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Ex Situ Mineralization in Closed Engineered Systems
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This Module (Independent components of Isometric Certified Protocols which are transferable between and applicable to different Protocols.) details durability and monitoring requirements for storage (Describes the addition of carbon dioxide removed from the atmosphere to a reservoir, which serves as its ultimate destination. This is also referred to as “sequestration”.) of CO2 removed from the atmosphere via engineered carbon removal technology (such as Direct Air Capture) and stored in the solid phase using engineered systems. Durability (The amount of time carbon removed from the atmosphere by an intervention – for example, a CDR project – is expected to reside in a given Reservoir, taking into account both physical risks and socioeconomic constructs (such as contracts) to protect the Reservoir in question.) refers to the length of time for which carbon is removed from the Earth’s atmosphere and cannot contribute to further climate change.
CO2 mineralization and storage in engineered systems refers to the addition of concentrated CO2 to an engineered reactor containing crushed rock or mineral feedstock. The use of engineered systems accelerates the natural chemical reaction of mineral carbonation, which constitutes a durable (>1,000 years) CO2sink (Any process, activity, or mechanism that removes a greenhouse gas, a precursor to a greenhouse gas, or an aerosol from the atmosphere.) when storage site requirements are met. This is possible because parameters that drive the reaction rate (i.e. temperature, pressure, pCO2) can be precisely controlled when operating in an engineered reactor. Additionally, because a reactor is a closed system, the amount of carbon stored can be precisely calculated with targeted measurements of the ingoing and outgoing CO2 stream and feedstock. When implemented correctly, this provides high confidence in the amount of stored CO2.
Mineralization of CO2 as carbonate minerals, through reaction with silicate rocks, occurs naturally as part of the weathering process. The carbonation rate of silicate rock can be dramatically increased by increasing reactive surface area and/or the pressure and concentration of CO2 in the fluid. Mineralization projects can occur at Earth’s surface (open system ex-situ mineralization), in the subsurface (in-situ mineralization), or in closed reactors (ex-situ mineralization in engineered systems). In engineered ex-situ mineralization, a concentrated CO2 stream is introduced to rock or mineral feedstock, commonly waste materials from mining operations,1, 2, 3 in a reactor to form carbonate minerals.4, 5 Because carbonation reactions are kinetically limited in typical surface environments, reactors may be held at elevated temperature and/or pressure and may use feedstock that has been pre-treated (i.e. crushed to a fine grain size, treated with acid or base, and/or heat treated (see Section 3) to increase reactivity6. Laboratory and pilot studies estimate that 65-85% of the total carbonation potential of a given feedstock can be achieved in 12 hours.6, 7 Given current global estimates of suitable feedstock, this represents a stable sink for carbon dioxide at the mega to gigatonne scale.
Reversal (The escape of CO₂ to the atmosphere after it has been stored, and after a Credit has been Issued. A Reversal is classified as avoidable if a Project Proponent has influence or control over it and it likely could have been averted through application of reasonable risk mitigation measures. Any other Reversals will be classified as unavoidable.) risks are considered to be minimal during the reaction of feedstock and concentrated CO2. There are further reversal risks associated with storage of carbonated materials. These risks, as well as the monitoring requirements associated with them, are described in detail in the Carbonated Materials Storage and Monitoring Module 1.0.
This Module outlines the requirements for evaluating carbon storage in the solid phase via reaction of feedstock in engineered reactors for mineralization of rock or mineral feedstock, with an emphasis on in-line measurements of influent/effluent CO2 and mineralogical change in post-reaction feedstock. Requirements for reactor design, calculation of carbon stored and CO2 monitoring are given in Sections 2, 4 and 5 of this Module respectively. Requirements for feedstock characterization can be found in the Rock and Mineral Feedstock Characterization Module 1.0. Monitoring requirements for storage cases are detailed in the Carbonated Materials Storage and Monitoring Module 1.0.
This Module is applicable to any Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) in which a rock or mineral feedstock is carbonated in an engineered system. This may include, but is not limited to:
Details of the carbonation method employed must be described in the Project Design Document (PDD) (The document that clearly outlines how a Project will generate rigorously quantifiable Additional high-quality Removals or Reductions.). This description should include:
To be eligible for carbon credits using this Module, CO2 must be reacted with feedstock in an engineered reactor. This Section details the requirements for reactor design and maintenance. These requirements are applicable to any and all reactors used in the project. For example, if a project uses an indirect carbonation method (see Section 1.1), reactors used at each step of the process must adhere to the requirements outlined in Section 1.1.
Any type of engineered chemical reactor is eligible under the Module, provided that the reactor design requirements set out in Sections 2.2, 2.3, 2.4 and 2.5 below are satisfied. Acceptable reactor types include, but are not limited to, stirred tanks (batch, semi-batch or continuous) and tubular reactors (plug flow, fixed bed, fluidized bed, bubble bed or trickle bed). This list is meant to be comprehensive, but not exhaustive. A brief overview of common reactor types covered under this Module is provided in Table 1. Novel reactor designs not belonging to any of the categories listed here will be acceptable provided that the appropriate reactor design documentation according to Section 2.2 is supplied in the PDD. All reactor designs, including the reactor type, engineering design diagrams, reactor modeling calculations and materials selection must be described in the PDD.
An engineering design diagram of the chemical reactor must be included in the PDD. The design diagram must include details of the dimensions of the reactor, the locations of material inflows/outflows, the positioning of sensors for the monitoring of flow rate, reactant/product chemical composition, temperature and pressure, details of any internal equipment such as agitators or heating/cooling coils and details of any external heat transfer equipment (including heat exchange fluid entry/exit points and corresponding sensors for flow rate and temperature). A sufficient number of viewpoints must be included in the engineering design diagram to show the positioning of all of the key components listed above. Any other process equipment essential to the safe and effective operation of the reactor not listed above should be included and highlighted in the engineering design diagram.
The reactor design must include sensors necessary to quantify any loss of CO2 from the feedstock during operation of the reactor to leakage (The increase in GHG emissions outside the geographic or temporal boundary of a project that results from that project's activities.). This should include, at a minimum, sensors to determine the inflow/outflow of carbon dioxide from the reactor, to be used in conjunction with a suitable reactor model to determine the amount of carbon dioxide reacted and to estimate any loss of carbon dioxide to leakage. Only carbon dioxide which has been determined by this calculation to have undergone complete chemical reaction into a solid mineral product is eligible for carbon credits issued under this Module.
In addition to loss of CO2 from the reactor, Project Proponents should consider the possibility of rock or mineral feedstock loss from the reactor in applicable systems. For example, in a packed bed or fluidized bed reactor using CO2 dissolved in liquid, it is necessary to set flow rates such that loss of solid feedstock particles from the system is minimized. Projects using reactors in which this is a risk are required to characterize solid feedstock loss; further detail is given in Section 5.1.3.
The chemical reactor model used to characterize reactor performance and estimate CO2 and solid feedstock losses should consider all physical and chemical mechanisms relevant to operation of the chosen reactor type. The chemical reactor model should incorporate a chemical kinetics model which is based on the latest scientific understanding for the chosen chemical reaction pathway. Where chemical kinetics are derived from in-house experimental measurements, details of the experimental procedure used to perform these measurements should be included in the PDD.
Suitable mass/volume flow meters must be placed on all material inlets/outlets from the reactor to allow for characterization of reactor performance and to monitor any material losses to the environment. These sensors should be positioned immediately upstream/downstream of the reactor, as appropriate. Suitable sensors to measure pressure, temperature and pH (if applicable) should be implemented to allow for accurate characterisation of the reactor performance through a combination of measurements and modeling. For stirred tank reactor types, these sensors should be placed so that they accurately characterize the measured property in the bulk phase of the reactor. For tubular reactors, two (or more) measurements of each property at different locations may be necessary to accurately characterize the reactor performance. In this case, several sensors should be placed along the length of the reactor. Justification for the positioning of such sensors for characterization of reactor performance should be provided in the PDD.
It is anticipated that operation of the chemical reactor may occur at high temperature and pressure, and that the pH inside the reactor may be acidic. Appropriate considerations need to be made in the design of the reactor to mitigate these operational conditions to ensure operational loss prevention. Details must be provided in the PDD to describe the selection of materials for each component of the reactor, including suitable justification for these choices from the perspectives of heat and corrosion resistance. For reactors operating at high pressures, considerations should be made relating to the operating pressure, vessel shape/size, positioning of material inlets/outlets, and positioning of sensors to ensure mechanical integrity of the reaction vessel. Such considerations should be made in compliance with a suitable local standard which provides regulations for the design and fabrication of pressure vessels, such as 2014/68/EU (the “Pressure Equipment Directive”) or an appropriate regional equivalent standard in the region of operation. If no such regional standard exists in the area of operation, Project Proponents are required to use the 2014/68/EU standard.
Project Proponents are required to implement an appropriate reactor maintenance plan should be in place, and must be detailed in the PDD. The maintenance plan should outline how the Project Proponent will ensure the structural integrity of the reactor vessel to mitigate against potential material loss events. This includes suitable monitoring and mitigation for mechanical, thermal and corrosive events which may lead to failure of the vessel and subsequent release of reaction materials into the environment. All maintenance plans should be in compliance with a suitable local standard which provides regulations for the maintenance of pressure vessels, such as 2014/68/EU or an appropriate regional equivalent standard in the region of operation.
Table 1. Reactor type overview
| Reactor Category | Reactor Type | Description |
|---|---|---|
| Stirred tank | Batch | A closed well-mixed batch system where reactants are added to the vessel at the start of the batch, and products are removed from the vessel at the end of the batch. Mixing is provided by stirring with an agitator. |
| Semi-batch | A well-mixed batch system where reactants are added to the vessel at the beginning of the batch, and products are removed at the end of the batch. Reactants and/or products may be added/removed from the vessel over time throughout the batch. Mixing is provided by stirring with an agitator. | |
| Continuous | An open well-mixed system where reactants and products are both added/removed from the vessel continuously. Mixing is provided by stirring with an agitator. | |
| Tubular | Plug flow | A simple open tubular reactor where reactants flow through the vessel and chemical reaction occurs along the length of the vessel. |
| Fixed bed | An open tubular multiphase reactor where reactants flow over a fixed packed bed of solid reactive material. Chemical reaction occurs along the length of the vessel. | |
| Fluidized bed | An open tubular multiphase reactor where reactants fluidize a bed of solid reactive material. Fluid reactants and solid material flow co-currently within the vessel. Chemical reaction occurs along the length of the vessel. | |
| Bubble bed | An open tubular multiphase reactor where gaseous reactants flow in a vessel saturated with liquid. The gaseous species migrate through the column as bubbles of gas. Chemical reaction occurs along the length of the vessel. | |
| Trickle bed | An open tubular multiphase reactor where liquid reactants flow downwards over a packed bed of reactive solids, while gaseous species flow upwards. Chemical reaction occurs along the length of the vessel. |
All feedstocks must be characterized according to the Rock and Mineral Feedstock Characterization Module 1.0 prior to commencement of project activities (The steps of a Project Proponent’s Removal or Reduction process that result in carbon fluxes. The carbon flux associated with an activity is a component of the Project Proponent’s Protocol.). Note that Project Proponents are required to perform a full suite of geotechnical characterization measurements for all feedstocks used in ex-situ mineralization projects. Ex-situ mineralization projects are additionally required to characterize carbonated feedstocks according to the Rock and Mineral Feedstock Characterization Module 1.0 prior to storage in accordance with the Carbonated Materials Storage and Monitoring Module 1.0.
Some Project Proponents may choose to pre-treat their feedstock to increase reactivity.
Methods of pre-treatment may include, but are not limited to:
Any pre-treatment must be fully described in the PDD, including:
Project Proponents using a thermal activation method for feedstock pre-treatment must demonstrate that there were no carbonate minerals in the feedstock prior to heating. If carbonate minerals are present in the feedstock prior to pre-treating, Project Proponents are required to characterize the mass of carbon lost during heating and include this in calculations of Greenhouse Gas Emissions (GHG) emissions related to project activities.
This section details the calculation of net CO2 storage for ex-situ mineralization projects. The monitoring requirements are described in detail in Section 5. Ex-situ mineralization projects are subject to some additional monitoring requirements associated with pre-treated and carbonated feedstocks, including the geochemical and physical characteristics of carbonated feedstocks (see Section 3, Section 5.3 and the Rock and Mineral Feedstock Characterization Module 1.0) and reversal risk monitoring associated with the storage conditions of carbonate materials (see Carbonated Materials Storage and Monitoring Module 1.0).
The quantity of net CO2 storage for each Reporting Period, RP, can be calculated as follows:
[math: CO_2e_{Stored, RP} = CO_2e_{Mineralized, RP} - CO_2e_{Counterfactual, RP} - CO_2e_{Emissions, RP} ]
Equation 1
Where:
Calculation of CO2eMineralized .
[math: CO_2e_{Mineralized, RP} =\sum \Delta CO_2e_{Mineralized, T2 - T1, MP} - \sum CO_2e_{Losses, MP}]
Equation 2
Where:
[math: CO_2e_{Mineralized, T2 - T1, MP}] must be calculated from direct measurements of feedstock prior to and following the carbonation reaction. Feedstock characterization is required to include quantification of pre-existing carbonate minerals; these analyses must be conducted for every batch of feedstock, as defined in the Rock and Mineral Feedstock Characterization Module 1.0.
[math: CO_2e_{Counterfactual, RP}] is defined as the amount of inorganic carbon that would have been stored in the aqueous or solid phase as a result of passive weathering of the feedstock used, without project intervention, across a credit lifetime (in this case, 1,000 years). In calculating [math: CO_2e_{Counterfactual}], this is the default assumption if no additional information regarding the storage conditions and duration of the feedstock at the mine/quarry site can be provided. If additional information on the conditions and duration of feedstock storage at the feedstock supplier are available, Project Proponents may justify calculating the counterfactual (An assessment of what would have happened in the absence of a particular intervention – i.e., assuming the Baseline scenario.) across a time period relevant to the specific mine or quarry from which the feedstock is sourced in the PDD. For example, projects operating in conjunction with active mines may find it appropriate to use the time of mine closure and provide details of the closure plan in the PDD; alternatively, if sufficient documentation exists suggesting that piles of waste materials generated by the feedstock will not be exposed to ambient environmental conditions for a period exceeding a set number of years, the counterfactual may be considered across that time span.
Additionally, it is important to note that studies have shown that the vast majority of weathering in tailings piles occurs in the surface layer that is exposed to the atmosphere, provided that there is no mechanical overturn13 ,14 ,15. For this reason, counterfactual weathering needs to be accounted for in the top meter of the tailings pile.
[math: CO_2e_{Counterfactual, RP}] must be calculated by a combination of direct measurements and modeling of the expected weathering rate of feedstock under storage conditions relevant to the source site for either 1,000 years or a time period justified in the PDD as described above. Models must be justified by empirical data from subsamples of the feedstock; guidelines for sampling procedures that adequately capture feedstock heterogeneity are described in the Rock and Mineral Feedstock Characterization Module 1.0. Models must take into account:
The measurements and model used to calculate [math: CO_2e_{Counterfactual}] must be provided to Isometric and the VVB. Project Proponents may choose to either assume the total counterfactual as a one-time deduction or to spread the counterfactual deduction across a project lifetime.
[math: CO_2e_{Emissions}] is the total greenhouse gas emissions associated with a given Reporting Period, RP.
Equations and emissions calculation requirements for [math: CO_2e_{Emissions}], including emissions associated with reactor operations and reaction monitoring, are set out in the relevant Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) and are not included in this Module.
This Module requires that fluids are characterized at the point of fluid introduction (influent) and at the point of fluid exit from the system (effluent). Where applicable, analytical methods must be cross-referenced with an appropriate standard (e.g. ISO, EN, BSI, ASTM, EPA) or standard operating procedure. Where a Project utilizes a non-standardized methodology or SOP for the determination of a listed parameter, the Project Proponent is required to outline the relevant method within the project design document (PDD) submitted to the Validation and Verification Bodies (VVB). Note that this Module does not prescribe specific measurement methods, though suggested methods are included. Novel measurement methods may be considered on a case-by-case basis. Further detail is given in Section 5.4.
Project Proponents are required to characterize the amount of non-carbonic acid present in the water source used prior to commencement of project activities. This is to determine the potential risk of non-carbonic acid for dissolution of precipitated carbonates in ex-situ mineralization projects. This must be measured as major anions in the water source, including NO3-, Cl-, PO43-, SO42-, and any other anions relevant to the specific fluid and feedstock used. Measurement methods should comply with ISO 10304-1:2007 or an equivalent national standard. If anion measurements are made on the influent by a partner facility (e.g. wastewater treatment plant, industrial facility), these values may be substituted for direct measurements. To conservatively (Purposefully erring on the side of caution under conditions of Uncertainty by choosing input parameter values that will result in a lower net CO₂ Removal or GHG Reduction than if using the median input values. This is done to increase the likelihood that a given Removal or Reduction calculation is an underestimation rather than an overestimation.) calculate weathering that occurs as a result of non-carbonic acid, Project Proponents choosing to substitute this data for measurements must assume that all non-carbonic acid present in the fluid will react with feedstock:
[math: CO_2e_{Non-carbonic acid} = \sum_i c_i n_i]
Equation 3
Where:
The concentration of non-carbonic acid in the source fluid must be reported in the PDD. Project Proponents are strongly encouraged to calculate the expected losses related to non-carbonic acid and compare this value to expected CO2 storage based on feedstock characteristics to ensure that the water source is suitable for the project.
Depending on the source of the fluid, the concentration of anions may be highly temporally variable. Project Proponents using direct measurements must provide details of their baseline sampling plan and describe how the chosen sampling frequency is appropriate for capturing any significant variation in concentration in the water source.
This Module requires direct monitoring of the carbonic acid system to verify storage via ex-situ mineralization. To adequately constrain the carbonic acid system within the engineered reactor, Project Proponents are required to measure at least two of the following parameters in both the influent and effluent fluids:
To reduce uncertainty (A lack of knowledge of the exact amount of CO₂ removed by a particular process, Uncertainty may be quantified using probability distributions, confidence intervals, or variance estimates.) in carbonic acid system calculations, it is highly recommended to measure all four of these parameters where possible. Bicarbonate (HCO3-) and carbonate (CO32-) can then be calculated using the two-for-six method16, which is commonly accomplished using PHREEQC (typically used for freshwater) software. Project proponents are required to submit data for all parameters of the carbonic acid system, both measured and calculated; where calculations were performed using methods other than PHREEQC, Project Proponents are required to submit the script or spreadsheet where the calculations were made.
Due to the high CO2 concentrations in reactor streams, it is critical that samples are stored properly and analyzed as soon after collection as possible to mitigate any potential re-equilibration of the carbonic acid system. Samples must be stored in refrigerated conditions without headspace in sealed vials. Sample collection procedures and sample storage conditions must be described in the PDD. Where possible, measurement via in-line sensors is highly recommended. Where in-line sensors are installed, Project Proponents are required to report calibration data and frequency, fluid flow paths through the sensor and measurement error (as determined by measurement of standards).
As part of reporting carbonic acid system measurements, Project Proponents must describe in detail the point at which concentrated CO2 is introduced to the system, whether it is dissolved in water prior to introduction into the reactor or if it is introduced into the reactor directly via bubbling or similar. Where possible, the CO2 concentration of the influent must be measured directly. Where this is not possible (e.g. in instances where CO2 is introduced to the reactor directly), Project Proponents must calculate a conservative estimate of CO2 concentration using the concentration of the CO2 stream, the reactor volume, and the partial pressure of CO2 in the reactor. All calculations must be described and reported in the PDD.
In engineered systems where feedstock may be lost, such as fluidized bed reactors, Project Proponents are required to monitor feedstock loss from the system. This should be monitored using turbidity/total suspended solids sensors installed at the influent and effluent points. Alternate methods of quantifying feedstock loss may be appropriate and must be described and justified in the PDD.
This Module requires a full suite of elemental analyses in influent and effluent samples. Fluid samples must be analyzed by either inductively coupled plasma mass spectrometry (ICP-MS; [ISO 17294-1:2004]) or inductively coupled plasma optical emission spectroscopy (ICP-OES; [ISO 11885:2007]) as the primary determination method. Project proponents should take analytical precision and detection limits into account when determining their measurement method. Project proponents are required to describe their measurement methods in the PDD. When reporting data from ICP-MS/OES, project proponents must include information on calibration standards, blanks, and geostandards; requirements for data reports are described in the Rock and Mineral Feedstock Characterization Module 1.0).
For Projects employing a direct carbonation method, in which concentrated CO2 is introduced directly into the reactor without being dissolved in water, Project Proponents are exempt from liquid-phase measurements; instead, influent CO2 concentration must be reported. Reactors must be closely monitored for any potential leakage of CO2 and this monitoring plan must be provided in the PDD.
As outlined in Section 2.4, measurements of temperature, pressure, flow rate and/or pH inside the reactor at one or more locations (depending on the reactor type) may be required for (i) characterization of loss of CO2 due to leakage from the reactor, and/or (ii) as part of a maintenance plan to ensure reactor integrity in terms of thermal, mechanical, or corrosive containment failures. Measurement methods to determine temperature should comply with the ASTM Temperature Measurement Standards, or an equivalent standard in the region of operation. Measurement methods to determine pressure should comply with ASME 19.2-2010, or an equivalent standard in the region of operation. Measurement methods to determine pH should comply with ASTM E70-19, or an equivalent standard in the region of operation. Reactor modeling conducted for quantification of CO2 loss due to leakage from the reactor should follow best practice reactor modeling principles. Owing to the variety of valid approaches which could be used to accurately model the performance of a given chemical reactor, justification of the chosen reactor model formulation should be supplied in the PDD.
In addition to feedstock characterization prior to introduction to the reactor, ex-situ mineralization projects are required to characterize their materials post-carbonation, following the requirements in the Rock and Mineral Feedstock Characterization Module 1.0. This is required for all ex-situ mineralization projects, including those choosing to quantify carbon removal based on aqueous phase measurements, as the physical and geochemical characteristics of carbonated materials are critical for determining appropriate storage conditions and reversal risk monitoring (detailed further in the Carbonated Materials Storage and Monitoring Module 1.0).
Project Proponents must describe their sampling plan in detail in the PDD, paying particular attention to how it addresses heterogeneity in the carbonated feedstock. This includes variation associated with the degree of carbonation, grain sorting based on particle size, geochemical variability inherent to the source material, or any other feedstock characteristics that may introduce bias into the quantification scheme.
Novel measurement methods may be permissible for quantification of any parameter and will be examined on a case-by-case basis. To be eligible, Project Proponents must demonstrate that the novel measurement technique performs within error of conventional methods for all system variation that can be expected under normal operational conditions. Where system variability is well-characterized, Project Proponents may choose to perform this comparison at intervals that reflect the full variability of the system. If this is not possible, due to high variability or lack of system characterization, this comparison must be performed across a full reporting cycle. System variability characterization must include the following parameters:
The final storage reservoir for ex-situ mineralization projects is in the carbonated materials removed from the reactor. Modeling and monitoring requirements associated with storage of carbonated materials are given in the Carbonated Materials Storage and Monitoring Module. Carbonated Materials Storage and Monitoring Module 1.0.
In accordance with Section 3.8 of the Isometric Standard, it is a requirement of this Module that all data associated with quantification of [math: CO_2e_{Stored}] is hosted publicly on the Isometric Registry. This includes all measurements that directly feed into the equation terms listed in Section 4. While it is required to measure and report redundant data that is collected to resolve the mass balance of a system to Isometric, it is not a requirement to make this data public. Further clarity on which measurements will be publicly shared is given in Appendix 1.
| Parameter | Rationale | Possible Measurement Technique/Standards | Requirements | Acceptable Data Sources | Public on registry/Private | |
|---|---|---|---|---|---|---|
| Fluid Measurements | pH | One component of the carbonic acid system, used to calculate the concentration of dissolved CO2 in a fluid. Note that at least 2 components of the carbonic acid system must be directly measured. | In-line pH sensor Discrete pH measurements | Required for influent and effluent samples | Direct measurement or calculation using a 2 for 6 model | Public |
| Dissolved Inorganic Carbon (DIC) | One component of the carbonic acid system, used to calculate the concentration of dissolved CO2 in a fluid. Note that at least 2 components of the carbonic acid system must be directly measured. | Total carbon analyzer | Required for influent and effluent samples | Direct measurement or calculation using a 2 for 6 model | Public | |
| Total Alkalinity | One component of the carbonic acid system, used to calculate the concentration of dissolved CO2 in a fluid. Note that at least 2 components of the carbonic acid system must be directly measured. | Titration | Required for influent and effluent samples | Direct measurement or calculation using a 2 for 6 model | Public | |
| pCO2 | One component of the carbonic acid system, used to calculate the concentration of dissolved CO2 in a fluid. Note that at least 2 components of the carbonic acid system must be directly measured. | In-line pCO2 sensor Headspace equilibration + gas chromatography | Required for influent and effluent samples | Direct measurement or calculation using a 2 for 6 model | Public | |
| Turbidity | Determination of rock or mineral feedstock loss | Turbidity sensor | Required for influent and effluent samples for projects in which rock or mineral feedstock may be lost from the system due to fluid flow | Direct measurement | Private | |
| Total Suspended Solids | Determination of rock or mineral feedstock loss | Total suspended solids sensor Filtration test | Required for influent and effluent samples for projects in which rock or mineral feedstock may be lost from the system due to fluid flow | Direct measurement | Private | |
| Major and trace elements | Determination of weathering by mass balance Determination of trace metal concentrations for regulatory compliance | ICP-MS ICP-OES | Required for influent and effluent samples | Direct measurement | Public | |
| Anions | Determination of strong acid concentration | Ion chromatography | Required for baseline samples | Direct measurements Regulatory data may be substituted if available | Private | |
| Electrical conductivity | Can serve as an additional parameter in 2 for 6 calculations to reduce uncertainty | In-line conductivity sensor | Recommended for baseline, influent and effluent samples | Direct measurement | Private | |
| System Measurements | Pressure | Reactor performance monitoring | Pressure gauge | Required in reactors; variable based on reactor type | Direct measurement | Private |
| Temperature | Reactor performance monitoring Calculation of reaction kinetics | In-line thermometer | Required in reactors; variable based on reactor type | Direct measurement | Private | |
| Flow rate | Reactor performance monitoring Chemical reactor model input | Flow meter | Required in reactors; variable based on reactor type | Direct measurement | Private | |
| Feedstock Measurements | Mineralogy | Assessment of CDR potential and environmental risk | X-ray diffraction (XRD) Scanning electron microscopy (SEM) | Required prior to and following carbonation | Direct measurement | Public |
| Major and trace elements | Assessment of CDR potential and environmental risk | Acid digestion coupled with ICP-MS Acid digestion coupled with ICP-OES X-ray fluorescence (XRF) | Required prior to and following carbonation | Direct measurement | Private | |
| Particle Size Distribution | Reaction rate and chemical reactor modeling | Gravimetric sieving Laser diffraction X-ray scattering | Required prior to and following carbonation | Direct measurement | Private | |
| Surface Area | Reaction rate modeling | Brunauer Emmett Teller (BET) analysis | Required prior to and following carbonation | Direct measurement | Private | |
| Total Inorganic Carbon (TIC) | Determination of carbonation | Thermogravimetric analysis (TGA) | Required prior to and following carbonation | Direct measurement | Public |
| Reactor Design | Parameter | Documentation Required | Requires justification | Other Requirements |
|---|---|---|---|---|
| Reactor Type | Engineering Design Diagram | Yes | ||
| Materials Selection | Engineering Design Diagram | Yes | ||
| Sensor Positioning | Engineering Design Diagram | Yes | ||
| CO2 Introduction Point | Engineering Design Diagram | Yes | ||
| Reactor modeling calculations | Chemical reactor model | Yes | If in-house experimental measurements are used to derive chemical kinetics, experimental procedures and measurements must be provided | |
| Reactor maintenance plan | Documentation detailing the maintenance plan | Yes | ||
| Feedstock | Requirements detailed in the Rock and Mineral Feedstock Characterization Module 1.0 | |||
| Feedstock Pre-treatment, if used | Pre-treatment Method | Pre-treatment plan | Yes | Standard method or laboratory SOP must be provided |
| Physical and chemical characteristics of feedstock after pre-treatment | Data report, including particle size distribution, surface area, and total inorganic carbon | No | Methods used for feedstock characterization must be provided | |
| Counterfactual | Model timescale | Counterfactual weathering model | Yes | If using a timescale other than the default of 1,000 years, documentation must be provided to support the timescale claimed. |
| Source site temperature | Data report | No | ||
| Source site average yearly precipitation | Data report, generated either by rain gauges installed by the Project Proponent or sourced from a weather station | Yes – justification of data source | ||
| Source site average rainwater pH | Data report, generated either by direct measurements by the Project Proponent or sourced from a weather station | Yes – justification of data source | ||
| Source site average groundwater pH | Data report, generated either from direct measurements by the Project Proponent or sourced from a groundwater database | Yes – justification of data source | ||
| Measurements | All measurements listed in Appendix 1 must be reported in the PDD | Data report | Yes, where alternate methods than those listed are used | Standard and calibration data must be provided alongside measurements. All standards or SOPs used for measurements must be provided. |
| Carbonic acid system calculations | Data report and calculations used (spreadsheet, script) | No | ||
| Sampling | Feedstock sampling plan and procedure | See guidance in the Rock and Mineral Feedstock Characterization Module 1.0 | Yes | Sampling plans should be provided for raw feedstock, carbonated feedstock, and pre-treated feedstock (if applicable) |
| Fluid sampling plan and procedure | Detailed description of fluid sampling, both temporally and spatially, and the sampling procedure | Yes | ||
| Aqueous sample storage | Detailed description of storage conditions for aqueous samples | Yes | ||
| Miscellaneous | Any significant but allowable deviation from the requirements outlined in this Module, as approved in consultation with Isometric | Detailed documentation appropriate to the deviation | Yes |
| Parameter | Measurement Frequency | Rationale | |
|---|---|---|---|
| Fluid Measurements | pH | Continuous or pre-defined time steps | pH can be continuously monitored through in-line pH sensors. Discrete pH measurements should be taken at regular intervals to confirm the functionality of in-line sensors. The sampling cadence will be determined by reactor type and flow rate. |
| Dissolved Inorganic Carbon | Pre-defined time steps | Sampling cadence will be determined by the reactor type and flow rate. This must be temporally consistent with other measurements of the carbonic acid system (e.g. tied to a time on continuous sensor output or taken from a volume of fluid collected at the same sampling interval). | |
| Total Alkalinity | Pre-defined time steps | Sampling cadence will be determined by the reactor type and flow rate. This must be temporally consistent with other measurements of the carbonic acid system (e.g. tied to a time on continuous sensor output or taken from a volume of fluid collected at the same sampling interval). | |
| pCO2 | Continuous or pre-defined time steps | pCO2 can be monitored continuously through in-line pCO2 sensors. Where in-line pCO2 sensors cannot be installed, discrete measurements may be substituted. Sampling cadence will be determined by the reactor type and flow rate. This must be temporally consistent with other measurements of the carbonic acid system (e.g. tied to a time on continuous sensor output or taken from a volume of fluid collected at the same sampling interval). | |
| Turbidity | Continuous | Turbidity can be monitored continuously through in-line turbidity sensors. | |
| Total Suspended Solids | Continuous or pre-defined time intervals | Total suspended solids can be monitored continuously through in-line suspended solids sensors. Discrete measurements can be substituted for in-line measurements. Project Proponents choosing to monitor TSS through discrete measurements must justify the time intervals of measurement based on reactor type, flow rate through the reactor and particle size distribution of the feedstock. | |
| Major and trace elements | Pre-defined time intervals | Measurement of major and trace elements requires discrete sampling. Sampling cadence will be determined by the reactor type and flow rate. This must be temporally consistent with sampling for other geochemical measurements. | |
| Anions | Baseline and pre-defined time intervals | Anion measurements are required for baseline fluids and at regular intervals if a strong risk of non-carbonic acid weathering is identified. Measurement of anions requires discrete sampling. Sampling cadence for applicable projects will be determined by the reactor type and flow rate. This must be temporally consistent with sampling for other geochemical measurements. | |
| Electrical Conductivity | Continuous or pre-defined time intervals | Electrical conductivity can be measured continuously using in-line conductivity sensors. Project Proponents choosing to measure electrical conductivity may also use discrete measurements. Sampling cadence will be determined by the reactor type and flow rate. This must be temporally consistent with sampling for other geochemical measurements. | |
| System Measurements | Pressure | Continuous | Pressure should be measured continuously by an in-line pressure gauge. |
| Temperature | Continuous | Temperature should be measured continuously by an in-line thermometer. | |
| Flow Rate | Continuous | Flow rate should be measured continuously by an in-line flow meter. | |
| Feedstock Measurements | Mineralogy | Prior to and following carbonation, as well as following any feedstock pre-treatment | Mineralogy of the feedstock must be constrained prior to and following carbonation to inform the conditions of pre-treatment (if applicable), reactor conditions and mineral storage conditions. |
| Major and Trace Elements | Prior to and following carbonation | Geochemical composition of the feedstock must be constrained prior to and following carbonation to inform the conditions of pre-treatment (if applicable), reactor conditions and mineral storage conditions. | |
| Particle Size Distribution | Prior to and following carbonation, as well as following any feedstock pre-treatment | Particle size distribution of the feedstock must be constrained prior to and following carbonation to inform the conditions of pre-treatment (if applicable), reactor conditions and mineral storage conditions. | |
| Surface Area | Prior to and following carbonation, as well as following any feedstock pre-treatment | Surface area of the feedstock must be constrained prior to and following carbonation to inform the conditions of pre-treatment (if applicable), reactor conditions and mineral storage conditions. | |
| Total Inorganic Carbon (TIC) | Prior to and following carbonation, as well as following any feedstock pre-treatment | TIC of the feedstock must be constrained prior to and following carbonation to inform the conditions of pre-treatment (if applicable), reactor conditions and mineral storage conditions, as well as to ensure accurate accounting of carbon storage. |
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