This Module details the requirements for storage of carbon as biochar in the built environment, including reversal risk and durability. Within this Module, a built material is defined as a product used in the construction of buildings or infrastructure projects, including concrete, cement, and asphalt. Durability refers to the stability of CO2e stored as biochar in the built material and the length of time for which CO2 is removed from Earth's atmosphere (> 1,000 years). Within this Module, concrete durability is used to refer to the structural durability of concrete. This Module is intended for use in conjunction with other Isometric Protocols and Modules, and assumes the following:
This Module applies to biochar that is physically incorporated into conventional built materials (e.g., concrete and asphalt) during their manufacture. It does not apply to CO2 stored in built materials as carbonate minerals, which is addressed by the CO2 Storage via Carbonation in the Built Environment Module. Where a built material both incorporates biochar and stores CO2 through carbonation, only the carbon stored as biochar is Certified under this Module.
The durability horizon for biochar in built materials is 200 years, and Certificate issuance under this Module is limited to the inertinite fraction of the biochar, quantified by random reflectance against the inertinite benchmark1 and refined to the recalcitrant fraction by thermogravimetric analysis2. The horizon is shorter than the 1,000-year default applied elsewhere by the Isometric Standard. It is not a finding that the inertinite degrades after 200 years. It limits the durability claim to the period over which the fate of the material can be documented rather than extrapolated. The durability discount in this Module (Appendix A: Reversal risk) depends on how many times the material is demolished, milled, or recycled, and on the end-of-life pathway at each event. Service lives and reprocessing intervals are documented over approximately one service life plus first reuse; across 1,000 years the number of reprocessing cycles and the pathway at each cycle are unconstrained. This applies with particular force to asphalt, which is milled and reprocessed at intervals of decades. A 200-year horizon corresponds approximately to the design life of a built asset, indicatively 50 years for common buildings and 100 years for monumental structures and bridges under EN 1990:2023, plus reuse.
A further consideration applies to cementitious materials only. Biochar in concrete and other cement-based materials is exposed to the pore solution during encapsulation, typically at pH 12.5 to 13.53, which alters its structure4. While the material remains intact this is not itself a carbon loss pathway, but altered and aged carbon is more susceptible to oxidation5, so the exposure may leave the biochar more vulnerable to degradation once the material is broken up and the carbon is exposed to the open environment. Direct evidence on the degradation of biochar recovered from cured cementitious material is not yet available. This consideration does not apply to asphalt, in which the binder is a hydrophobic bituminous matrix rather than an alkaline aqueous environment.
The stability of carbon within the built environment, and thus its durability, depends on interactions with the surrounding environment and the intended use case. Built materials used forin the construction of buildings or infrastructure projectsProjects may be exposed to variable environmental conditions during their use life. Potential riskRisk factors whichthat may affect the expected durability of built materials include, but are not limited to, interactions with acidic fluids (e.g.such as acid rain, and low-pH groundwater), building fire, abrasion, comminution during recycling, and high-temperature closed-loop recycling of concrete. For the purpose of this Module, built materials are treated as an open system storage mechanism. InReversal comparisonrisk over the durability horizon is assessed on a Project-specific basis and applied as an uncertainty discount, closedas systemsset areout isolatedin fromAppendix externalA: environmentalReversal changesrisk.
Biochar storage in the built environment is a novel CDR approach, so this Module incorporates requirements that may be more stringent than some current relevant regulations or other Protocols related to biochar for CDR. This Module will be reviewed when there is an update to scientific published literature whichthat would affect net CO2e removal quantification, durability claims, or the monitoring guidelines outlined in this Module. Future versions of this Module may be altered, particularly regarding requirements for demonstrating durability of biochar, as the stability of carbon in biochar is better demonstrated and documented; quantification of biochar degradation is further improved and refined; and the overall body of knowledge and data regarding all processes, from feedstock supply to conversion and to permanent storage, is significantly increased.
Projects seeking CreditsCertificates fromfor biochar stored in the built environment will beare subject to applicabilitythe requirements (set out in SectionApplicability 2.0and Biochar Characterization), biocharand characterisationto requirements (Section 6.0) andthe reversal risk assessment (set out in SectionAppendix 10.0A: Reversal risk) to account for unobservable reversals.
This Module is applicable to Projects that store CO2 in the built environment in the form of biochar incorporated into built materials. The following products are applicable under this Module:
Projects seeking CreditsCertificates under this Module must meet the following criteria:
Only biochar incorporated into asphalt that is laid in a Sub-Surface Layer is eligible for certification under this Module. Biochar in a surface course is not eligible.
The surface course is excluded because its service life prevents a conservative, verifiable estimate of the biochar retained. It is the only bound layer under direct tire contact, so part of its biochar is liberated continuously during service as road pavement wear particles. Reported abrasion rates span more than an order of magnitude (0.04 to 0.5 mm per year13) depending on traffic, tire type, studded-tire use, and climate, and the abraded mass cannot be measured for an individual pavement or verified after the fact. The surface course is also the layer milled at each resurfacing, roughly every 15 to 25 years14, and its reclaimed material may be returned to a new surface course, so the biochar can remain in the most exposed position across successive cycles. Wear particles, which peak at 63 to 106 μm15, are carried to roadside soil, road runoff, stormwater and wastewater systems, and street-sweeping waste. Some of these routes end in sewage-sludge or waste incineration, which destroys the carbon, and the share following each route cannot be determined for a Project. The exclusion rests on the inability to quantify and verify the retained fraction, not on a finding that dispersed inertinite degrades in every receiving environment.
Isometric will reconsider this exclusion on evidence that allows in-service loss from a surface course to be bounded conservatively and verified for a Project, including measured retention of biochar carbon in cores taken from in-service surface courses across a range of traffic levels and climates, a field method for quantifying biochar in asphalt cores and wear particles that can be audited by a VVB, and data on the fate of biochar-bearing wear particles across receiving pathways.
The Project Proponent must identify the layer in which the biochar-amended mixture is laid against a recognized pavement-layer convention. Sub-surface placement must be evidenced for each mass of biochar claimed, by production batch records or, where these are unavailable, a job mix formula that restricts the biochar to a sub-surface mix, as set out in Incorporation and Placement Evidence. Biochar mass for which sub-surface placement is not evidenced is treated as surface-placed and is not eligible.
[/R-3C5D-0]Projects that are explicitly not applicable under this Module include:
Biochar is a durable carbon-rich solid material produced from the pyrolysis of waste biomass. The carbon content in biochar can be further separated into stable (with inertinite as a proxy) and degradable (labile) fractions. These distinct carbon fractions have different carbon durabilities, with the stable fraction of biochar being stored durably for a time horizon of 1,000 years and above81 while the labile fraction can degrade over shorter time horizons in the range of a few years to decades, when used in conventional soil amendment applications916 (see Isometric Biochar Production and Storage Protocol). Different production processes and feedstocks directly impact biochar's quality and stability, as they may result not only in variations in the proportions of labile and fixed (stable) fraction but also changes in biochar structure.
TheBiochar labile fraction of biochar gradually degrades over time through various pathways, depending on the conditions of its storage environment. In the context ofin the built environment, theseis pathwayssubject canto includetwo categories of process. The first is physical liberation and dispersal:
When assessingThis theacts total carbon removal capacity for each material, the durability of the stored carbon is impacted by both the biochar quality and type of construction material end application. Therefore, the reversal risk is dependentprincipally on the materiallabile usefraction, exposure to environmental conditions and howonly theseonce interactthat withfraction is exposed.
This Module certifies the buildingstable elementsfraction only. SeeThe Sectionphysical 10.0processes that liberate biochar from the host matrix are therefore the dominant determinant of durability, and they are the basis for furtherthe discussioninertinite ofretention reversalfactor set out in Appendix A: Reversal risk. andThe howstable fraction is durable over geological timescales once formed1; the question this Module answers is usednot towhether determinethat ancarbon uncertainty discount for biochardegrades in place, but whether it remains held within the built environmentmaterial.
In recent years, the incorporation of biochar in construction materials has been receiving increasing interest, owing to its unique properties such as porosity, high specific surface area, water retention capacity and organic carbon content. Biochar's unique structure and porosity makes it a versatile and innovative material that can be utilized in multiple applications including concrete, asphalt, bricks, tiles, insulation materials118, composites, panels, plasters and geopolymers. These uses not only contribute to permanent carbon removal but may also enhance specific material properties1218.
Previous studies have focused on integrating biochar in construction materials as a substitute, filler, additive or modifier, mainly in concrete and asphalt production49,1218. Applications that have gained traction include biochar used in:
These applications are discussed in further detail in Sectionthe 1.2.2Built Environment section.
New research on biochar stored in built materials has shown that these novel materials may capture additional CO2 from the air, particularly in the case of biochar - cement composites1420. Replacement of the aggregates in concrete production with biochar improves pore size distribution1218 and can enhance the CO2 carbonation process and increases concrete's ability to sequester carbon27.
At the time of writing, there is not sufficient evidence to include this in the quantification framework for net CDR achieved by biochar storage in the built environment. This will be revisited in future editions of the Module as new evidence is published and/or presented to Isometric by Project Proponents as proof of quantification.
Concrete, made from cement, sand, aggregate, water, and chemical admixtures, is the most widely used construction material in the world, with approximately 4.2 billion tonnes of cement produced globally in 2020 (Global Cement and Concrete Association, Cement and Concrete Around the World). Compared to other structural materials, concrete has a relatively low cost and embodied carbon, while also providing strength, durability and adaptability. However, because of the large volume of concrete produced and used globally, the concrete supply chain has a large carbon impact -, accounting for approximately 5- to 8% of total global CO2 emissions1521. The vast majority of emissions during concrete production result from manufacturing Portland Cement (PC) via calcination. During this process, crushed limestone (CaCO₃) is heated in a kiln to high temperatures (~1400°C), causing degradation to CaO (lime) and CO2CO2:
[math: CaCO_3 \to CaO + CO_2]
(Equation 1)
Though a portion of emissions are associated with processing limestone and heating the kilns, approximately half of the process emissions are the result of direct emissions from calcination1622.
Using less material in the built environment and using lower embodied carbon alternatives to PC both play a key role in efforts to reduce the climate impact of the construction industry. Several recent studies (summarized well in Legan et al.1420) have shown that addition of biochar in building materials, notably cement, can improve several key performance indicators while reducing the environmental impact of concrete production. For example, researchers have observed enhanced mechanical properties of biochar-amended concrete, including compressive, flexural and tensile strength; thermal stability and conductivity; bulk density; ductility; flowability; water absorption and penetration potential; and albedo1723. However, some studies have also noted decreased flexural strength1723 and decreased compressive strength186,9 at biochar dosages up to 40% by mass of cement.
Limits to the amount of biochar addition in construction materials are dictated from material specification and performance standards, especially in terms of the fresh and hardened mechanical properties of concrete and other cementitious composites. The impact on the mechanical performance and other properties is dependent on the biochar type (e.g., feedstock used, temperature of production, post-processing), percentage of biochar incorporated, and concrete mix design. Previously reported limit values of biochar in built materials ranged from 0.5% -to 40%1420, although these thresholds can vary depending on the material and application. Biochar is typically added at rates of up to 20% and 15% in concrete and asphalt production, respectively1924,2025,2126.
[Image: Figure 1 concrete stage]
Figure 1: Stages of a concrete product, from materials extraction, through processing, use and end-of-life scenarios. Biochar is incorporated in the processing stage as aggregate, filters or as an SCM.
Asphalt is a viscoelastic material that is commonly used in pavement construction, roofing and other building applications1827. It is a composite material typically including a mixture of aggregate materials, such as crushed stone, sand and gravel, bound together with bitumen, a highly viscous material derived from petroleum. Asphalt production requires significant energy consumption and is consequently an emissions-intensive process2228. Conventional methods of asphalt production are referred to as 'hot-mix asphalt', in which aggregates are heated to remove moisture and are combined with bitumen at high temperatures (typically 170- to 190°C)2329.
Several alternatives to hot-mix asphalt have been proposed to reduce the environmental impact of pavement construction. These include warm-mix asphalt, which produces a similar product at lower temperatures (130- to 150°C)2228; recycled asphalt pavements; and bio-asphalt, which encompasses both the partial replacement of fossil fuel-derived bitumen with plant-derived bio-oil2430 and addition of biochar to the mixture as an asphalt modifier2126. Cold-mix asphalt, including mixtures bound with bitumen emulsion or foamed bitumen and cold recycling of reclaimed asphalt, is produced at ambient or near-ambient temperatures, with lower energy use and volatile release than hot-mix production. Recent studies have shown that addition of modest amounts of biochar can maintain the rheological behaviors and enhance the oxidation resistance of asphalt2531, improve deformation resistance2426, and inhibit volatile organic compounds (VOCs)2632.
[Image: FigureHowever, 2surface concreteasphalt stage]
Figureis 2:prone Stagesto significant abrasion and loss through tyre wear, and therefore the durability and environmental fate of anthe asphalt product, from materials extraction, through processing, use and end-of-life scenarios. Biocharbiochar is incorporated in the processing stage as an aggregateuncertain.
Performance requirements for built assets and individual components are influenced by a complex set of factors, including the intended design life, the exposure environment and the mechanical properties needed to meet the requirements of the installation and application.
The design life of a built asset is the assumed period for which it can be used for its intended purpose. Examples of common asset types and design lives (as defined in EN 1990:2023 and CD 226) are summarized in Table 1.. Assets with slow rates of change, such as transport or public health infrastructure, will typically be designed with a longer service life and the minimization of maintenance in mind. Corporate office buildings, which are more likely to change in alignment with trends, may be designed with replaceability, adaptability or de-constructabilitydeconstructability in mind. It is important to note that design life of an asset is not necessarily equivalent to functional service life, which may be longer or shorter than the design life based on a variety of factors such as asset ownership, changes in regional regulatory environments, societal preferences and asset performance. A study of buildings in North America found that the majority of demolished buildings were less than 50 years old2733 and the Royal Institute of British Architects highlight that, in the UK, the functional service lives of buildings within the commercial sector are 25 to 30 years2834.
Table 1: Overview of common asset types and their design lives as defined in EN 1990:2023 and CD 226.
Asset Type | Design Life (years) |
|---|---|
Monumental building structures, bridges, other civil engineering structure supporting road or railway traffic | 100 |
Building structures, including commercial and residential buildings | 50 |
Asphalt pavement | 40 |
Agricultural (or similar) structures, replaceable structural parts other than tension components | 25 |
Temporary structures (e.g. pavilions, emergency buildings, structures associated with specific sport or art events) | < 10 |
Within a given asset, different components will have different expected design lives. For some element groups, such as the structural skeleton of buildings or the piers of a bridge, which serve the key functional purpose of providing the structure of the asset, the goal is a long service life. Elements with more transient functional requirements, such as internal space partitions, or those prone to disturbance, such as paving over buried services or utilities, will typically have shorter design lives.
Concrete may be used in one or more types of asset throughout its functional life, depending on regional policies and trends surrounding end-state concrete use. This topic is covered in further detail in (the Section 3.2.3.2.1 End-State Use Cases (Concrete) . Similarly, asphalt may be recycled into new pavement or other civil engineering projects throughout its functional life (see Section 3.2.3.2.2 End-State Use Cases, Asphalt).
Across long timescales,Over the process200-year ofdurability horizon, a built material may pass through one or more construction, demolition, and reuse may occur several timestransitions, and each oftransition these cycles will havecarries a Project-specific associated reversal risk (described in depthAppendix inA: SectionReversal 10risk.0). ConsequentlyConcrete is typically recycled at most once as a bound material before reaching a terminal downcycled state, so the uncertaintynumber inof transitions within the remaininghorizon biocharis content, and thus the volume of CO2 stored within a given amount of a built material, increases with each subsequent construction-demolition-reuse cyclesmall. The design life of anthe asset thereforedetermines influenceshow many transitions occur, and the numberuncertainty in the location and condition of thesethe cyclesbiochar thatincreases anwith amounteach of concrete may move through across 1,000+ years, which is critical for informing models of reversal risk (Section 10.0). A list of common asset types and their typical design life (as defined in EN 1990:2023 and CD 226) is given in Table 1one.
Figure 1 summarizes the typical life cycle of concrete, from procurement of raw material, through to processing, use and end-of-life scenarios. In the context of this Module, end-state use case refers to the fate of a given amount of biochar-amended concrete co-located within a single asset after the functional service life of that asset. How concrete is used after the end of an asset's life is influenced by a variety of complex factors, notably the geographic location and the economic and regulatory landscape for particular waste routes. Here, we discuss five possible end-state use cases and implications for CO2 stored within concrete.
1. In-situ Reuse
In-situ reuse refers to extending the use of concrete in its original form. Some level of repair may be required. Because the concrete remains in its original form, it is not subjected to additional reversal risk and stored biochar is considered stable.
2. Ex-situ Reuse
Ex-situ reuse refers to reuse of concrete in its original form, but in a different asset. This is uncommon practice for reinforced structural concrete elements due to the difficulty of extracting these components, lack of demand and the relatively low cost of new concrete. There are greater opportunities for ex-situ reuse with precast concrete elements, as these may be designed to facilitate deconstruction. There are currently limited regulatory frameworks worldwide that incentivize extensive re-use, though some examples do exist (see Norwegian Standard NS 3682). Frameworks currently under development will likely limit concrete reuse based on exposure class, potentially resulting in more extensive reuse of lower performance elements. Because the concrete remains in its original form, it is not subjected to additional reversal risk and stored biochar is considered stable.
3. Closed-loop Recycling
Closed-loop recycling refers to waste processing that occurs in a closed loop, allowing the waste to retain its original value and return to the original production process. Two routes must be distinguished, because they have opposite consequences for stored carbon.
In mechanical closed-loop recycling, concrete is crushed and the recovered material is used as aggregate in new concrete. The biochar is liberated from its original matrix and re-encapsulated, but it is not exposed to conditions that destroy the stable fraction.
In thermal closed-loop recycling, the recovered cement paste is reprocessed to clinker at the calcination temperatures described in Concrete. This destroys the biochar carbon, including the stable fraction. Technologies for concretethermal closed-loop concrete recycling remain nascent and have not yet been deployed at scale. As such,At the currenttime likelihoodof thatdrafting concretethere willare bea recycledlimited number of pilot projects operating at end-of-lifesmall scale, including in the United Kingdom, France, and Canada, and policy in several jurisdictions is verydirected lowtoward expanding this route.
Both routes are included in the reversal assessment set out in Appendix A: Reversal risk. However,Earlier itversions isof importantthis toModule note thatexcluded closed-loop recycling commonlyfrom involvesthe high-temperaturereversal wastecalculation processingon the grounds that mayit resultwas innot exposureoperating andat degradationscale. That exclusion no longer holds over the durability horizon of storedthis biocharModule.
4. Downcycling
Downcycling refers to waste processing where the resultant product has lower value than the original product. This is the most common end-state use case for concrete,. for example approximatelyApproximately 90% of concrete and demolition waste in the UK is managed in this wayrecovered (DEFRA, UK Statistics on Waste)2935. ThisThe process typically involves crushing of concrete and subsequent use in applications such as road subbase, coastal defenses, engineering fill, and external landscaping. Downcycled concrete may also be used as aggregate in new concrete products in instances where contamination from other waste products is low. But only a low precent of aggregates are reused, and generally the secondary aggregate replacement rates are typically capped in new structural concrete mixes.
Downcycling increases uncertainty about the location of the biochar-amended concrete,and butexposes additional surface area at the surfaces created by crushing. It does not introduceexpose anythe directbiochar to temperatures that destroy the stable fraction, and material placed in an unbound downcycled application is not subsequently routed to high-temperature reprocessing, so downcycling is treated as a terminal state for the purposes of the reversal risksassessment. The biochar is not re-encapsulated, however, and the alkaline pre-conditioning described above applies to it, so downcycled material is not equivalent to biochar that remains held within an intact matrix.
5. Landfill
Concrete is landfilled when it cannot be effectively used in another application through reuse, closed-loop recycling or downcycling. Landfilled concrete can be assumed to remain within a single storage location for long timescales, decreasing geographical uncertainty. However, additional reversal risks may be introduced (e.g. acidic groundwater) depending on regional environmental characteristics and regulations.
A report published by the National Asphalt Pavement Association in 20243036 found that 99% percent of reclaimed asphalt pavement (RAP) is recycled, with 93% percent reused in new asphalt pavements and the remaining percentageremainder used in other civil engineering projects, such as unbound aggregate bases. A small percentage, (reported at 0.2% reportedpercent in 2022) of RAP, is landfilled ifwhere it cannot be used in construction, for example if it contains hazardous materials.
InA additionpavement tois recyclingbuilt in layers. The surface course is the uppermost bound layer and landfillingis ofin asphaltdirect contact with vehicle tires. Beneath it sit the binder course, the base, and, where it is importantbituminous-bound, tothe notesubbase. thatThese somelower materiallayers are together defined in this Module as the Sub-Surface Layer.
Material is removed from roadthe surfacessurface duecourse toover time by abrasion caused by friction between tire treads and the pavement, generating tire wear particles (TWP) and road pavement wear particles (RPWP). The road abrasion rate is dependentdepends on several factors, including driving conditions and traffic volume, butand has been reported at 0.04-0.5 mm per year 3113. A recent study 3215 found that, for asphalt pavement, wear particle size distributions peaked at 63-106 μm, with 84% of the wear particles falling in the size range of 38-212 μm. ThisParticles introducesat uncertaintythat size are readily transported from the road surface by wind and water, so biochar co-abraded from the surface course disperses to the roadside environment and its subsequent location cannot be tracked.
Biochar placed in a Sub-Surface Layer is shielded from direct tire contact. It is liberated principally when the environmentlayer toitself whichis thesemilled particlesor willreclaimed, beat exposedrehabilitation or reconstruction, rather than progressively during service. This Module certifies biochar in Sub-Surface Layers only, as set out in Applicability.
Reversal in asphalt is assessed through the liberation and may potentially increase the risk of reversal (See Section 10.0). If biochar is used exclusively in sub-surface layers (e.g., binder or base courses), it is generally not exposed to direct mechanical wear and thus less susceptible to particle loss through abrasion. Project Proponents are recommended to specify the locationdispersal of biochar withinduring milling and recycling. This is a different approach from the pavement structure. However, it should be noted that the approach for assessing reversal will still be consistent with the approachone used for concrete, applicationsand (Seeboth are set out in SectionAppendix 10.0A: Reversal risk).
Biochar incorporated into a built material is not contained for the whole of its service life. Constituents may leach from the matrix into runoff, soil, and groundwater; biochar-bearing fines are released when the material is milled, crushed, or demolished; and workers are exposed to dust and fume at each point where the biochar and the biochar-amended material are handled, blended, and placed.
This Module does not set built-environment-specific numeric contaminant thresholds. A single numeric limit cannot distinguish a contained sub-surface placement from a crushed and downcycled one, and would not identify the exposure pathway that actually applies to a given Project. Instead, The Project Proponent must declare contaminant concentrations against the World Biochar Certificate material thresholds (Required measurements) and must separately assess and mitigate the exposure arising from The Project's biochar, placement, and end-of-life pathway.
The Project Proponent must specify in the Project Design Document (PDD) how contaminant levels will be monitored, including their potential impact on product quality and the surrounding environment, the specific contaminants to be tracked, and the frequency of testing. The monitoring plan must cover the contaminants declared under Required measurements and must be consistent with the Contaminant Exposure Risk Assessment. If material quality or groundwater are demonstrated or anticipated to be adversely affected, the Project Proponent must complete the following:
The Project Proponent must complete a contaminant exposure risk assessment and submit it in the PDD. The assessment must cover the heavy metals and organic contaminants declared under Required measurements, and must be completed for each combination of built material and placement for which Certificates are sought.
[/R-Q112-0]The assessment must apply a recognized published exposure assessment methodology and must name the methodology applied, so that the assessment is auditable by the VVB. The assessment must be updated and re-submitted when the feedstock, the production process, the mix design, or the placement changes, and at the renewal of each Crediting Period.
[/G-T517-0]The risk of environmental exposure assessment must address, at a minimum:
The occupational limb of the assessment must address inhalable and respirable dust, polycyclic aromatic hydrocarbons, and heavy metals across, at a minimum:
Exposure must be evaluated against the occupational exposure limit values in force in the jurisdiction of each activity, following EN 689:2018 or an equivalent national strategy for testing compliance with occupational exposure limit values.
[/G-1ERH-0]Where the assessment identifies an exposure risk, The Project Proponent must state in the PDD the mitigation applied, the party responsible for implementing it, and the evidence that it is in place. Mitigation may include a change to the biochar specification or feedstock, a change to the mix design or placement, engineering controls such as enclosure or extraction at the point of handling, or personal protective equipment. Certificates must not be issued for material for which the assessment identifies an exposure risk and no mitigation is evidenced.
[/G-N3M6-0]As outlined in the Biochar Production and Storage Protocol, there are some potential risks to environmental and human health associated with biochar composition, for example:
Project Proponents must include environmental legal and regulatory requirements applicable to their Project in the PDD. In the absence of regulation, the World Biochar Certificate guidelines must be met for storage of biochar in materials for:
a. 16 EPA PAH (declaration of concentration required)
b. PCB (0.2 mg kg⁻¹ DM)
c. PCDD/F (20 ng kg⁻¹)
Best practice for how to carry out measurements of these parameters is provided by the World Biochar Certificate3337, and shouldmust be followed by Project Proponents and outlined in full in the PDD.
Activities that were already occurring and would continue to occur without theThe Project may be omitted from the system boundary of the GHG accounting, if evidence that the activity was already occurring and would have continued to occur in the absence of the biochar storage activity can be provided.
Emissions associated with upstream and downstream activities associated with the biochar storage process may be omitted from the system boundary if the biochar-amended product meets the same performance requirements as a conventional product for the intended use case and does not require additional products or activities related to product manufacturing, installation, maintenance and end-of-life, as compared to conventional products. For asphalt, the conventional product is a mixture of the same production type (hot-, warm-, or cold-mix) for the same pavement layer.
Transport of biochar from the production facility to the point of incorporation, and any intermediate storage and handling of biochar before incorporation, are within the Project system boundary and must be accounted for in accordance with the Biochar Production and Storage Protocol. The exclusion described above applies only to activities associated with the manufacture, installation, maintenance, and end-CCP7of-0]
This is based on the assumption that emissions associated with biochar-amended product manufacturing, installation, maintenance and end-of-life would have occurred anyway had a different product been produced and used. The exception to this rule is that additional information is required for exclusion of transport emissions, including transport of biochar-amended built materials to the end-use site (defined as the final location where the biochar-amended product is installed or used). This is to negate the risk of induced transport associated with lower availability of novel biochar-amended products.
In order to exclude transport emissions from the system boundary, theThe Project Proponent must provide suitable justification that transport distances are expected to be within the bounds of national average transport distances for equivalent conventional materials.
Emissions associated with all activities and equipment related to biochar storage in the built environment must be fully accounted for within the Project system boundary. Project Proponents relying on this exclusion must confirm that it applies and provide supporting evidence in the PDD, as set out in Section 8.1.
The chemical analyses required to assess the reactivity and durability of biochar-C in different storage environments are given in Table 2.. Some of these measurements will be used in the quantification of CO2e stored, as outlined in Section 7.0 Quantification of CO₂e Stored. The required and recommended measurements listed below investigate multiple mechanisms of reactivity (or prevention of), including aromaticity and aromatic condensation, functional groups and volatility.
Specific analysis, including heavy metals and PAHs, should be conducted to assess the potential impact of biochar when used in building materials.
[/R-NYQT-0]Please note that this is not an exhaustive list of analytical methods for each property. If Project Proponents wish to use an alternative, appropriate method of analysis, they may justify its use in the PDD.
[/G-G275-0]Table 2: Requirements for physical characterization of biochar
Property | Threshold | Analytical Method | Description | Monitoring Frequency | Recommended or required? |
|---|---|---|---|---|---|
Total Carbon Content | Standard Test Methods for Determination of Carbon, Hydrogen and Nitrogen in Analysis Samples of Coal and Carbon in Analysis Samples of Coal and Coke ASTM D5373 or Standard Test Method for Determination of Carbon, Hydrogen and Nitrogen in Analysis of Solid Biofuels EN ISO 16948:2015 | The carbon content of applied biochar is necessary for the quantification of Corg and thus | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch. | Required | |
Inorganic Carbon Content ( | Standard Test Method for Rapid Determination of Carbonate Content of Soils ASTM D4373-02 or Testing of Solid Fuels - Determination of the Carbonate Carbon Dioxide Content DIN 51726:2004-06 | Measurement of inorganic carbon in biochar is required to accurately differentiate Corg from total carbon content, which may include both inorganic and organic forms. Only Corg is | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch. | Required | |
| Direct mass measurement with calibrated weigh scales | The carbon content of applied biochar is necessary for the quantification of CO2e stored, in accordance with Section 7.0. See the Biochar Production and Storage Protocol for carbon content sampling guidance. | Measure every storage batch | Required | |
Moisture Content | Standard Test Methods for Determination of Moisture Content in Analysis Samples of Wood Charcoal ASTM D1762-84 or Standard Test Method for Determination of Moisture Content in Analysis of Chemical and Physical Tests of Soil Improvers BS EN 13040:2007 | The moisture content of applied biochar is necessary for the quantification of CO2e stored, in accordance with the Biochar Production and Storage Protocol. Carbon content can be reported on a dry basis to account for differences in total biochar mass. | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch | Required | |
Random Reflectance ([math: R₀]) | White-light microscopy, eg ISO 7404-5:2009 | Random reflectance is an indicator of aromaticity, aromatic ring unit size and condensation. A R₀ value greater than 2% has been proposed as a benchmark for quantifying the permanent pool of carbon in a biochar. The R₀ frequency distribution histogram can be used to decide what fraction of biochar above this benchmark can be classified as chemically inert | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch | Required | |
Reactive Organic Carbon and Residual Organic Carbon ( | Thermogravimetric analysis e.g., Hawk, Rock-Eval® or equivalent. The sample is subjected to re-pyrolysis using a standardized heating procedure: it is first held isothermally at 300 | Measurement of reactive organic carbon in biochar is important because this fraction represents the more labile, easily degradable component of organic carbon. Elevated levels of ROC can reduce biochar’s long-term carbon stability, as it is more susceptible to microbial decomposition and mineralization in soil. Random reflectance values are subsequently only applied to the residual, stable fraction of biochar. | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 3 samples per storage batch | Required | |
Ash Content | Standard Test Method for the Determination of Ash Content in Solid Biofuels ISO 18122:2022 | Ash is the inorganic portion of biochar that will not volatilize even if combusted | Measure every production/storage batch as per the guidance in the Calculation of Cbiochar section of the Biochar Protocol. Minimum number of 1 samples per storage batch | Required | |
Polycyclic Aromatic Hydrocarbons PAHs, sum of USEPA 16 | Gas Chromatography coupled with Mass Spectrometry (GC-MS) and/or High Performance Liquid Chromatography analysis eg ISO 13859:2014 or BS EN 17503:2022 | Polycyclic aromatic hydrocarbons are organic molecules with fused aromatic rings that can be formed during the pyrolysis process and retained in the biochar. They are chemically stable with a high sorption capacity, known carcinogens and are persistent pollutants that can travel in the environment chain. | Measure at project validation unless feedstock, reactor or process parameters change. Minimum number of 1 sample | Required | |
Heavy metals including As, Cr, Cd, Co, Cu, Hg, Ni, Pb, Sb, Zn, V | Elements As, Cd, Cr, Cu, Ni, Pb, Zn refer to EN ISO 17294-2 ICP - MS standard test method for determination of selected elements. Element Hg refer to ISO 16772:2004 standard test method for the determination of Mercury using cold - vapor atomic absorption spectrometry. Elements Sb, Co, V refer to EN 15411:2011 standard test method for the determination of trace elements | Concentration of heavy metals in biochar is dependent on the feedstock and the process used | Measure at project validation unless feedstock, reactor or process parameters change. Minimum number of 1 sample | Required |
This section details the calculation of net CO2 storage in biochar-amended built materials. The monitoring requirements are describedset in detailout in Section 8.0 Monitoring Requirements.
Accurate quantification of net CO2 stored requires a robust quantification of associated projectProject emissions within the project boundary. In the context of this Module, a Project refers to the point of CO2 capture and the point of CO2 storage. This Module defines the point of CO2 storage as the point of incorporation of biochar into a built material. Note that thisThis Module applies only applies to biochar that is considereddurable for 200 years.
This horizon is shorter than the Isometric 1,000-year default and is specific to bebiochar durablein forbuilt materials. Over 1,000 years.
Projects are required to provide detailed descriptions of projectProject boundaries for all Creditingactivities activitiesassociated with certificate issuance. Project boundaries must include all areas where removal mechanisms/ and processes may occur, removed carbon storage locations/ and forms, and potential reversal/ and loss pathways.
The quantity of net CO2 removal for each Reporting Period,RP, can be calculated as follows:
[math: CO_2e_{Removal,\ RP} = CO_2e_{Stored,\ RP} - CO_2e_{Counterfactual,\ RP} - CO_2e_{Emissions,\ RP}]
(Equation 2)
Where:
[math:CO_CO_2e_{2estored,\text{Stored,RP}} = C_{\text{Biochar}biochar} \timescdot m_{\text{Biochar}biochar} \timescdot F_{\text{Durabledurable,Material}material} \timescdot \frac{44.01}{12.01}]
(Equation 32)
Where:
This Module only Credits forcertifies the durably stored organic carbon fraction of biochar, which is used to calculate [math: CO_2e_CO_2e_{StoredRemoval,RP}]. While biochar associated inorganic carbon generally makes up a small fraction of total biochar carbon. However, the fate of biochar-associated inorganic carbon is much less predictable. Thus, [math: C_{Biocharbiochar}] is calculated using the following equation:
[math: C_{\text{biochar}} = \text{Total Carbon Content} - C_{\text{inorg}}]
(Equation 43)
Where:
Please refer to Section 8.3.1 of the Biochar Production and Storage Protocol for full guidelines on number of samples required for the measurement of biochar carbon content, [math: C_{biochar}].
SeePlease refer to theSection relevant section8.4 of the Biochar Production and Storage Protocol for full guidelines on measurement of mass of biochar buriedapplied, [math: m_{Biocharbiochar}].
[math: F_{Durable, Materialdurable}] is calculatedthe fraction of the incorporated biochar certified as durably stored over the 200-year horizon. This Module certifies the inertinite (recalcitrant) fraction of the biochar only, quantified by random reflectance and thermogravimetric analysis ([math: F_{durable}]).
[math: F_{Durabledurable,Materialmaterial} =F_{Inertinite}(1+-[1-(3U) \timescdot F_{Reversal})] F_{Labiledurable}]
(Equation 54)
Where:
The quantificationdurable frameworkfraction is quantified by the random-reflectance inertinite method, following Sanei et al. (2024)1 for determining the [math: CO_2e_{Stored}R_0]inertinite forbenchmark, 1000-year durability is based on the quantification approach set outrefined by Sanei et al,. (20242025)8112 Thistto approachaccount quantifiesfor biochar ononly the randomrecalcitrant reflectancefraction, value ofwith the biochar,reactive comparedfraction todiscounted inertinitevia asthermogravimetric aanalysis. proxyThe only difference from that Module is the horizon label (200 years for geologicallybuilt stable carbon. Using petrographic analysis, Sanei et al., (2024materials)8 identified that biochars with a mean random reflectance (R₀ ≥ 2%) exhibit structural characteristics equivalent to inertinite macerals in fossil coals and chars,the whichdownstream arereversal knowndiscount to[math: persistU] over(Equation geological timescales4).
As outlined in Section 6.0 of this Module, Project Proponents must report a set of at least 500 measurements of [math: R_0]R0, calculated at the maceral-level, for eachat sampleleast three replicate samples of their biochar. Batches that adopt this measurement approach can be credited, for the fractionpercentage of their biochar which passes the 2% [math: R_0]R0 benchmark, as outlined in Sanei et al. (2024)81 . The histogram of the [math: R_0]R0 values must be submitted at the point of project verification for this Crediting option. This method was further updated in Sanei et al., (in submission2025)382 to refine the methodology to only account for the recalcitrant fraction of biochar (discounting the reactive fraction, determined by thermogravimetric analysis).
To ensure a conservative approach when Creditingissuing certificates against biochar durability, we account for uncertainty in both [math:the R_0]fraction measurement,of biochar passing the 2% R₀ benchmark and the proportion of carbon that is non-reactive. Specifically, for each replicate sample we determine the credited durable fraction ([math:of F_{Durable}])R₀ measurements that meet or exceed the 2% benchmark. The certified inertinite fraction is calculated using the mean valuesof forthese eachfractions parameteracross all samples analyzed, reduced by one standard deviation of the fractions (Equation 5). This methodis applied to the non-reactive carbon fraction, itself reduced by one standard deviation (Equation 6), to give the durable fraction of the biochar (Equation 7). This ensures that the durability estimate reflects a lower-bound confidence level, mitigating the risk of overestimating long-term carbon storage.
As such, [math: F_{Durabledurable}] is calculated through:
Calculating the sample standard deviation of [math: R_0] quantifying the typical deviation of individual [math: R_0] measurements from their mean, which is used to account for uncertainty and conservatively adjust the estimated durable fraction of biochar carbon, as:
[math:F_{\text{inertinite}} = \left( \overlines_{R_0}-= \sqrt{\frac{1}{n_{R_0}-1}\sum_{i=1}^{n_{R_0}}\left(R_{0,i} - \overlinebar{R_0}\right)^2}]
(Equation 5)
Where:
Calculating the sample standard deviation of [math: C_{non-reactive}] quantifying the typical deviation of individual [math: C_{non-reactive}] measurements from their mean, which is used to account for uncertainty and conservatively adjust the estimated durable fraction of biochar carbon, as:
[math: s_{C_{\text{non-reactive}}}-= \sqrt{\frac{1}{n_Cn_{C_{non-reactive}}-1}\sum_{i=1}^{n_Cn_{C_{non-reactive}}} \left(C_{\text{non-reactive},i} - \overlinebar{C_C}_{\text{non-reactive}}}\right)^2}\right)]
(Equation 6)
Where:
Quantification of biochar storage for Crediting in the built environment will be updated in future versions of this Module in line with the best available science as more research in peer-reviewed literature is published.
This Module distinguishes between [math: F_{Reversal}] for biochar stored in concrete and biochar stored in asphalt. Note that [math: F_{Reversal}] for biochar stored in asphalt is assumed to be 100%, and thus the labile fraction is not included in calculation of [math: F_{Durable, Material}].
[math: F_{Reversal}] in concrete is determined through a geochemical model that assesses the weathering of a given built material over 1,000 years. An overview of the geochemical model used for this assessment and key assumptions underlying this model are given in Section 10.0.
The default value, based on a worst-case assessment (described in Section 10.0), is 2%. Project Proponents may choose to submit additional documentation to conduct a project-specific reversal assessment. As shown in Equation 5, a safety factor of 3 is applied to [math: F_{Reversal}] to ensure a conservative estimate. This approach, and the safety factor applied, will be reassessed as scientific consensus evolves.
[math: F_{Labile}] is defined as the portion of biochar that is not considered inertinite (e.g. does not pass the 2% [math: R_0] threshold). It is calculated asThen:
[math: F_{Labiledurable} =\frac{m_{Biocharmin(0.95 ,totalmax( 0 , (\bar{R_0} -m_s_{Biochar,R_0})inertinite(\bar{C}_{\text{non-reactive}} − s_{m_C_{Biochar, totalnon-reactive}}) ) ) )]
(Equation 7)
Where:
The maximum and minimum functions are applied to ensure that the fractions are bounded.
[math: U] is the project-specific durability discount for physical liberation and dispersal of the certified durable carbon through wear, comminution, and recycling over the 200-year horizon. It does not re-discount the labile fraction (which is not certified), the one-standard-deviation conservatism already contained within [math: F_{durable}], or acid and matrix dissolution: acid dissolves the host matrix and can expose biochar, but does not mineralize the inertinite fraction, which is the same basis on which the inertinite fraction is treated as permanent in the Biochar Storage in Low Oxygen Burial Environments Module.
[math: U] is determined per Project, and per distinct placement or mix design where a Project spans several, by the reversal risk questionnaire in Appendix A. The questionnaire scores placement and incorporation, physical exposure, and end-of-life and recycling factors, applies gating exclusions, and maps the net score to a durability discount band.
The Project Proponent must complete the reversal risk questionnaire (Appendix A) for each placement or mix design, record the supporting evidence for each response in the PDD, and apply the resulting durability discount [math: U]. Where a new storage site is added to the Project after validation, such as a new plant at which biochar is incorporated or a new asset, placement, or region in which the biochar-amended mixedmaterial intois concreteused, the questionnaire must be completed for that site, before Certificates are issued for biochar stored there. The questionnaire must be re-completed at the renewal of each Crediting Period or on material change. A Project that does not complete the questionnaire, or that leaves a variable uncharacterized, receives the worst-case (Very High) discount for that variable.
For biochar production, the calculation of [math: CO_2e_{Counterfactual,\ RP}] is determined by the requirements laid out in the Counterfactuals sectionSection of the Biomass Feedstock Accounting Module.
[math: CO_2e_{Emissions,\ RP}] is the total greenhouse gas emissions associated with a given Reporting Period, RP.
Equations and emissions calculation requirements for [math: CO_2e_{Emissions,\ RP}] including emissions associated with reactor operations and reaction monitoring, are set out in the relevant Protocol and are not included in this Module. Specific considerations for CO2 stored as biochar in built materials are set out here.
CO2 removals must not be double counted, regardless of the production of product Environmental Product Declarations.. The product must still comply with all relevant emission accounting regulations and requirements, which may mean emissions are double counted,; however, removals must not be double counted. This is the most conservative approach to take. CreditingCertificate issuance claims must be transparently reported and must not form part of marketing for a separate product.
Allocation procedures may be undertaken to separate emissions associated with the concrete production and the emissions associated with the CO2 storage process. Allocation procedures must follow the following emissions allocation procedure:
Transport emissions must be considered if the average transport distance for biochar-amended built materials is more than the average transport distance of normal products produced by the production facility. All other downstream emissions may be excluded from the system boundary if these activities were already occurring and would continue to occur in the absence of theThe Project. This can be evidenced by providing documentation that the biochar-amended product meets the same performance requirements of a conventional product for the intended use case, as is described under 'the Section 2.0 Applicability'.
As outlined in the Risk of Reversal section of the Isometric Standard, the Buffer Pool is a mechanism used to insure against Reversal risks that may be observable and attributable to a particular project through monitoring. Based on present understanding, reversals in Biochar storage will not be directly observable with measurements and attributable to a particular project. Projects Crediting againstusing this Storage Module are Creditedtypically conservativelydeemed to accounthave forNo degradationObservable Risk of labile pools of biochar within the relevant Crediting time horizon. Projects applicable to this Module are categorized as having a Very Low Risk Level of Reversalreversal, according to the Isometric Standard Risk Assessment Questionnaire (also found in the relevant Protocol), as all reversal risk is accounted for using the reversal risk modelling and Uncertainty Discount approach. TheThis Bufferresults Poolin correspondinga to0% buffer pool for Projects using this lowestStorage Module. This reversal risk scorewill isbe 2%reassessed at the renewal of the Crediting Period, or when new scientific research and isknowledge intendedare as an additional precaution against unknownsproduced.
ThisThe requirements in this section outlinesapply to the monitoringprocess requirementssteps and equipment within the Project system boundary. Where the exclusion of downstream manufacturing emissions set out in the System Boundaries section is relied upon, the boundary terminates at the point at which biochar or a biochar-containing material transfers to the downstream manufacturer, and process data for Projectsthe incorporatingmanufacturer's own operations is not required. Requirements relating to the mass of biochar incorporated, the mix into which it was incorporated, and the pavement layer in buildingwhich materialsit eitherwas aslaid aapply filler,irrespective aggregate,of modifierthat or other formexclusion.
Project Proponents are required to provide detailed information on the end material production process in the PDD. This must include:
Process specific details, including energy consumption, curing steps and processing temperatures, are required only where the exclusion of downstream manufacturing emissions set out in the System Boundaries section is not relied upon. Where the biochar-amended product meets the same performance requirements as a conventional product for the intended use case and requires no additional products or activities related to product manufacturing, installation, maintenance and end-of-life, those emissions are omitted from the system boundary and the underlying process data is not required.
Project Proponents relying on the exclusion must instead evidence that it applies. The evidence must address both conditions of the exclusion, because equivalent product performance does not by itself show that processing is unchanged:
Where either condition cannot be evidenced, the exclusion does not apply and the process data set out below is required.
[/G-8RFV-0]Where the exclusion is not relied upon, Project Proponents must provide, for each additional or modified process step, the energy consumption, processing temperature and curing regime, together with the emissions allocation procedure applied under the Quantification of CO2e Stored section. Where sub-process energy cannot be metered separately, Procedure 1 (Section 7.2.3) must be applied and all process emissions allocated to the removal.
[/G-JAHE-0]Irrespective of whether the exclusion is relied upon, Project Proponents must state the maximum temperature to which the biochar is exposed during production of the final material. Where this exceeds 200°C, the release of volatile organic compounds and PAHs must be addressed in the contaminant exposure risk assessment required under the Environmental and Social Safeguards section.
[/G-5ZD3-0]To verify incorporation of biochar into the final product, Project Proponents must provide documentation in the PDD inthat oneestablishes both the mass of biochar incorporated and the threemix into which it was incorporated. Acceptable forms include:
IfProduction batch records must identify the biochar-basedissuing productfacility, isthe soldbatching system from which they are extracted and the date of extraction, must cover the full Reporting Period, and must reconcile to multiplethe downstreamProject manufacturersProponent's records of biochar dispatched to that facility. For asphalt, the documentation provided must identify the mix designation (e.g., concreteEN producers13108 withor differentSuperpave) mixfor designs)each batch, Projectso Proponentsthat maythe providepavement layer can be established as required under the Asphalt Layer Eligibility section.
Only biochar shown to have been incorporated into the built material, by the documentation set out above, is certified. Biochar dispatched to a representativefacility rangebut ofnot useincorporated, casesincluding biochar lost in transport, storage, or handling, must not be certified, and typicallosses incorporationmust rates,be alongrecorded withand supportingdeducted documentation.as Inset such cases, justification for the assumed biochar contentout in the finalBiochar constructionProduction materialand Storage Protocol. Biochar stored before incorporation, at the incorporating plant or at any intermediate location, must be clearlyheld statedin enclosed silos or containers or in covered stockpiles, protected from wind and surface water, sited away from drains and watercourses, and conservativemanaged assumptionsto prevent self-heating. The Project Proponent must describe these storage and handling arrangements in the PDD.
Where biochar is added to an asphalt mixture as a separate component rather than through the binder, the Project Proponent must state the point at which it is added in the plant (for example, directly to a batch-plant mixer, or through an additive or filler feed on a drum plant).
Where production batch records are not available, mix-level evidence may be usedprovided instead to establish placement: for asphalt, a job mix formula that identifies the biochar and its dosage and restricts it to a mix designated for a Sub-Surface Layer; for concrete, an element and mix specification that ties the biochar-amended mix to its placement. The mass of biochar incorporated must still be established by one of the forms listed above. Placement evidenced in this way is scored under the mix-level response to question A3 of the reversal risk questionnaire (Appendix A).
An engineering designflow diagram of the process steps and equipment usedwithin the project boundary, up to transfer to the downstream manufacturer (including any dosing or feed system installed there, and modified steps at the manufacturer where the emissions exclusion is not relied upon).]
A process flow diagram covering the process steps and equipment within the Project system boundary must be included in the PDD. The designdiagram must cover the equipment the Project Proponent operates or contracts, including any dosing or feed system installed at the downstream manufacturer's facility, and must terminate at the point at which the material transfers to the downstream manufacturer. Where the exclusion of downstream manufacturing emissions set out in the System Boundaries section is not relied upon, the diagram must include:also cover the additional or modified process steps at the manufacturer's facility.
The process flow diagram must be prepared to ISO 10628 or an equivalent convention, and must show:
Project Proponents must also provide an equipment list stating, for each item of equipment within the boundary, its function, make and model or asset identifier, and rated throughput capacity.
Process detailssteps should include acceptable processes including, but not limited to:
Characterization of biochar and ongoing monitoring requirements are outlined in Section 6.0 and must be included in the PDD for validation and subsequently submitted for verification adhering to the sampling frequency requirements.
ThoughThe Project Proponent must state in the PDD a best estimate of the expected service life of the built element and, for asphalt, of the biochar-bearing layer, including the expected resurfacing, rehabilitation, or reconstruction interval, with its basis. The estimate is not a commitment. Its basis may be the applicable design standard or the published maintenance policy of the road authority or asset owner for the application type and region; asset-specific records are not required.
Where the application or expected service life is not known, for example because the biochar-amended material is supplied by a third-party producer to unspecified end uses, the Project Proponent must state this, and the worst-case responses to questions C1 and C2 of the reversal risk questionnaire (Appendix A) apply, together with the default comminution interval in Table A6.
[/G-D94D-0]Further site information can help demonstrate reduced risk of carbon loss if certain thresholds are met and highlight portions of the material stream that may require additional assessment. Where site information is used to support a response to the reversal risk questionnaire other than the worst option, its basis must be stated in the PDD. This may include:
For asphalt applications:
For concrete applications:
An applicability criteriacriterion for Creditingcertification with this Module is that the biochar-amended built materials must meet the same performance requirements as conventional products for the intended use case.
Project Proponents are required to demonstrate compliance with the relevant standards for the use case of each mix produced, while also demonstrating the product is comparable to traditional products and results in no additional product use. It is the responsibility of theThe Project Proponent to clearly demonstrate comparability between produced products and traditional products within the PDD submitted to theThe Project VVB and Isometric. Standards, methodologies and SOP'sSOPs that are utilized by a Project Proponent must be clearly outlined and referenced in the PDD upon submission, and deviations from standards must be highlighted.
Built materials produced for the purpose of carbon storage and CreditCertificate issuanceissuances are expected to meet the required performance standards and criteria for the intended application, as defined by applicable codes or regulations. These materials shouldmust be demonstrably fit for purpose and comparable in functional performance to traditional products that would have been used in the absence of the biochar-amended material. This may be achieved through the undertaking of standardized performance testing procedures required in the location the material is utilized. In the absence of local or regional standards related to production and performance criteria, a Project Proponent is required to adhere to International Organization for Standardization (ISO) and/or CEN (the European Committee for Standardization) criteria. The final product should be compliant with relevant product standards such as EN 15804 for Environmental Product Declaration in the construction industry, relevant product classes and quality standards that are applicable.
Evidence and data, resulting from research studies of biochar addition in built materials such as asphalt, cement or other building elements, have shown the potential for additional benefits and improvements on the final product quality 49,3941,4042. Biochar addition can impact a range of different properties (mechanical, chemical and physical properties) including but not limited to the following:
Project Proponents should include any additional product characterization, analysis and reported properties of the final produced materials. Changes or deviations from the baseline product values should also be included and relevant product standards referenced in the PDD Appendix.
Departures from standard may be permissible on a case-by-case basis. Project Proponents seeking a departure from standard must submit documentation on the requested departure and proof of approval by the relevant regulatory body to Isometric and the VVB.
AThis keyModule certifies biochar in built materials over a 200-year durability horizon, rather than the Isometric 1,000-year default. The grounds are set out in full in Section 1.0 and summarized here. They are specific to biochar rather than general to built materials. Containment over 1,000 years is neither guaranteed nor observable for this pathway, because the fate of the material through demolition, recycling, and end-of-life reprocessing across that span is extrapolated rather than documented. For cementitious materials, a further consideration forapplies. Biochar is exposed to the durabilitypore solution of CO2a storedcementitious inmatrix during encapsulation, typically at pH 12.5 to 13.53, which alters its structure, including pore enlargement and matrix defectiveness4. While the builtmaterial environmentremains intact this is not onlyitself a carbon-loss pathway, because there is no oxygen, no export route, and the condensed inertinite core is chemically resistant1. Altered and aged carbon is, however, more susceptible to oxidation5, so the exposure may leave the biochar more vulnerable to conditionsdegradation once the material is broken up and the carbon is exposed to the open environment. This consideration does not apply to asphalt, in which biocharthe durabilitybinder is likelya hydrophobic bituminous matrix rather than an alkaline aqueous environment; for asphalt, the horizon rests solely on the extent to which the fate of the material can be negativelydocumented. impactedThe 200-year horizon corresponds approximately to the design life of a built asset, butindicatively also50 years for common buildings and 100 years for monumental structures and bridges under EN 1990:2023, plus first reuse.
A second consideration is the uncertainty in the location of the productmaterial at any given time. As described inwith the relevant section of the CO2 Storage via Carbonation in the Built Environment Module, a built material may gopass through many different use cases inacross its life cycle, depending on the initial use case, local regulatory requirements, and economic incentives. In the traditional construction industry, there has not been ano need to track built materials past the life cycle of an asset, particularly where elements are designed to perform with minimal maintenance or intervention. Thus, biocharBiochar-amended built materials are therefore likely to transition through several construction-demolition-reuse cycles with minimal ability to track these changes. Over longthe time200-year periods (e.g. 1,000 years),horizon this leads to a high degree of uncertainty in both the storage location of the productmaterial and, consequently, whether or not the productit is exposed to conditions that lead to degradationloss of the biocharcertified carbon. This treats built-environment storage as an open system and necessitates athe conservative, project-specific approach to reversal risk,set describedout in the following sectionbelow.
TheThis labileModule certifies inertinite (recalcitrant) fraction of the biochar only (Equation 7). That fraction is subjectdurable over geological timescales once formed1 and is refined to degradationthe overthermally anon-reactive longerresidual periodby thermogravimetric analysis2. It is chemically resistant while it remains encapsulated in the host matrix, and while it remains in contained chunks after the matrix is broken up. The reversal concern is therefore not chemical mineralization of timeencapsulated duecarbon, but physical liberation of the certified inertinite to differentmobile degradationfines that are dispersed into the open environment. Once dispersed, the location and fate of the fines cannot be verified, and they are exposed to pathways that arecan applicablereturn the carbon to the physicalatmosphere, including oxidation of fine, high-surface-area and aged material5 and thermal destruction where sewage sludge, road runoff solids, or sweepings are incinerated. Consistent with the conservative approach this Module takes to a novel storage locationpathway, carbon is certified only where its retention can be quantified and verified, and certified carbon liberated to mobile fines is therefore treated as not retained. TheseThis treatment is adopted because the retention of dispersed fines cannot be demonstrated; it is not a finding that dispersed inertinite degrades in every receiving environment. Isometric will revisit it if evidence on the fate of dispersed biochar fines becomes available. Liberation happens through wear, comminution, and recycling. The pathways canthat act on liberated, dispersed material include:
EachTwo related mechanisms are handled outside this dispersal term. Acid and matrix dissolution can expose biochar as the host matrix is lost, but does not mineralize the inertinite fraction, so it is treated as an exposure driver in the questionnaire (Section B), not a carbon-loss term. Thermal exposure during hot asphalt recycling (approximately 150 to 190°C) is highly unlikey to reverse the certified fraction, because that fraction is by construction the thermally non-reactive residual determined by thermogravimetric analysis (Equation 7), which is stable well above that range: road-grade biochar loses only about 1% of theseits pathwaysmass to 150°C and about 5% to 400°C46, and oxidation onset rises with pyrolysis temperature, well above the hot-mix range47. High-temperature reprocessing of concrete to clinker (approximately 1,400°C, the calcination temperature described in the Concrete background) destroys even the inertinite, and is directlyhandled influencedas bya thegating storage environment, with the relevant site characteristics influencing which degradation pathways may be most prevalent in that storage environment. The durability of biochar is dependent not only on the storage site conditions but on biochar's physical and chemical propertiesexclusion (see Section 6.0 for more informationbelow).
Quantifying the risk of reversal associated with biochar-amended concrete is inherently complex, given the high degree of uncertainty and variability in possible end-states of the concrete over 1,000 years. Degradation of the labile fractionLiberation of biochar withinfrom concrete can occur when biochar particles become exposed, which may occuroccurs when the concretematerial is inlost aor 'broken up, either during use case'or (e.g.at as partend of alife. building)During use, or when the concreterelevant goesdrivers throughare an end-of-life transition (e.g. recycled). This is the result of processes such as concretesurface loss by physical or chemical weathering, demolition of a built asset or other processes that expose additional surface area of the concrete. In most scenarios, physical loss of concrete is likely to be the most prevalent loss pathway, leading toincluding exposure of embedded biochar. This may occur under the following scenarios:
During use:
DuringThe end-of-life processespathways and their reversal treatment are set out in the Section 3.2.3.2.1 End-State Use Cases (Concrete) background and summarized here:
Noteagainst thatthermal theclosed-loop likelihood ofrecycling.]Thermal closed-loop recycling occurring,to whileclinker: potentiallyreprocessing resultingat incalcination sometemperatures degradation ofdestroys the labilecertified fractioninertinite. ofThis biochar,pathway is currentlya extremelygating lowexclusion due to the nascency of the technology. At the time of drafting, there are(G3): a limitedProject numberwith a credible, unconstrained likelihood of pilot projects operating at small scale, including in the United Kingdom, France and Canada. As closed-loop recycling is not currently operating at scale, it has been excluded from the calculation of reversal risk at this time. However, it is importantineligible tounless notea that closed-loop recyclingbinding, ifevidenced includedrestriction against it is in place. [/G-B0T4-0]
[Image: Figure A1 concrete stage]
Figure A1: Sensitivity of the likelihood of closed-loop recycling on the amount of CO2 emitted to the atmosphere from closed-loop recycling over 1,000 years. The likelihood of closed-loop recycling was varied from 0 to 100%, while the likelihood of downcycling was decreased accordingly.
AsOnly discussedbiochar in a Sub-Surface Layer is eligible for certification under this Module; biochar in the surface course, and in bituminous surface treatments, is an ineligible practice, as set out in the Section 3.2.30.2.2 Surface-course material abrades directly under tire contact, generating tire and road pavement wear particles at a size (peaking at 63 to 106 μm)15 asphaltthat is abraded over time due to friction between tire treads and the pavement surface. Abraded particles fall within a dust-sized particle size distribution, and thus these particles can be easilyreadily transported away from the road surface by wind orand water. ThisThe leadsabraded fraction cannot be quantified or verified for an individual pavement, and its subsequent location and fate cannot be determined (see Asphalt Layer Eligibility). For eligible Sub-Surface placements, the reversal concern is the biochar comminuted to uncertaintymobile infines during milling and recycling over the finalhorizon, locationwhich ofis quantified through the abradedquestionnaire particles, as well asand the interactionsUncertainty betweenDiscount the([math: environmentU]) andderivation co-abraded biocharbelow. Equally, exposureExposure to chemicals such as chlorides (from road salt) and sulphatessulfates (from surface water) may leadincrease tothe destabilisationreactivity of thedispersed biochar structure and increased reactivity. Conservatively constraining the amount of biochar that is abraded and subject to degradation is a critical step in reliably determining the amount of carbon that is durably stored in biochar-amended asphaltmaterial.
Reversal Concrete
Dueis toassessed limitedfor dataeach onProject the incidence of high-temperature structure fires, the reversal risk presented in this section focuses on reversal through contact with low-pH fluids. Numerical Modelling was adopted asusing a method for evaluating the associated reversal risksquestionnaire. The modelnet willscore be revisited as more data becomes available.
To refine the assumption of reversal duemaps to acidic exposure, a geochemicalbanded modeldurability that simulates CO2 loss from concrete due to long-term acid exposure was developed using PHREEQC (version 3)discount, an open-source program for simulating chemical reactions and transport processes. This model quantifies the extent of degradation in biochar-based concrete over a 1,000-year period due to dissolution of concrete in acidic environments, both naturally occurring (e.g., acid rain, acidic groundwater) and industrially impacted (e.g., acid mine drainage)—across a pH range from 7 to 0.1, and subsequent exposure of the labile biochar fraction to atmospheric conditions.
The geochemical model incorporates equilibrium and kinetic interactions between aqueous solutions and cement phases using the Cemdata18 database: a chemical thermodynamic database for hydrated Portland cement and alkali-activated materials. Key model parameters, data input are sourced from literature studies include: cement composition44,45, reactive surface area (grain size)46,47, reaction constant of specific mineral phases48,49,50,51 and acid concentration52,53.
The geochemical model assumes no carbonation happened within concrete in advance. The Total Inorganic Carbon (TIC[math: U]) content before acid weathering is recorded and used as baseline comparison with remaining TIC after interaction with various acidic fluids. This model considers acid rain, acidic groundwater, acid mine drainage, and an extreme pH scenario, represented by varying the amount of sulfuric acid in the model conditions. Sensitivity analysis was performed on scenarios where reactive surface area and temperature varied from low to high. The remaining TIC reported for different scenarios is based on consumption of the initial material, with the reaction reaching equilibrium at the last step of the model. This allows for the computation and comparison of the worst case scenario (pH 0.1, high reactive surface area, room temperature). ThisEach scenarioband's resulted in approximately 2% lossvalue of the initial concrete material. In some less aggressive conditions (e.g., groundwater at pH 7), the loss was as low as less than 0.001%.
Taking the result of this reversal risk model, some simplifying assumptions can be used to conservatively estimate the portion of biochar that will degrade over 1000 years. These assumptions include:
Using this framework, it can be assumed that 2% of concrete loss by mass over 1000 years correlates with 2% of biochar by mass that will be exposed to conditions that may lead to degradation of the labile fraction. Thus, to account for this uncertainty, the percentage of the labile fraction that is associated with the 2% of the exposed biochar surfaces will be discounted from [math: CO_{2e_{Stored}}U] is derived from a comminution and dispersal model of how the certified inertinite is physically liberated over the horizon, set out under Derivation of the Durability Discount below.
Reversal risk is assessed on a project-by-project basis. The Project Proponent must complete the questionnaire for each Project, for each distinct placement or mix design where a Project spans several, and for each new storage site added to the Project after validation (see Calculation of Uncertainty Discount,[math: U]). Because built-environment storage is largely unobservable over the horizon, the output is a durability uncertainty discount on the certified durable fraction ([math: U] applied in Equation 4), instead of a buffer-pool contribution. This assessment is alsoconservative givenby adefault: safetyany factor of 3, as described in Section 7.2.1.3, to account for concrete degradation pathways that arevariable not consideredcharacterized withinwith verifiable evidence is scored at its worst option, and gating answers override the geochemicaltotal modeland but maycan result in biocharineligibility exposure,of suchthe as crushing during demolitionProject.
Note that Projects may choose to provide documentationdocumentations specific to the region of operations to calculate a Project-specific reversal risk. This documentation may include, but is not limited to:
ToTable conservativelyA1: estimateGating Criteria.
Ref | Gating question | If yes |
|---|---|---|
G1 | Is the | Ineligible |
G2 | Can the Project provide layer-constraining product evidence (job mix formula or EN 13108 / Superpave designation for asphalt; element and mix specification for concrete) tying the biochar mass to its placement, as set out in Incorporation and Placement Evidence? | If no, score the volume at the worst option in every question |
G3 | Concrete: is there a credible, unconstrained likelihood of closed-loop reprocessing to clinker (approximately 1,400°C, destroying even the inertinite), with no binding restriction against it? | Ineligible or Very High unless mitigated by D1 |
Table A2: Section A (placement and incorporation).
Ref | Factor | Response option | Points |
|---|---|---|---|
A1 | Placement within the built element | Asphalt, Sub-Surface base course | 0 |
Asphalt, binder or intermediate course | 2 | ||
Asphalt, surface course | Not eligible | ||
Concrete, thick structural or foundation | 0 | ||
Concrete, above-ground building element | 2 | ||
Concrete, thin element (brick, facade panel, paving, tile) | 4 | ||
A2 | Incorporation route (degree of encapsulation) | Fully encapsulated (asphalt: binder modifier, or filler-sized biochar in the mastic; concrete: cementitious matrix, filler, or SCM) | 0 |
Aggregate substitute | 2 | ||
Coarse or functional-layer incorporation (exposed) | 3 | ||
A3 | Placement evidence quality | Production batch records stating the mix designation or element and mix specification, reconciled to biochar dispatched (Incorporation and Placement Evidence) | 0 |
Mix-level evidence only (a job mix formula or element and mix specification that restricts the biochar to a stated placement), without per-batch records | 2 | ||
Buyer attestation only, or none (triggers G2) | worst-case |
For asphalt, the fully encapsulated response to A2 applies where the biochar is abradedincorporated frominto asphaltthe overmastic, 1000either:
Using these assumptions, it is possible(70 to calculate100% passing the amount0.063 ofmm biocharsieve) thator isASTM lostD242/D242M per- year19 and,(70 consequently,to 100% passing the percentage0.075 ofmm the labile fraction that will degrade per year. As shown in Figure A2sieve), theseevidenced calculationsby demonstrateparticle thatsize 100%distribution testing of the biochar containedas delivered to the plant for each storage batch.
In both cases, the job mix formula or mix design for the final mixture must identify the biochar and its function in the originalmixture. blockBiochar added as a separate component that is coarser than filler grading, or for which filler grading is not evidenced, is scored as an aggregate substitute.
Table A3: Section B (physical exposure over the horizon).
Ref | Factor | Response option | Points |
|---|---|---|---|
B1 | Abrasion or surface-wear exposure (asphalt) | Not surface-exposed (Sub-Surface) | 0 |
Low-volume road or light traffic | 2 | ||
High-traffic highway | 4 | ||
B2 | Chemical exposure (concrete EN 206 class; asphalt de-icing) | Mild (for example XC1, dry or sheltered) | 0 |
Moderate | 1 | ||
Aggressive (XA, XS, XF; low-pH groundwater or acid rain) | 3 | ||
B3 | High-temperature or fire event exposure (asset type and region) | Low | 0 |
Moderate | 1 | ||
High | 2 |
Table A4: Section C (end-of-life and recycling).
Ref | Factor | Response option | Points |
|---|---|---|---|
C1 | Service life before the first end-of-life event (for asphalt, the first event that mills, reclaims, or removes the biochar-bearing layer) | Long (greater than 50 years) | 0 |
Medium (25 to 50 years) | 1 | ||
Short (less than 25 years) | 3 | ||
C2 | Recycling or reprocessing cycles within the horizon (for asphalt, events that mill or reclaim the biochar-bearing layer) | 0 to 1 | 0 |
2 to 5 | 2 | ||
More than 5 | 4 | ||
C3 | Dominant regional end-of-life pathway | Contained (in-situ or ex-situ reuse; downcycle to aggregate or base; engineered landfill) | 0 |
Recycling into new bound material, hot, warm, or cold (comminution, re-lay) | 2 | ||
Closed-loop reprocessing to clinker or other high-temperature destruction | Gating G3 / Very High | ||
Unknown | 4 | ||
C4 | Regional recycling rate and policy trajectory | Low and stable | 0 |
Moderate | 1 | ||
High, or rising toward high-temperature reprocessing | 3 |
For asphalt, C1 and C2 are answered for the biochar-bearing layer. C1 is the expected time until that layer is first milled, removed, or reprocessed. C2 is the number of asphaltsuch is abradedevents within 90the yearshorizon, and thusmust webe assumeconsistent thatwith 100%[math: N] as determined under Derivation of the labileDurability fractionDiscount degradesU. withinWhere a layer-specific interval is not evidenced, C1 and C2 are answered on the resurfacing interval.
For C3, engineered landfill means disposal at a landfill operated under a permit issued under the applicable waste regulation for the class of waste concerned (for example, Council Directive 1999/31/EC on the landfill of waste, or equivalent national regulation), with the basal barrier, leachate controls, and capping required for that timelandfill frameclass, and with records of the waste accepted. TheDisposal calculationsat shownunpermitted insites Figureor A2open assumedumps, or use as unregulated fill, is not engineered landfill and is scored as Unknown. To score C3 as contained on the basis of landfill, the Project Proponent must evidence, from national or regional waste statistics, that thelandfill labileat fractionsuch facilities is 5%the perdominant massend-of-life ofpathway biochar;for importantly,the because a key assumption is that biochar particles are evenly distributedmaterial in the pavementregion, and must identify the lossregulatory percentagesregime under which those facilities operate.
Table A5: Section D (containment safeguards and mitigants). Subtract from the Section A to C total.
Ref | Mitigation | Response | Points |
|---|---|---|---|
D1 | Binding end-use restriction (for example Sub-Surface only; no closed-loop clinker recycling), enforced by design or contract and evidenced | Yes | −3 |
No | 0 | ||
D2 | Regional regulatory or practical constraint preventing the high-risk pathway | Yes | −2 |
No | 0 | ||
D3 | Asset-level tracking: the biochar-amended material is recorded in the asset owner's asset or pavement management register, identifying its location, element or layer, and biochar content, and the asset owner has agreed in writing to notify the Project Proponent of works that will mill, remove, or demolish it during the Crediting Period | Yes | −1 |
No | 0 |
Completion of the questionnaire for each new storage site added to the Project, and its re-completion at each Crediting Period renewal or on material change, are required of all Projects (Calculation of Uncertainty Discount,[math: U]) and do not changescore withunder Section D. Where D3 is claimed, the biocharregister concentrationentry or withand the labileasset fraction.
[Image:owner's Figureagreement A2must biocharbe loss]
Figureprovided A2in Percentagethe of biochar lost over time from a 1 m3 block of asphaltPDD, assumingworks annotified abrasionunder ratethe ofagreement 0.5must mm/yearbe reported at the next Verification, and anotified biocharworks contenttrigger of 5% by mass.
Because these calculations demonstrate complete lossre-completion of the labilequestionnaire.
Scoring. fractionSum ofSections biochar-amendedA asphaltto within 100 yearsC, 100%then subtract Section D to give the net score. Map the net score to the risk rating and durability discount [math: U] in the banded discount schedule below (Derivation of the labileDurability fractionDiscount U). A Project that does not complete the questionnaire, or that leaves variables uncharacterized, receives the worst-case discount.
Responses to Section C are forecasts over the 200-year horizon, based on the evidence available at the time of theassessment, biocharand producedare not commitments by the Project Proponent. A response other than the worst option must be supported by documented evidence, such as the design working life of the asset under the applicable design standard, the maintenance, rehabilitation, and reconstruction policy of the asset owner or road authority, and national or regional data on end-of-life and recycling practice, and the highest-risk response consistent with that evidence must be selected. The questionnaire is deductedcompleted fromfor each new storage site added to the CreditsProject and re-completed at each Crediting Period renewal or on material change, and a revised discount applies to Certificates issued after the re-assessment.
[math: U] is the project-specific durability discount as specified in Equation 4, Section 7. The term also represents the fraction of the certified inertinite that may be physically liberated to mobile fines and dispersed into oxic surface environments over the 200-year horizon. The calculation for [math: U]does not re-discount the labile fraction, which is not certified under this Module.
Note; thatthe thisone-standard-deviation frameworkconservatism is already accounted for in [math: F_{durable}]; or acid and matrix dissolution, which exposes but does not takemineralize intoinertinite1. accountThermal commondestruction maintenance(clinker practicesreprocessing) and surface abrasion are handled as gating exclusions, so they are also excluded from the graded discounts here.
[math: U] is derived from the comminuted-inertinite retention model as shown by the equation below:
[math: U = 1 - (1 - f_{disp})^{N}]
(Equation 8)
Where:
[math: N] follows from the service life of the element or, for asphalt pavements, suchof the biochar-bearing layer. The basis is the design standards and documented maintenance and replacement-interval data. Design working lives under EN 1990:2023 are 50 years for common buildings, 100 years for monumental structures and bridges, and 25 years for agricultural buildings; foundations are frequently left in situ.
For asphalt, [math: N] is the number of events within the 200-year horizon at which the biochar-bearing layer is milled, removed, or reprocessed, because the biochar is comminuted only when its own layer is disturbed. A resurfacing event counts for a layer where the milling or removal depth reaches any part of that layer. Rehabilitation, reconstruction, full-depth reclamation, and in-place recycling count where they reach that layer.
By default, every resurfacing event is treated as sealcoatingdisturbing the biochar-bearing layer. [math: N] is then set by the resurfacing interval, roughly 15 to 25 years14, rather than the 40-year pavement design-life label in Table 1. A longer interval may be used only where the Project Proponent evidences, for the application type and region:
This must be set out as theserequired practicesunder varyStorage by region and specific applicationSite. ThusThe basis may be the applicable pavement design standard or the published maintenance policy of the road authority or asset owner, together with the layer thicknesses in the absencepavement design. Where the evidence supports a range of specific information regardingintervals, the useshortest caseinterval andis regionalused.
Table practicesA6: relevantComminution rounds N over the 200-year horizon, by placement band.
Band | Service life (sourced) | N over 200 yr |
|---|---|---|
Concrete structural or foundation | 50 to 100+ yr; often left in situ (EN 1990:2023) | ~0 to 2 |
Concrete above-ground element | ~50 yr (EN 1990:2023) | ~3 to 4 |
Concrete thin element (facade, paving, tile) | ~20 to 25 yr (EN 1990:2023) | ~8 to 10 |
Asphalt Sub-Surface default (biochar-bearing layer disturbed at each resurfacing) | Disturbance interval of the biochar-bearing layer; default ~15 to 25 yr milling interval where not evidenced. N over 200 yr: ~7 to 13 (default); lower where a longer disturbance interval is evidenced ~15 to 25 yr milling interval, N over 200 yr: ~7 to 13 | ~7 to 13 |
Asphalt Sub-Surface, layer-specific interval evidenced | Evidenced milling, rehabilitation, or reconstruction interval of the biochar-bearing layer | 200 yr divided by the evidenced interval |
The Reclaimed Asphalt Pavement (RAP) multiple-recycling literature shows the binder degrades cycle-on-cycle48, so later asphalt cycles are downcycling rather than re-laying, but this does not reduce [math: N], because the biochar is comminuted at each event that mills or reclaims the biochar-bearing layer, whether the material is re-laid or downcycled.
Recycling of biochar-bearing reclaimed asphalt into a new bound mixture, whether by hot, warm, or cold recycling, is not treated as a reversal of the biochar it contains. The durability discount applies only to the fraction comminuted to mobile fines at each milling or processing round ([math: f_{disp}]); the remainder is treated as retained, whether it is re-bound in a new pavement or used in another construction application.
Where biochar is added to a Projectmixture that contains biochar-bearing RAP, only the mostnewly added biochar mass may be certified, and the biochar carried in the RAP must not be certified again.
[math: f_{disp}], no study measures biochar carbon retention through actual asphalt or concrete recycling and this represents a gap in the current literature. As such, [math: f_{disp}] is inferred from the fines (sub-0.075 mm) generated per processing round in the aggregate-recycling literature:
The high end of each range is taken because biochar is more friable than mineral aggregate and the dispersed fraction is untraceable.
These values are a conservative scenarioproxy isfor used.the Projectliberation Proponentsof may choosebiochar to providemobile additionalfines, informationpending direct measurement. Isometric will recalibrate [math: f_{disp}] as direct measurements of biochar carbon retention through asphalt and concrete milling, crushing, and recycling become available.
Applying Equation 8 across the sourced parameter ranges of [math: f_{disp}] gives: concrete structural ([math: f_{disp}] 0.03 to conduct0.05, aN Project1 to 2) roughly 0 to 10%; concrete above-specificground (0.04 to 0.05, N 3.5 to 4) roughly 13 to 19%; asphalt base (0.05 to 0.075, N 7) roughly 30 to 42%; concrete thin (0.06 to 0.08, N 9 to 10) roughly 43 to 57%; and asphalt binder (0.075 to 0.10, N 10 to 13) roughly 63 to 65%. These model outputs cluster into four risk bands shown in Table A7. The Module adopts one durability discount calculation[math: U] per band; the Table below maps each net score and risk rating to that discount and to the representative placement and parameter basis behind it.
Table A7: Durability discount U by risk band.
Net score | Risk rating | [math: U] | Representative placement, and parameter basis |
|---|---|---|---|
0 to 3 | Low | 10% | Concrete structural or foundation; N ~0 to 2 (EN 1990:2023), minimal coarse-crush fines50 |
4 to 8 | Moderate | 30% | Above-ground concrete; asphalt base course; N ~3 to 7 (EN 1990:2023^49), RAP-fines proxy49 |
9 to 14 | High | 60% | Thin concrete; asphalt binder course; N ~8 to 13 (EN 1990:2023^49), elevated fines51,52 |
15 or more | Very High | 90% (or ineligible) | Extreme dispersal, or worst-case default for un-characterized projects |
Gating (G1; G3 unmitigated) | Ineligible | 100% | Surface asphalt and seal coats (in-service dispersal that cannot be quantified or verified, Applicability Section); unmitigated clinker reprocessing (thermal destruction) |
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