1 +- [1-(3U) \timescdot F_{Reversal})] F_{Labiledurable}]

(Equation 54)

Where:

7.2.1.3.1 Calculation of [math: F_{Inertinitedurable}]

The quantificationdurable frameworkfraction is quantified by the random-reflectance inertinite method, following Sanei et al. (2024)1 for determining the [math: CO_2e_{Stored}R_0]inertinite forbenchmark, 1000-year durability is based on the quantification approach set outrefined by Sanei et al,. (20242025)8112 Thistto approachaccount quantifiesfor biochar ononly the randomrecalcitrant reflectancefraction, value ofwith the biochar,reactive comparedfraction todiscounted inertinitevia asthermogravimetric aanalysis. proxyThe only difference from that Module is the horizon label (200 years for geologicallybuilt stable carbon. Using petrographic analysis, Sanei et al., (2024materials)8 identified that biochars with a mean random reflectance (R₀ ≥ 2%) exhibit structural characteristics equivalent to inertinite macerals in fossil coals and chars,the whichdownstream arereversal knowndiscount to[math: persistU] over(Equation geological timescales4).

[R-7B96-0, Projects must report a set of at least 500 measurements of R0 calculated at the maceral level for each sample of their biochar.]

As outlined in Section 6.0 of this Module, Project Proponents must report a set of at least 500 measurements of [math: R_0]R0, calculated at the maceral-level, for eachat sampleleast three replicate samples of their biochar. Batches that adopt this measurement approach can be credited, for the fractionpercentage of their biochar which passes the 2% [math: R_0]R0 benchmark, as outlined in Sanei et al. (2024)81 . The histogram of the [math: R_0]R0 values must be submitted at the point of project verification for this Crediting option. This method was further updated in Sanei et al., (in submission2025)382 to refine the methodology to only account for the recalcitrant fraction of biochar (discounting the reactive fraction, determined by thermogravimetric analysis).

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To ensure a conservative  approach when Creditingissuing certificates against biochar durability, we account for uncertainty in both [math:the R_0]fraction measurement,of biochar passing the 2% R₀ benchmark and the proportion of carbon that is non-reactive. Specifically, for each replicate sample we determine the credited durable fraction ([math:of F_{Durable}])R₀ measurements that meet or exceed the 2% benchmark. The certified inertinite fraction is calculated using the mean valuesof forthese eachfractions parameteracross all samples analyzed, reduced by one standard deviation of the fractions (Equation 5). This methodis applied to the non-reactive carbon fraction, itself reduced by one standard deviation (Equation 6), to give the durable fraction of the biochar (Equation 7). This ensures that the durability estimate reflects a lower-bound confidence level, mitigating the risk of overestimating long-term carbon storage.

As such, [math: F_{Durabledurable}] is calculated through:

Calculating the sample standard deviation of [math: R_0] quantifying the typical deviation of individual [math: R_0] measurements from their mean, which is used to account for uncertainty and conservatively adjust the estimated durable fraction of biochar carbon, as:

[math: F_{\text{inertinite}} = \left( \overlines_{R_0} - = \sqrt{ \frac{1}{n_{R_0}-1}  \sum_{i=1}^{n_{R_0}} \left ( R_{0,i} - \overlinebar{R_0} \right)^2 } ]

(Equation 5)

Where:

Calculating the sample standard deviation of [math: C_{non-reactive}] quantifying the typical deviation of individual [math: C_{non-reactive}] measurements from their mean, which is used to account for uncertainty and conservatively adjust the estimated durable fraction of biochar carbon, as:

[math: s_{C_{\text{non-reactive}}} - = \sqrt{ \frac{1}{n_C n_{C_{non- reactive}}-1}  \sum_{i=1}^{n_Cn_{C_{non-reactive} }} \left( C_{\text{non-reactive},i} - \overlinebar{C_C}_{\text{non-reactive}}} \right)^2 } \right)]

(Equation 6)

Where:

Quantification of biochar storage for Crediting in the built environment will be updated in future versions of this Module in line with the best available science as more research in peer-reviewed literature is published.

7.2.1.3.2 Calculation of [math: F_{Reversal}]

This Module distinguishes between [math: F_{Reversal}] for biochar stored in concrete and biochar stored in asphalt. Note that [math: F_{Reversal}] for biochar stored in asphalt is assumed to be 100%, and thus the labile fraction is not included in calculation of [math: F_{Durable, Material}].

[math: F_{Reversal}] in concrete is determined through a geochemical model that assesses the weathering of a given built material over 1,000 years. An overview of the geochemical model used for this assessment and key assumptions underlying this model are given in Section 10.0.

The default value, based on a worst-case assessment (described in Section 10.0), is 2%. Project Proponents may choose to submit additional documentation to conduct a project-specific reversal assessment. As shown in Equation 5, a safety factor of 3 is applied to [math: F_{Reversal}] to ensure a conservative estimate. This approach, and the safety factor applied, will be reassessed as scientific consensus evolves.

7.2.1.3.3 Calculation of [math: F_{Labile}]

[math: F_{Labile}] is defined as the portion of biochar that is not considered inertinite (e.g. does not pass the 2% [math: R_0] threshold). It is calculated asThen:

[math: F_{Labiledurable} = \frac{m_{Biocharmin(0.95 , totalmax( 0 , (\bar{R_0} - m_s_{Biochar,R_0}) inertinite(\bar{C}_{\text{non-reactive}} − s_{m_C_{Biochar, totalnon-reactive}}) ) ) )]

(Equation 7)

Where:

The maximum and minimum functions are applied to ensure that the fractions are bounded.

7.2.1.3.2 Calculation of Uncertainty Discount, [math: U]

[math: U] is the project-specific durability discount for physical liberation and dispersal of the certified durable carbon through wear, comminution, and recycling over the 200-year horizon. It does not re-discount the labile fraction (which is not certified), the one-standard-deviation conservatism already contained within [math: F_{durable}], or acid and matrix dissolution: acid dissolves the host matrix and can expose biochar, but does not mineralize the inertinite fraction, which is the same basis on which the inertinite fraction is treated as permanent in the Biochar Storage in Low Oxygen Burial Environments Module.

[math: U] is determined per Project, and per distinct placement or mix design where a Project spans several, by the reversal risk questionnaire in Appendix A. The questionnaire scores placement and incorporation, physical exposure, and end-of-life and recycling factors, applies gating exclusions, and maps the net score to a durability discount band.

[R-YARC-0, Projects must submit a completed reversal risk questionnaire (Appendix A) for each placement or mix design, with evidence for every response (including gates G1–G3 and any Section D mitigation claimed), the resulting risk band and the durability discount U.]

The Project Proponent must complete the reversal risk questionnaire (Appendix A) for each placement or mix design, record the supporting evidence for each response in the PDD, and apply the resulting durability discount [math: U]. Where a new storage site is added to the Project after validation, such as a new plant at which biochar is incorporated or a new asset, placement, or region in which the biochar-amended mixedmaterial intois concreteused, the questionnaire must be completed for that site, before Certificates are issued for biochar stored there. The questionnaire must be re-completed at the renewal of each Crediting Period or on material change. A Project that does not complete the questionnaire, or that leaves a variable uncharacterized, receives the worst-case (Very High) discount for that variable.

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7.2.2 Calculation of CO2eCounterfactualCO2e Counterfactual, RP

For biochar production, the calculation of [math: CO_2e_{Counterfactual,\ RP}] is determined by the requirements laid out in the Counterfactuals sectionSection of the Biomass Feedstock Accounting Module.

7.2.3 Calculation of CO2eEmissionsCO2e Emissions, RP

[math: CO_2e_{Emissions,\ RP}] is the total greenhouse gas emissions associated with a given Reporting Period, RP.

Equations and emissions calculation requirements for [math: CO_2e_{Emissions,\ RP}] including emissions associated with reactor operations and reaction monitoring, are set out in the relevant Protocol and are not included in this Module. Specific considerations for CO2 stored as biochar in built materials are set out here.

CO2 removals must not be double counted, regardless of the production of product Environmental Product Declarations.. The product must still comply with all relevant emission accounting regulations and requirements, which may mean emissions are double counted,; however, removals must not be double counted. This is the most conservative approach to take. CreditingCertificate issuance claims must be transparently reported and must not form part of marketing for a separate product.

Allocation procedures may be undertaken to separate emissions associated with the concrete production and the emissions associated with the CO2 storage process. Allocation procedures must follow the following emissions allocation procedure:

Transport emissions must be considered if the average transport distance for biochar-amended built materials is more than the average transport distance of normal products produced by the production facility. All other downstream emissions may be excluded from the system boundary if these activities were already occurring and would continue to occur in the absence of theThe Project. This can be evidenced by providing documentation that the biochar-amended product meets the same performance requirements of a conventional product for the intended use case, as is described under 'the Section 2.0 Applicability'.

7.3 Buffer Pool

As outlined in the Risk of Reversal section of the Isometric Standard, the Buffer Pool is a mechanism used to insure against Reversal risks that may be observable and attributable to a particular project through monitoring. Based on present understanding, reversals in Biochar storage will not be directly observable with measurements and attributable to a particular project. Projects Crediting againstusing this Storage Module are Creditedtypically conservativelydeemed to accounthave forNo degradationObservable Risk of labile pools of biochar within the relevant Crediting time horizon. Projects applicable to this Module are categorized as having a Very Low Risk Level of Reversalreversal, according to the Isometric Standard Risk Assessment Questionnaire (also found in the relevant Protocol), as all reversal risk is accounted for using the reversal risk modelling and Uncertainty Discount approach. TheThis Bufferresults Poolin correspondinga to0% buffer pool for Projects using this lowestStorage Module. This reversal risk scorewill isbe 2%reassessed at the renewal of the Crediting Period, or when new scientific research and isknowledge intendedare as an additional precaution against unknownsproduced.

8.0 Monitoring Requirements

ThisThe requirements in this section outlinesapply to the monitoringprocess requirementssteps and equipment within the Project system boundary. Where the exclusion of downstream manufacturing emissions set out in the System Boundaries section is relied upon, the boundary terminates at the point at which biochar or a biochar-containing material transfers to the downstream manufacturer, and process data for Projectsthe incorporatingmanufacturer's own operations is not required. Requirements relating to the mass of biochar incorporated, the mix into which it was incorporated, and the pavement layer in buildingwhich materialsit eitherwas aslaid aapply filler,irrespective aggregate,of modifierthat or other formexclusion.

8.1 Process Requirements

[R-V04V-01, Projects must provideconfirm detailedhow informationthey onwill evidence the: 1) biochar mass percentage (wt.%) in the endfinal material; production2) processadmixtures or materials required because of the biochar, their function, and whether they are in the baseline mix; 3) whether the downstream-emissions exclusion (System Boundaries) is relied upon. ]

Project Proponents are required to provide detailed information on the end material production process in the PDD. This must include:

  • The reactor and equipment description including engineering design diagrams.
  • Mass percentage of biochar wt.% incorporated into the final construction material (e.g., concrete, brick, insulation panel).
  • Process specific details including energy consumption, curing steps or processing temperatures.
  • A list of all additional materials or admixtures (e.g., superplasticizers, accelerators, binders) that are required as a direct consequence of using biochar, along with an explanation of their function and whether they would be present in the baseline mix design.
  • Confirmation of whether the exclusion of downstream manufacturing emissions set out in the System Boundaries section is relied upon.
[/R-V04V-1]

Process specific details, including energy consumption, curing steps and processing temperatures, are required only where the exclusion of downstream manufacturing emissions set out in the System Boundaries section is not relied upon. Where the biochar-amended product meets the same performance requirements as a conventional product for the intended use case and requires no additional products or activities related to product manufacturing, installation, maintenance and end-of-life, those emissions are omitted from the system boundary and the underlying process data is not required.

[G-8RFV-0, Conditional: Where the downstream-emissions exclusion is relied upon, projects must evidence both conditions: 1) equivalent performance: a declaration of conformity or performance to the applicable product standard, supported by the underlying test reports or a third-party factory production control certificate where the manufacturer issues the declaration; and 2) no additional products or activities: the job mix formula or mix design for the amended and baseline formulations, plus production records for representative batches of both showing mixing temperature, mixing time and curing regime, or matching EPDs for both products under the same product category rules.]

Project Proponents relying on the exclusion must instead evidence that it applies. The evidence must address both conditions of the exclusion, because equivalent product performance does not by itself show that processing is unchanged:

  • Equivalent performance: a declaration of conformity or declaration of performance to the applicable product standard for the intended use case. Where the declaration is issued by the manufacturer, it must be supported by the test reports on which it is based (for example, type testing or factory production control results for the amended mixture) or by a certificate of factory production control issued by an independent certification body.
  • No additional products or activities: the job mix formula or mix design for both the amended and baseline formulations, showing that no additional materials or admixtures are required, together with production records for representative batches of both formulations showing the production or mixing temperature, mixing time, and curing regime, and confirming that no additional plant or processing steps are used. An Environmental Product Declaration (EPD) for the amended product, prepared under the same product category rules and system boundary as an EPD for the baseline product, may be provided in place of the production records.

Where either condition cannot be evidenced, the exclusion does not apply and the process data set out below is required.

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[RG-EN0GJAHE-0, Conditional: Where the downstream-emissions exclusion is not relied upon, projects must give energy use, processing temperature and curing regime for each added or modified process step.]

Where the exclusion is not relied upon, Project Proponents must provide, for each additional or modified process step, the energy consumption, processing temperature and curing regime, together with the emissions allocation procedure applied under the Quantification of CO2e Stored section. Where sub-process energy cannot be metered separately, Procedure 1 (Section 7.2.3) must be applied and all process emissions allocated to the removal.

[/G-JAHE-0]
[G-5ZD3-0, Projects must providestate documentationsthe verifyingmaximum temperature the biochar incorporationreaches during production of the final material and, if above 200°C, confirm VOC and PAH release is addressed in the contaminant exposure risk assessment.]

Irrespective of whether the exclusion is relied upon, Project Proponents must state the maximum temperature to which the biochar is exposed during production of the final material. Where this exceeds 200°C, the release of volatile organic compounds and PAHs must be addressed in the contaminant exposure risk assessment required under the Environmental and Social Safeguards section.

[/G-5ZD3-0]

8.1.1 Incorporation and Placement Evidence

[R-EN0G-1, Projects must select the documentation that will evidence biochar mass incorporated and the mix: 1) production batch records from the automated batching system; 2) bills of sale for biochar-containing admixtures or materials; 3) final product specifications from downstream users; 4) EPDs. For asphalt, the records must state the mix designation.]

To verify incorporation of biochar into the final product, Project Proponents must provide documentation in the PDD inthat oneestablishes both the mass of biochar incorporated and the threemix into which it was incorporated. Acceptable forms include:

  • Production batch records extracted from the producer's automated batching system, stating the mass of each material input per batch and the mix designation produced,
  • Bills of sale for biochar-containing admixtures or materials.,
  • Final product specifications from downstream users, or
  • Environmental Product Declarations (EPDs) where available.
[/R-EN0G-01]

IfProduction batch records must identify the biochar-basedissuing productfacility, isthe soldbatching system from which they are extracted and the date of extraction, must cover the full Reporting Period, and must reconcile to multiplethe downstreamProject manufacturersProponent's records of biochar dispatched to that facility. For asphalt, the documentation provided must identify the mix designation (e.g., concreteEN producers13108 withor differentSuperpave) mixfor designs)each batch, Projectso Proponentsthat maythe providepavement layer can be established as required under the Asphalt Layer Eligibility section.

[R-CY70-0, Projects must describe how biochar is stored and handled before incorporation, at the incorporating plant and any intermediate location, and confirm that it is: 1) held in enclosed silos or containers, or in covered stockpiles; 2) protected from wind and surface water; 3) sited away from drains and watercourses; and 4) managed to prevent self-heating.]

Only biochar shown to have been incorporated into the built material, by the documentation set out above, is certified. Biochar dispatched to a representativefacility rangebut ofnot useincorporated, casesincluding biochar lost in transport, storage, or handling, must not be certified, and typicallosses incorporationmust rates,be alongrecorded withand supportingdeducted documentation.as Inset such cases, justification for the assumed biochar contentout in the finalBiochar constructionProduction materialand Storage Protocol. Biochar stored before incorporation, at the incorporating plant or at any intermediate location, must be clearlyheld statedin enclosed silos or containers or in covered stockpiles, protected from wind and surface water, sited away from drains and watercourses, and conservativemanaged assumptionsto prevent self-heating. The Project Proponent must describe these storage and handling arrangements in the PDD.

[/R-CY70-0]

Where biochar is added to an asphalt mixture as a separate component rather than through the binder, the Project Proponent must state the point at which it is added in the plant (for example, directly to a batch-plant mixer, or through an additive or filler feed on a drum plant).

Where production batch records are not available, mix-level evidence may be usedprovided instead to establish placement: for asphalt, a job mix formula that identifies the biochar and its dosage and restricts it to a mix designated for a Sub-Surface Layer; for concrete, an element and mix specification that ties the biochar-amended mix to its placement. The mass of biochar incorporated must still be established by one of the forms listed above. Placement evidenced in this way is scored under the mix-level response to question A3 of the reversal risk questionnaire (Appendix A).

8.1.12 Reactor and Equipment Description

[R-29W5-01, Projects must provide ana engineeringprocess design diagram.]

An engineering designflow diagram of the process steps and equipment usedwithin the project boundary, up to transfer to the downstream manufacturer (including any dosing or feed system installed there, and modified steps at the manufacturer where the emissions exclusion is not relied upon).]

A process flow diagram covering the process steps and equipment within the Project system boundary must be included in the PDD. The designdiagram must cover the equipment the Project Proponent operates or contracts, including any dosing or feed system installed at the downstream manufacturer's facility, and must terminate at the point at which the material transfers to the downstream manufacturer. Where the exclusion of downstream manufacturing emissions set out in the System Boundaries section is not relied upon, the diagram must include:also cover the additional or modified process steps at the manufacturer's facility.

[/R-29W5-01]

The process flow diagram must be prepared to ISO 10628 or an equivalent convention, and must show:

Project Proponents must also provide an equipment list stating, for each item of equipment within the boundary, its function, make and model or asset identifier, and rated throughput capacity.

Process detailssteps should include acceptable processes including, but not limited to:

8.1.2 Biochar Characterization

[R-NYQT-0, Projects must describe biochar characterization and the approach to ongoing monitoring requirements.]

Characterization of biochar and ongoing monitoring requirements are outlined in Section 6.0 and must be included in the PDD for validation and subsequently submitted for verification adhering to the sampling frequency requirements.

[/R-NYQT-0]

8.1.3 Storage Site

[R-0K2N-0, Projects must state a best estimate of the expected service life of the built element and, for asphalt, of the biochar-bearing layer, including the expected resurfacing, rehabilitation or reconstruction interval, and the basis for each estimate (e.g. the applicable design standard or the road authority’s or asset owner’s published maintenance policy).]

ThoughThe Project Proponent must state in the PDD a best estimate of the expected service life of the built element and, for asphalt, of the biochar-bearing layer, including the expected resurfacing, rehabilitation, or reconstruction interval, with its basis. The estimate is not a commitment. Its basis may be the applicable design standard or the published maintenance policy of the road authority or asset owner for the application type and region; asset-specific records are not required.

[/R-0K2N-0]
[G-D94D-0, providingConditional: specificWhere the application or expected service life is not known (e.g. biochar-amended material supplied to unspecified end uses), projects must state this and confirm that the worst-case responses to questions C1 and C2 of the reversal risk questionnaire and the default comminution interval in Table A6 are applied.]

Where the application or expected service life is not known, for example because the biochar-amended material is supplied by a third-party producer to unspecified end uses, the Project Proponent must state this, and the worst-case responses to questions C1 and C2 of the reversal risk questionnaire (Appendix A) apply, together with the default comminution interval in Table A6.

[/G-D94D-0]
[G-0Y02-0, Conditional: Where site information supports a reversal risk questionnaire response other than the worst option, projects must state the information used and its basis (for asphalt, e.g. application type, traffic level, pavement layer, layer thickness and asphalt density; for concrete, e.g. design life, exposure class, concrete type and strength class, application type, demolition likelihood, and the end-of-life fate of returned concrete).]

Further site information can help demonstrate reduced risk of carbon loss if certain thresholds are met and highlight portions of the material stream that may require additional assessment. Where site information is used to support a response to the reversal risk questionnaire other than the worst option, its basis must be stated in the PDD. This may include:

For asphalt applications:

  • AsphaltApplication lifespantype (for example, trunk road, local road, parking area, or industrial pavement)
  • Traffic densitylevel (for example, annual average daily traffic or design traffic loading)
  • AsphaltPavement layer, layer thickness, and asphalt density

For concrete applications:

  • Structural/design lifespan of concrete
  • Exposure class (e.g. using EN206 or equivalent)
  • Concrete type and strength class
  • Application type (exampleexamples include but are not limited to; foundations, structural, decorative)
  • Demolition likelihood or planned obsolescence
  • Estimated fraction of returned or unused concrete from construction sites, and its associated end-of-life fate (e.g., landfill, reuse, downcycling)
[/G-0Y02-0]

9.0 Compliance withWith Product Standards

[G-MB8N-0, Project must provide evidences demonstrate comparability between produced products and traditional products. Standards, methodologies and SOP's that are utilized must be clearly outlined and referenced in the PDD upon submission, and deviations from standards must be highlighted.]

An applicability criteriacriterion for Creditingcertification with this Module is that the biochar-amended built materials must meet the same performance requirements as conventional products for the intended use case.

[G-MB8N-0, Projects must list the product standards, test methods and SOPs used to demonstrate comparability with the conventional product, and highlight any deviations from those standards.]

Project Proponents are required to demonstrate compliance with the relevant standards for the use case of each mix produced, while also demonstrating the product is comparable to traditional products and results in no additional product use. It is the responsibility of theThe Project Proponent to clearly demonstrate comparability between produced products and traditional products within the PDD submitted to theThe Project VVB and Isometric. Standards, methodologies and SOP'sSOPs that are utilized by a Project Proponent must be clearly outlined and referenced in the PDD upon submission, and deviations from standards must be highlighted.

[/G-MB8N-0]
[R-9KKF-01, Projects must provide evidence demonstrating(e.g. test reports, certificates of conformity) that each mix complies with the productsapplicable arelocal inproduct compliancestandards, withor relevantISO/CEN standards andwhere thenone products are comparable with traditional productsexist.]

Built materials produced for the purpose of carbon storage and CreditCertificate issuanceissuances are expected to meet the required performance standards and criteria for the intended application, as defined by applicable codes or regulations. These materials shouldmust be demonstrably fit for purpose and comparable in functional performance to traditional products that would have been used in the absence of the biochar-amended material. This may be achieved through the undertaking of standardized performance testing procedures required in the location the material is utilized. In the absence of local or regional standards related to production and performance criteria, a Project Proponent is required to adhere to International Organization for Standardization (ISO) and/or CEN (the European Committee for Standardization) criteria. The final product should be compliant with relevant product standards such as EN 15804 for Environmental Product Declaration in the construction industry, relevant product classes and quality standards that are applicable.

[/R-9KKF-01]

Evidence and data, resulting from research studies of biochar addition in built materials such as asphalt, cement or other building elements, have shown the potential for additional benefits and improvements on the final product quality 49,3941,4042. Biochar addition can impact a range of different properties (mechanical, chemical and physical properties) including but not limited to the following:

  • Flexural strength (N/mm²)
  • Sound absorption (Hz) (applicable for concrete and other building elements like insulation or plaster)
  • Compressive strength (N/mm²)
  • Tensile strength (N/mm²)
  • Density (kg/m³)
  • Electrical resistance [(Ω])
  • Sorption capacity
  • Fire resistance (fire retardant or fire resistance)

Project Proponents should include any additional product characterization, analysis and reported properties of the final produced materials. Changes or deviations from the baseline product values should also be included and relevant product standards referenced in the PDD Appendix.

Departures from standard may be permissible on a case-by-case basis. Project Proponents seeking a departure from standard must submit documentation on the requested departure and proof of approval by the relevant regulatory body to Isometric and the VVB.

10.0 Contributors

11.0 Definitions and Acronyms

Independent components of Isometric Certified Protocols which are transferable between and applicable to different Protocols.
Describes the addition of carbon dioxide removed from the atmosphere to a reservoir, which serves as its ultimate destination. This is also referred to as “sequestration”.
The escape of CO₂ to the atmosphere after it has been stored, and after a Certificate has been Issued. A Reversal is classified as avoidable if a Project Proponent has influence or control over it and it likely could have been averted through application of reasonable risk mitigation measures. Any other Reversals will be classified as unavoidable.
The amount of time carbon removed from the atmosphere by an intervention – for example, a CDR project – is expected to reside in a given Reservoir, taking into account both physical risks and socioeconomic constructs (such as contracts) to protect the Reservoir in question.
A material used in the construction of an asset.
An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.
A composite material composed of aggregate, cement, sand and water that cures to a solid over time.
A chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Ordinary Portland Cement (PC) is the most common cement used in modern concrete. Other types of cement include Ground Granulated Blast-furnace Slag (GGBS), Pulverised Fly Ash (PFA) and natural pozzolans.
The amount of CO₂ emissions that would cause the same integrated radiative forcing or temperature change, over a given time horizon, as an emitted amount of GHG or a mixture of GHGs. One common metric of CO₂e is the 100-year Global Warming Potential.
A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.
TheA amountpublicly visible, uniquely identifiable, Verified instrument Issued on the Isometric Registry. Isometric Issues three Certificate Types: Carbon Dioxide Removal Certificates, Emission Reduction Certificates and Environmental Attribute Certificates.
A lack of CO₂knowledge emissions that would causeof the sameexact integratedgreenhouse radiativegas forcingimpact (removal, reduction, or temperatureavoidance) change,associated overwith a givenparticular time horizon, as an emitted amount of GHGprocess or aEnvironmental mixture of GHGsAttribute. OneUncertainty commonmay metricbe ofquantified CO₂eusing isprobability thedistributions, 100-yearconfidence Globalintervals, Warmingor Potentialvariance estimates.
Activities that remove carbon dioxide (CO₂) from the atmosphere and store it in products or geological, terrestrial, and oceanic Reservoirs. CDR includes the enhancement of biological or geochemical sinks and direct air capture (DAC) and storage, but excludes natural CO₂ uptake not directly caused by human intervention.
The term used to represent the CO₂ taken out of the atmosphere as a result of a CDR process.
Raw material which is used for CO₂ Removal or GHG Reduction.
A publiclyretirement visiblepathway uniquelyin identifiablewhich Creditan Certificateexisting IssuedEAC byis retired to enable the issuance of a Registrynew thatEAC giveswith thedifferent ownerspecified of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocolcharacteristics.
The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.
Third-party auditing organizations that are experts in their sector and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric prior to conducting validation and verification.
The document, written by a Project Proponent, which records key characteristics of a Project and which forms the basis for Project Validation and evaluation in accordance with the relevant Certified Protocol. (Also known as “PDD”).
The document that clearly outlines how a Project will generate rigorously quantifiable Additional high-quality Removals or Reductions.
TheA termprocess usedfor toevaluating describeand greenhouse gas emissions toconfirming the atmospherenet asRemovals aand resultReductions of Project activities.
The steps offor a Project, Proponent’susing Removaldata orand Reductioninformation processcollected that result in carbon fluxes. The carbon flux associated with an activity is a component offrom the Project Proponent’sand assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).
A measurement which correlates with but is not a direct measurement of the variable of interest.
A collection of Removal or Reduction processes that have mechanisms in common.
for open systems, biogeochemical and/or physical interactions which occur during the removal process that decrease the CO₂ removal .
A lack of knowledge of the exact greenhouse gas impact (removal, reduction, or avoidance) associated with a particular process or Environmental Attribute. Uncertainty may be quantified using probability distributions, confidence intervals, or variance estimates.
Emissions that are produced by a specific CDR process and are directly controllable.
A mixture of water, organic acids, aldehydes, ketones, sugars, phenols, and other organic compounds derived from the thermal breakdown of biomass. Thermal breakdown of biomass is achieved via thermochemical processes, such as pyrolysis, which heat biomass in low- or no-oxygen environments to high temperatures (~e.g. 350-650°C). Bio-oil is often also referred to as pyrolysis oil or bio-crude.
Any tangible or intangible property that has value and can be owned, controlled or utilized by an individual or organization. In the context of this module, an asset refers to a physical structure.
A calculation, series of calculations or simulations that use input variables in order to generate values for variables of interest that are not directly measured.
An output of a process that has no intended value to the producer.
The document, written by a Project Proponent, which records key characteristics of a Project and which forms the basis for Project Validation and evaluation in accordance with the relevant Certified Protocol. (Also known as “PDD”).
Any person or entity who can potentially affect or be affected by Isometric or an individual Project activity.
The period of time over which a Project Design Document is valid, and over which Removals, Reductions or Environmental Attributes may be Verified, resulting in Issued Certificates.
A United States Government agency that protects human health and the environment.
GHG sources, sinks and reservoirs (SSRs) associated with the project boundary and included in the GHG Statement.
Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).
A systematic and independent process for evaluating the reasonableness of the assumptions, limitations and methods that support a Project and assessing whether the Project conforms to the criteria set forth in the Isometric Standard and the Protocol by which the Project is governed. Validation must be completed by an Isometric approved third-party (VVB).
The defined temporal and geographical boundary of a Project.
Reporting Period
A set of data describing pre-intervention or control conditions to be used as a reference scenario for comparison.
A conservative adjustment applied to estimated greenhouse gas (GHG) emission reductions or carbon removals to account for uncertainties, risks, or variability in measurement, permanence, or effectiveness of the credited activity. It reduces the amount of carbon Certificates issued to ensure environmental integrity and avoid over-crediting.
A process for evaluating and confirming the net Removals and Reductions for a Project, using data and information collected from the Project and assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).
Purposefully erring on the side of caution under conditions of Uncertainty by choosing input parameter values that will result in a lower net CO₂ Removal or GHG Reduction than if using the median input values. This is done to increase the likelihood that a given Removal or Reduction calculation is an underestimation rather than an overestimation.
A public document that transparently reports objective, comparable and third-party verified data about products and services' environmental performances from a lifecycle perspective. The EPD is supported by an underlying Life Cycle Assessment (LCA) report, a systematic and comprehensive summary of the LCA project to support the third-party verifier when verifying the EPD.
A common and recognized insurance mechanism among Registries allowing Certificates to be set aside (in this case by Isometric) to compensate for Reversals which may occur in the future.
A set of data describing pre-intervention or control conditions to be used as a reference scenario for comparison.
Certificates are issued to the Certificate Account of a Project Proponent with whom Isometric has a Validated Protocol after an Order for Verification and Certificate Issuance services from a Buyer and once a Verified Removal or Reduction has taken place.
A worldwide federation (NGO) of national standards bodies from more than 160 countries, one from each member country.
TotalA Inorganiccalculation, Carbon.
An analysisseries of howcalculations muchor differentsimulations componentsthat use input variables in a Model contributeorder to thegenerate overallvalues Uncertaintyfor variables of interest that are not directly measured.

1211.0 Appendix A: Reversal riskRisk

1211.1 Biochar Durability Horizon and Storage Uncertainty in the Built Environment

1211.1.1 Definition of Storage Uncertainty

AThis keyModule certifies biochar in built materials over a 200-year durability horizon, rather than the Isometric 1,000-year default. The grounds are set out in full in Section 1.0 and summarized here. They are specific to biochar rather than general to built materials. Containment over 1,000 years is neither guaranteed nor observable for this pathway, because the fate of the material through demolition, recycling, and end-of-life reprocessing across that span is extrapolated rather than documented. For cementitious materials, a further consideration forapplies. Biochar is exposed to the durabilitypore solution of CO2a storedcementitious inmatrix during encapsulation, typically at pH 12.5 to 13.53, which alters its structure, including pore enlargement and matrix defectiveness4. While the builtmaterial environmentremains intact this is not onlyitself a carbon-loss pathway, because there is no oxygen, no export route, and the condensed inertinite core is chemically resistant1. Altered and aged carbon is, however, more susceptible to oxidation5, so the exposure may leave the biochar more vulnerable to conditionsdegradation once the material is broken up and the carbon is exposed to the open environment. This consideration does not apply to asphalt, in which biocharthe durabilitybinder is likelya hydrophobic bituminous matrix rather than an alkaline aqueous environment; for asphalt, the horizon rests solely on the extent to which the fate of the material can be negativelydocumented. impactedThe 200-year horizon corresponds approximately to the design life of a built asset, butindicatively also50 years for common buildings and 100 years for monumental structures and bridges under EN 1990:2023, plus first reuse.
A second consideration is the uncertainty in the location of the productmaterial at any given time. As described inwith the relevant section of the CO2 Storage via Carbonation in the Built Environment Module, a built material may gopass through many different use cases inacross its life cycle, depending on the initial use case, local regulatory requirements, and economic incentives. In the traditional construction industry, there has not been ano need to track built materials past the life cycle of an asset, particularly where elements are designed to perform with minimal maintenance or intervention. Thus, biocharBiochar-amended built materials are therefore likely to transition through several construction-demolition-reuse cycles with minimal ability to track these changes. Over longthe time200-year periods (e.g. 1,000 years),horizon this leads to a high degree of uncertainty in both the storage location of the productmaterial and, consequently, whether or not the productit is exposed to conditions that lead to degradationloss of the biocharcertified carbon. This treats built-environment storage as an open system and necessitates athe conservative, project-specific approach to reversal risk,set describedout in the following sectionbelow.

1211.1.2 Biochar Reversal

TheThis labileModule certifies inertinite (recalcitrant) fraction of the biochar only (Equation 7). That fraction is subjectdurable over geological timescales once formed1 and is refined to degradationthe overthermally anon-reactive longerresidual periodby thermogravimetric analysis2. It is chemically resistant while it remains encapsulated in the host matrix, and while it remains in contained chunks after the matrix is broken up. The reversal concern is therefore not chemical mineralization of timeencapsulated duecarbon, but physical liberation of the certified inertinite to differentmobile degradationfines that are dispersed into the open environment. Once dispersed, the location and fate of the fines cannot be verified, and they are exposed to pathways that arecan applicablereturn the carbon to the physicalatmosphere, including oxidation of fine, high-surface-area and aged material5 and thermal destruction where sewage sludge, road runoff solids, or sweepings are incinerated. Consistent with the conservative approach this Module takes to a novel storage locationpathway, carbon is certified only where its retention can be quantified and verified, and certified carbon liberated to mobile fines is therefore treated as not retained. TheseThis treatment is adopted because the retention of dispersed fines cannot be demonstrated; it is not a finding that dispersed inertinite degrades in every receiving environment. Isometric will revisit it if evidence on the fate of dispersed biochar fines becomes available. Liberation happens through wear, comminution, and recycling. The pathways canthat act on liberated, dispersed material include:

EachTwo related mechanisms are handled outside this dispersal term. Acid and matrix dissolution can expose biochar as the host matrix is lost, but does not mineralize the inertinite fraction, so it is treated as an exposure driver in the questionnaire (Section B), not a carbon-loss term. Thermal exposure during hot asphalt recycling (approximately 150 to 190°C) is highly unlikey to reverse the certified fraction, because that fraction is by construction the thermally non-reactive residual determined by thermogravimetric analysis (Equation 7), which is stable well above that range: road-grade biochar loses only about 1% of theseits pathwaysmass to 150°C and about 5% to 400°C46, and oxidation onset rises with pyrolysis temperature, well above the hot-mix range47. High-temperature reprocessing of concrete to clinker (approximately 1,400°C, the calcination temperature described in the Concrete background) destroys even the inertinite, and is directlyhandled influencedas bya thegating storage environment, with the relevant site characteristics influencing which degradation pathways may be most prevalent in that storage environment. The durability of biochar is dependent not only on the storage site conditions but on biochar's physical and chemical propertiesexclusion (see Section 6.0 for more informationbelow).

1211.1.2.1 Biochar in Concrete

Quantifying the risk of reversal associated with biochar-amended concrete is inherently complex, given the high degree of uncertainty and variability in possible end-states of the concrete over 1,000 years. Degradation of the labile fractionLiberation of biochar withinfrom concrete can occur when biochar particles become exposed, which may occuroccurs when the concretematerial is inlost aor 'broken up, either during use case'or (e.g.at as partend of alife. building)During use, or when the concreterelevant goesdrivers throughare an end-of-life transition (e.g. recycled). This is the result of processes such as concretesurface loss by physical or chemical weathering, demolition of a built asset or other processes that expose additional surface area of the concrete. In most scenarios, physical loss of concrete is likely to be the most prevalent loss pathway, leading toincluding exposure of embedded biochar. This may occur under the following scenarios:

During use:

DuringThe end-of-life processespathways and their reversal treatment are set out in the Section 3.2.3.2.1 End-State Use Cases (Concrete) background and summarized here:

Noteagainst thatthermal theclosed-loop likelihood ofrecycling.]Thermal closed-loop recycling occurring,to whileclinker: potentiallyreprocessing resultingat incalcination sometemperatures degradation ofdestroys the labilecertified fractioninertinite. ofThis biochar,pathway is currentlya extremelygating lowexclusion due to the nascency of the technology. At the time of drafting, there are(G3): a limitedProject numberwith a credible, unconstrained likelihood of pilot projects operating at small scale, including in the United Kingdom, France and Canada. As closed-loop recycling is not currently operating at scale, it has been excluded from the calculation of reversal risk at this time. However, it is importantineligible tounless notea that closed-loop recyclingbinding, ifevidenced includedrestriction against it is in place. [/G-B0T4-0]

  • Landfill: the reversalmaterial riskremains model, hasin a significantsingle impactlocation, reducing geographic uncertainty, though acidic leachate exposure may apply depending on the total reversal risk (Figure A1)region. The inclusion of closed loop recycling in the reversal risk model will be revisited regularly as data availability increases and technologies develop.

    [Image: Figure A1 concrete stage]

    Figure A1: Sensitivity of the likelihood of closed-loop recycling on the amount of CO2 emitted to the atmosphere from closed-loop recycling over 1,000 years. The likelihood of closed-loop recycling was varied from 0 to 100%, while the likelihood of downcycling was decreased accordingly.

  • 1211.1.2.2 Biochar in Asphalt

    AsOnly discussedbiochar in a Sub-Surface Layer is eligible for certification under this Module; biochar in the surface course, and in bituminous surface treatments, is an ineligible practice, as set out in the Section 3.2.30.2.2 Surface-course material abrades directly under tire contact, generating tire and road pavement wear particles at a size (peaking at 63 to 106 μm)15 asphaltthat is abraded over time due to friction between tire treads and the pavement surface. Abraded particles fall within a dust-sized particle size distribution, and thus these particles can be easilyreadily transported away from the road surface by wind orand water. ThisThe leadsabraded fraction cannot be quantified or verified for an individual pavement, and its subsequent location and fate cannot be determined (see Asphalt Layer Eligibility). For eligible Sub-Surface placements, the reversal concern is the biochar comminuted to uncertaintymobile infines during milling and recycling over the finalhorizon, locationwhich ofis quantified through the abradedquestionnaire particles, as well asand the interactionsUncertainty betweenDiscount the([math: environmentU]) andderivation co-abraded biocharbelow. Equally, exposureExposure to chemicals such as chlorides (from road salt) and sulphatessulfates (from surface water) may leadincrease tothe destabilisationreactivity of thedispersed biochar structure and increased reactivity. Conservatively constraining the amount of biochar that is abraded and subject to degradation is a critical step in reliably determining the amount of carbon that is durably stored in biochar-amended asphaltmaterial.

    1211.2 Reversal Risk Approach and Calculation of Uncertainty Discounts

    12.2.1

    Reversal Concrete

    Dueis toassessed limitedfor dataeach onProject the incidence of high-temperature structure fires, the reversal risk presented in this section focuses on reversal through contact with low-pH fluids. Numerical Modelling was adopted asusing a method for evaluating the associated reversal risksquestionnaire. The modelnet willscore be revisited as more data becomes available.

    To refine the assumption of reversal duemaps to acidic exposure, a geochemicalbanded modeldurability that simulates CO2 loss from concrete due to long-term acid exposure was developed using PHREEQC (version 3)discount, an open-source program for simulating chemical reactions and transport processes. This model quantifies the extent of degradation in biochar-based concrete over a 1,000-year period due to dissolution of concrete in acidic environments, both naturally occurring (e.g., acid rain, acidic groundwater) and industrially impacted (e.g., acid mine drainage)—across a pH range from 7 to 0.1, and subsequent exposure of the labile biochar fraction to atmospheric conditions.

    The geochemical model incorporates equilibrium and kinetic interactions between aqueous solutions and cement phases using the Cemdata18 database: a chemical thermodynamic database for hydrated Portland cement and alkali-activated materials. Key model parameters, data input are sourced from literature studies include: cement composition44,45, reactive surface area (grain size)46,47, reaction constant of specific mineral phases48,49,50,51 and acid concentration52,53.

    The geochemical model assumes no carbonation happened within concrete in advance. The Total Inorganic Carbon (TIC[math: U]) content before acid weathering is recorded and used as baseline comparison with remaining TIC after interaction with various acidic fluids. This model considers acid rain, acidic groundwater, acid mine drainage, and an extreme pH scenario, represented by varying the amount of sulfuric acid in the model conditions. Sensitivity analysis was performed on scenarios where reactive surface area and temperature varied from low to high. The remaining TIC reported for different scenarios is based on consumption of the initial material, with the reaction reaching equilibrium at the last step of the model. This allows for the computation and comparison of the worst case scenario (pH 0.1, high reactive surface area, room temperature). ThisEach scenarioband's resulted in approximately 2% lossvalue of the initial concrete material. In some less aggressive conditions (e.g., groundwater at pH 7), the loss was as low as less than 0.001%.

    Taking the result of this reversal risk model, some simplifying assumptions can be used to conservatively estimate the portion of biochar that will degrade over 1000 years. These assumptions include:

    Using this framework, it can be assumed that 2% of concrete loss by mass over 1000 years correlates with 2% of biochar by mass that will be exposed to conditions that may lead to degradation of the labile fraction. Thus, to account for this uncertainty, the percentage of the labile fraction that is associated with the 2% of the exposed biochar surfaces will be discounted from [math: CO_{2e_{Stored}}U] is derived from a comminution and dispersal model of how the certified inertinite is physically liberated over the horizon, set out under Derivation of the Durability Discount below.

    Reversal risk is assessed on a project-by-project basis. The Project Proponent must complete the questionnaire for each Project, for each distinct placement or mix design where a Project spans several, and for each new storage site added to the Project after validation (see Calculation of Uncertainty Discount,[math: U]). Because built-environment storage is largely unobservable over the horizon, the output is a durability uncertainty discount on the certified durable fraction ([math: U] applied in Equation 4), instead of a buffer-pool contribution. This assessment is alsoconservative givenby adefault: safetyany factor of 3, as described in Section 7.2.1.3, to account for concrete degradation pathways that arevariable not consideredcharacterized withinwith verifiable evidence is scored at its worst option, and gating answers override the geochemicaltotal modeland but maycan result in biocharineligibility exposure,of suchthe as crushing during demolitionProject.

    Note that Projects may choose to provide documentationdocumentations specific to the region of operations to calculate a Project-specific reversal risk. This documentation may include, but is not limited to:

    1211.2.21 AsphaltThe Reversal Risk Questionnaire

    ToTable conservativelyA1: estimateGating Criteria.

    Ref

    Gating question

    If yes

    G1

    Is the amountbiochar in a bituminous surface treatment, or in a surface course? (see Section 2)

    Ineligible

    G2

    Can the Project provide layer-constraining product evidence (job mix formula or EN 13108 / Superpave designation for asphalt; element and mix specification for concrete) tying the biochar mass to its placement, as set out in Incorporation and Placement Evidence?

    If no, score the volume at the worst option in every question

    G3

    Concrete: is there a credible, unconstrained likelihood of closed-loop reprocessing to clinker (approximately 1,400°C, destroying even the inertinite), with no binding restriction against it?

    Ineligible or Very High unless mitigated by D1

    Table A2: Section A (placement and incorporation).

    Ref

    Factor

    Response option

    Points

    A1

    Placement within the built element

    Asphalt, Sub-Surface base course

    0

    Asphalt, binder or intermediate course

    2

    Asphalt, surface course

    Not eligible

    Concrete, thick structural or foundation

    0

    Concrete, above-ground building element

    2

    Concrete, thin element (brick, facade panel, paving, tile)

    4

    A2

    Incorporation route (degree of encapsulation)

    Fully encapsulated (asphalt: binder modifier, or filler-sized biochar in the mastic; concrete: cementitious matrix, filler, or SCM)

    0

    Aggregate substitute

    2

    Coarse or functional-layer incorporation (exposed)

    3

    A3

    Placement evidence quality

    Production batch records stating the mix designation or element and mix specification, reconciled to biochar dispatched (Incorporation and Placement Evidence)

    0

    Mix-level evidence only (a job mix formula or element and mix specification that restricts the biochar to a stated placement), without per-batch records

    2

    Buyer attestation only, or none (triggers G2)

    worst-case

    [G-QBYF-0, Conditional: Where an asphalt project claims 'fully encapsulated' for A2, projects must provide the binder or emulsion formulation stating biochar dosage, or biochar particle-size distribution meeting filler grading (EN 13043 or ASTM D242), plus a job mix formula identifying the biochar and its function.]

    For asphalt, the fully encapsulated response to A2 applies where the biochar is abradedincorporated frominto asphaltthe overmastic, 1000either:

    • dispersed yearsin andthe b)bituminous degradesbinder overor 1000bitumen years,emulsion before it is useful to base calculations on a hypothetical scenario, in which we consider a 1 m³ block of asphalt amendedcombined with athe given percentage of biochar. Key assumptions in this scenario are:

      • This block of asphalt is in a high-traffic density roadaggregate, whichevidenced weby assumebinder abradesor atemulsion aformulation raterecords of 0.5 mm/year 31. This assumption is conservative, as abrasion rates are lower in areas with lower traffic density.
      • The density of asphalt is taken as 2300 kg/m³ (Iowa Department of Transportation).
      • The biochar is evenly distributed through the pavement in all life cycles, and the labile fraction is evenly distributed amongstating the biochar particles.dosage; or
      • Theadded lifespanto the mixture as a separate component at filler size, meeting the filler-aggregate grading of asphaltEN pavement13043 is 15 years, with 93% of material recycled between lifespans.
      • The labile fraction of abraded biochar particles will degrade.

      Using these assumptions, it is possible(70 to calculate100% passing the amount0.063 ofmm biocharsieve) thator isASTM lostD242/D242M per- year19 and,(70 consequently,to 100% passing the percentage0.075 ofmm the labile fraction that will degrade per year. As shown in Figure A2sieve), theseevidenced calculationsby demonstrateparticle thatsize 100%distribution testing of the biochar containedas delivered to the plant for each storage batch. In both cases, the job mix formula or mix design for the final mixture must identify the biochar and its function in the originalmixture. blockBiochar added as a separate component that is coarser than filler grading, or for which filler grading is not evidenced, is scored as an aggregate substitute.

    [/G-QBYF-0]

    Table A3: Section B (physical exposure over the horizon).

    Ref

    Factor

    Response option

    Points

    B1

    Abrasion or surface-wear exposure (asphalt)

    Not surface-exposed (Sub-Surface)

    0

    Low-volume road or light traffic

    2

    High-traffic highway

    4

    B2

    Chemical exposure (concrete EN 206 class; asphalt de-icing)

    Mild (for example XC1, dry or sheltered)

    0

    Moderate

    1

    Aggressive (XA, XS, XF; low-pH groundwater or acid rain)

    3

    B3

    High-temperature or fire event exposure (asset type and region)

    Low

    0

    Moderate

    1

    High

    2

    Table A4: Section C (end-of-life and recycling).

    Ref

    Factor

    Response option

    Points

    C1

    Service life before the first end-of-life event (for asphalt, the first event that mills, reclaims, or removes the biochar-bearing layer)

    Long (greater than 50 years)

    0

    Medium (25 to 50 years)

    1

    Short (less than 25 years)

    3

    C2

    Recycling or reprocessing cycles within the horizon (for asphalt, events that mill or reclaim the biochar-bearing layer)

    0 to 1

    0

    2 to 5

    2

    More than 5

    4

    C3

    Dominant regional end-of-life pathway

    Contained (in-situ or ex-situ reuse; downcycle to aggregate or base; engineered landfill)

    0

    Recycling into new bound material, hot, warm, or cold (comminution, re-lay)

    2

    Closed-loop reprocessing to clinker or other high-temperature destruction

    Gating G3 / Very High

    Unknown

    4

    C4

    Regional recycling rate and policy trajectory

    Low and stable

    0

    Moderate

    1

    High, or rising toward high-temperature reprocessing

    3

    For asphalt, C1 and C2 are answered for the biochar-bearing layer. C1 is the expected time until that layer is first milled, removed, or reprocessed. C2 is the number of asphaltsuch is abradedevents within 90the yearshorizon, and thusmust webe assumeconsistent thatwith 100%[math: N] as determined under Derivation of the labileDurability fractionDiscount degradesU. withinWhere a layer-specific interval is not evidenced, C1 and C2 are answered on the resurfacing interval.

    For C3, engineered landfill means disposal at a landfill operated under a permit issued under the applicable waste regulation for the class of waste concerned (for example, Council Directive 1999/31/EC on the landfill of waste, or equivalent national regulation), with the basal barrier, leachate controls, and capping required for that timelandfill frameclass, and with records of the waste accepted. TheDisposal calculationsat shownunpermitted insites Figureor A2open assumedumps, or use as unregulated fill, is not engineered landfill and is scored as Unknown. To score C3 as contained on the basis of landfill, the Project Proponent must evidence, from national or regional waste statistics, that thelandfill labileat fractionsuch facilities is 5%the perdominant massend-of-life ofpathway biochar;for importantly,the because a key assumption is that biochar particles are evenly distributedmaterial in the pavementregion, and must identify the lossregulatory percentagesregime under which those facilities operate.

    Table A5: Section D (containment safeguards and mitigants). Subtract from the Section A to C total.

    Ref

    Mitigation

    Response

    Points

    D1

    Binding end-use restriction (for example Sub-Surface only; no closed-loop clinker recycling), enforced by design or contract and evidenced

    Yes

    −3

    No

    0

    D2

    Regional regulatory or practical constraint preventing the high-risk pathway

    Yes

    −2

    No

    0

    D3

    Asset-level tracking: the biochar-amended material is recorded in the asset owner's asset or pavement management register, identifying its location, element or layer, and biochar content, and the asset owner has agreed in writing to notify the Project Proponent of works that will mill, remove, or demolish it during the Crediting Period

    Yes

    −1

    No

    0

    Completion of the questionnaire for each new storage site added to the Project, and its re-completion at each Crediting Period renewal or on material change, are required of all Projects (Calculation of Uncertainty Discount,[math: U]) and do not changescore withunder Section D. Where D3 is claimed, the biocharregister concentrationentry or withand the labileasset fraction.

    [Image:owner's Figureagreement A2must biocharbe loss]

    Figureprovided A2in Percentagethe of biochar lost over time from a 1 m3 block of asphaltPDD, assumingworks annotified abrasionunder ratethe ofagreement 0.5must mm/yearbe reported at the next Verification, and anotified biocharworks contenttrigger of 5% by mass.

    Because these calculations demonstrate complete lossre-completion of the labilequestionnaire.

    Scoring. fractionSum ofSections biochar-amendedA asphaltto within 100 yearsC, 100%then subtract Section D to give the net score. Map the net score to the risk rating and durability discount [math: U] in the banded discount schedule below (Derivation of the labileDurability fractionDiscount U). A Project that does not complete the questionnaire, or that leaves variables uncharacterized, receives the worst-case discount.

    Responses to Section C are forecasts over the 200-year horizon, based on the evidence available at the time of theassessment, biocharand producedare not commitments by the Project Proponent. A response other than the worst option must be supported by documented evidence, such as the design working life of the asset under the applicable design standard, the maintenance, rehabilitation, and reconstruction policy of the asset owner or road authority, and national or regional data on end-of-life and recycling practice, and the highest-risk response consistent with that evidence must be selected. The questionnaire is deductedcompleted fromfor each new storage site added to the CreditsProject and re-completed at each Crediting Period renewal or on material change, and a revised discount applies to Certificates issued after the re-assessment.

    11.2.2 Derivation of the Durability Discount U

    [math: U] is the project-specific durability discount as specified in Equation 4, Section 7. The term also represents the fraction of the certified inertinite that may be physically liberated to mobile fines and dispersed into oxic surface environments over the 200-year horizon. The calculation for [math: U]does not re-discount the labile fraction, which is not certified under this Module.

    Note; thatthe thisone-standard-deviation frameworkconservatism is already accounted for in [math: F_{durable}]; or acid and matrix dissolution, which exposes but does not takemineralize intoinertinite1. accountThermal commondestruction maintenance(clinker practicesreprocessing) and surface abrasion are handled as gating exclusions, so they are also excluded from the graded discounts here.

    [math: U] is derived from the comminuted-inertinite retention model as shown by the equation below:

    [math: U = 1 - (1 - f_{disp})^{N}]

    (Equation 8)

    Where:

    [math: N] follows from the service life of the element or, for asphalt pavements, suchof the biochar-bearing layer. The basis is the design standards and documented maintenance and replacement-interval data. Design working lives under EN 1990:2023 are 50 years for common buildings, 100 years for monumental structures and bridges, and 25 years for agricultural buildings; foundations are frequently left in situ.

    For asphalt, [math: N] is the number of events within the 200-year horizon at which the biochar-bearing layer is milled, removed, or reprocessed, because the biochar is comminuted only when its own layer is disturbed. A resurfacing event counts for a layer where the milling or removal depth reaches any part of that layer. Rehabilitation, reconstruction, full-depth reclamation, and in-place recycling count where they reach that layer.

    By default, every resurfacing event is treated as sealcoatingdisturbing the biochar-bearing layer. [math: N] is then set by the resurfacing interval, roughly 15 to 25 years14, rather than the 40-year pavement design-life label in Table 1. A longer interval may be used only where the Project Proponent evidences, for the application type and region:

    This must be set out as theserequired practicesunder varyStorage by region and specific applicationSite. ThusThe basis may be the applicable pavement design standard or the published maintenance policy of the road authority or asset owner, together with the layer thicknesses in the absencepavement design. Where the evidence supports a range of specific information regardingintervals, the useshortest caseinterval andis regionalused.

    Table practicesA6: relevantComminution rounds N over the 200-year horizon, by placement band.

    Band

    Service life (sourced)

    N over 200 yr

    Concrete structural or foundation

    50 to 100+ yr; often left in situ (EN 1990:2023)

    ~0 to 2

    Concrete above-ground element

    ~50 yr (EN 1990:2023)

    ~3 to 4

    Concrete thin element (facade, paving, tile)

    ~20 to 25 yr (EN 1990:2023)

    ~8 to 10

    Asphalt Sub-Surface default (biochar-bearing layer disturbed at each resurfacing)

    Disturbance interval of the biochar-bearing layer; default ~15 to 25 yr milling interval where not evidenced. N over 200 yr: ~7 to 13 (default); lower where a longer disturbance interval is evidenced ~15 to 25 yr milling interval, N over 200 yr: ~7 to 13

    ~7 to 13

    Asphalt Sub-Surface, layer-specific interval evidenced

    Evidenced milling, rehabilitation, or reconstruction interval of the biochar-bearing layer

    200 yr divided by the evidenced interval

    The Reclaimed Asphalt Pavement (RAP) multiple-recycling literature shows the binder degrades cycle-on-cycle48, so later asphalt cycles are downcycling rather than re-laying, but this does not reduce [math: N], because the biochar is comminuted at each event that mills or reclaims the biochar-bearing layer, whether the material is re-laid or downcycled.

    Recycling of biochar-bearing reclaimed asphalt into a new bound mixture, whether by hot, warm, or cold recycling, is not treated as a reversal of the biochar it contains. The durability discount applies only to the fraction comminuted to mobile fines at each milling or processing round ([math: f_{disp}]); the remainder is treated as retained, whether it is re-bound in a new pavement or used in another construction application.

    [G-YNNS-0, Conditional: Where asphalt mixes may contain biochar-bearing RAP, projects must confirm that only newly added biochar mass will be claimed.]

    Where biochar is added to a Projectmixture that contains biochar-bearing RAP, only the mostnewly added biochar mass may be certified, and the biochar carried in the RAP must not be certified again.

    [/G-YNNS-0]

    [math: f_{disp}], no study measures biochar carbon retention through actual asphalt or concrete recycling and this represents a gap in the current literature. As such, [math: f_{disp}] is inferred from the fines (sub-0.075 mm) generated per processing round in the aggregate-recycling literature:

    The high end of each range is taken because biochar is more friable than mineral aggregate and the dispersed fraction is untraceable.

    These values are a conservative scenarioproxy isfor used.the Projectliberation Proponentsof may choosebiochar to providemobile additionalfines, informationpending direct measurement. Isometric will recalibrate [math: f_{disp}] as direct measurements of biochar carbon retention through asphalt and concrete milling, crushing, and recycling become available.

    Applying Equation 8 across the sourced parameter ranges of [math: f_{disp}] gives: concrete structural ([math: f_{disp}] 0.03 to conduct0.05, aN Project1 to 2) roughly 0 to 10%; concrete above-specificground (0.04 to 0.05, N 3.5 to 4) roughly 13 to 19%; asphalt base (0.05 to 0.075, N 7) roughly 30 to 42%; concrete thin (0.06 to 0.08, N 9 to 10) roughly 43 to 57%; and asphalt binder (0.075 to 0.10, N 10 to 13) roughly 63 to 65%. These model outputs cluster into four risk bands shown in Table A7. The Module adopts one durability discount calculation[math: U] per band; the Table below maps each net score and risk rating to that discount and to the representative placement and parameter basis behind it.

    Table A7: Durability discount U by risk band.

    Net score

    Risk rating

    [math: U]

    Representative placement, and parameter basis

    0 to 3

    Low

    10%

    Concrete structural or foundation; N ~0 to 2 (EN 1990:2023), minimal coarse-crush fines50

    4 to 8

    Moderate

    30%

    Above-ground concrete; asphalt base course; N ~3 to 7 (EN 1990:2023^49), RAP-fines proxy49

    9 to 14

    High

    60%

    Thin concrete; asphalt binder course; N ~8 to 13 (EN 1990:2023^49), elevated fines51,52

    15 or more

    Very High

    90% (or ineligible)

    Extreme dispersal, or worst-case default for un-characterized projects

    Gating (G1; G3 unmitigated)

    Ineligible

    100%

    Surface asphalt and seal coats (in-service dispersal that cannot be quantified or verified, Applicability Section); unmitigated clinker reprocessing (thermal destruction)

    1312.0 Relevant Works

    Footnotes

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    2. Sanei et al. (2025), Quantifying inertinite carbon in biochar, International Journal of Coal Geology 310, 104886. 10.1016/j.coal.2025.104886↩↩2↩3↩4↩5

    3. Plusquellec, G., Geiker, M. R., Lindgård, J., Duchesne, J., Fournier, B., & De Weerdt, K. (2017). Determination of the pH and the free alkali metal content in the pore solution of concrete: Review and experimental comparison. Cement and Concrete Research, 96, 13–26. 10.1016/j.cemconres.2017.03.002↩↩2

    4. Xu, W., Zhang, Y., Li, M., Qu, F., Poon, C. S., Zhu, X., & Tsang, D. C. W. (2024). Durability and micromechanical properties of biochar in biochar-cement composites under marine environment. Journal of Cleaner Production, 450, 141842. 10.1016/j.jclepro.2024.141842↩↩2↩3

    5. Zimmerman, A. R. (2010). Abiotic and microbial oxidation of laboratory-produced black carbon (biochar). Environmental Science & Technology, 44(4), 1295–1301. 10.1021/es903140c↩↩2↩3

    6. Kamini, G. P., Tee, K. F., Gimbun, J., & Chin, S. C. (2023). Biochar in cementitious material—A review on physical, chemical, mechanical, and durability properties. AIMS Materials Science, 10(3), 405-425. 10.3934/matersci.2023022↩↩2

    7. Gupta, S., Kua, H. W., & Low, C. Y. (2018). Use of biochar as carbon sequestering additive in cement mortar. Cement and Concrete Composites, 87, 110–129. 10.1016/j.cemconcomp.2017.12.009↩↩2

    8. Wijeyawardana, P., Nanayakkara, N., Law, D., Gunasekara, C., Karunarathna, A., & Pramanik, B. K. (2023). Performance of biochar mixed cement paste for removal of Cu, Pb and Zn from stormwater. Environmental Research, 232, 116331. 10.1016/j.envres.2023.116331↩↩2

    9. Barbhuiya, S., Bhusan Das, B., & Kanavaris, F. (2024). Biochar-concrete: A comprehensive review of properties, production and sustainability. Case Studies in Construction Materials, 20, e02859. 10.1016/j.cscm.2024.e02859↩↩2↩3↩4

    10. Kushwah, S., Singh, S., Agarwal, R., Nighot, N., S., Kumar, R., Athar, H., & Naik B, S. (2024). Mixture of biochar as a green additive in cement-based materials for carbon dioxide sequestration. Journal of Materials Science: Materials in Engineering, 19, 27. 10.1186/s40712-024-00170-y↩

    11. Rashid, S., Raghav, A., Goyal, A., Danie Roy, A. B., & Singh, M. (2024). Biochar as a sustainable additive in cementitious composites: A comprehensive analysis of properties and environmental impact. Industrial Crops and Products, 209, 118044. 10.1016/j.indcrop.2024.118044↩

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