This Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) provides the requirements and procedures for the calculation of net CO2 equivalent (CO2e) (The amount of CO₂ emissions that would cause the same integrated radiative forcing or temperature change, over a given time horizon, as an emitted amount of GHG or a mixture of GHGs. One common metric of CO₂e is the 100-year Global Warming Potential.)removals (The term used to represent the CO₂ taken out of the atmosphere as a result of a CDR process.) from the atmosphere via Industrial Process Biogenic Carbon Capture and Storage (Bio-CCS). This Protocol is developed for application to Bio-CCS processes or combinations of processes (e.g., solid sorption,1 liquid solvent,2 membrane processes,3 electrochemistry,4 etc.) in which a cradle-to-grave (Considering impacts at each stage of a product's life cycle, from the time natural resources are extracted from the ground and processed through each subsequent stage of manufacturing, transportation, product use, and ultimately, disposal.)GHG Statement (A document submitted alongside Claimed Removals and/or Reductions that details the calculations associated with a Removal or Reduction, including the Project's emissions, Removals, Reductions and Leakages, presented together in net metric tonnes of CO₂e per Removal or Reduction.) can be accurately applied and in which the CO2 captured is stored via physical5 or chemical6 trapping mechanisms for >1000 years.
The Protocol ensures:
Specific standards (Standard physical constants as well as standard values set forth by bodies such as the National Institute of Standards and Technology (NIST) or others.) and protocols which are utilized as the foundation of this Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) and for which this Protocol is intended to be fully compliant with are as follows:
Additional reference standards that inform the requirements and overall practices incorporated in this Protocol include:
This Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) was developed based on the current state of the art and publicly available science regarding Bio-CCS.7,8,9 As Bio-CCS is still a developing approach to carbon dioxide removal (CDR) (Activities that remove carbon dioxide (CO₂) from the atmosphere and store it in products or geological, terrestrial, and oceanic Reservoirs. CDR includes the enhancement of biological or geochemical sinks and direct air capture (DAC) and storage, but excludes natural CO₂ uptake not directly caused by human intervention.) with ever-expanding published literature, this Protocol incorporates requirements that may be more stringent than other available regulations or Protocols. The approach taken here may be altered in future versions of the Protocol in-line with advancements in the available technology and published research.
This Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) applies to projects (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) anywhere that capture biogenic carbon at a point-source resulting from processing of an eligible biomass feedstock (Raw material which is used for CO₂ Removal or GHG Reduction.) as outlined in the Biomass Feedstock Accounting Module, and store this carbon with >1000 years durability via physical or chemical trapping mechanisms laid out in a relevant CO2 Storage Module (see Section 8). Projects that capture CO2 that is not of biogenic origin are not eligible. A cradle-to-grave (Considering impacts at each stage of a product's life cycle, from the time natural resources are extracted from the ground and processed through each subsequent stage of manufacturing, transportation, product use, and ultimately, disposal.)GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) Statement must also be able to be accurately applied to all processes within the scope of The Project.
See Section 2 of Biomass Feedstock Accounting Module for eligibility criteria.
The Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) must consider environmental and social impacts and the Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) must provide evidence that The Project will do no net environmental or social harm by complying with Section 3.7 of the Isometric Standard as well as the following requirements:
The following topics are covered briefly in this Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) due to their inclusion in the Isometric Standard, which governs all Isometric Protocols. See in-text references to the Isometric Standard for further guidance.
For each specific Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) to be evaluated under this Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.), the Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) must document Project characteristics in a Project Design Document (PDD) (The document that clearly outlines how a Project will generate rigorously quantifiable Additional high-quality Removals or Reductions.) as outlined in Section 3.2 of the Isometric Standard. The PDD will form the basis for project Verification (A process for evaluating and confirming the net Removals and Reductions for a Project, using data and information collected from the Project and assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).) and evaluation in accordance with this Protocol, and must include consideration of processes unique to Bio-CCS, for example:
Projects (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) must be validated (A systematic and independent process for evaluating the reasonableness of the assumptions, limitations and methods that support a Project and assessing whether the Project conforms to the criteria set forth in the Isometric Standard and the Protocol by which the Project is governed. Validation must be completed by an Isometric approved third-party (VVB).) and project net CO2e removals verified (A process for evaluating and confirming the net Removals and Reductions for a Project, using data and information collected from the Project and assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).) by an independent third party consistent with the requirements described in this Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) as well as in Section 4 of the Isometric Standard.
The Validation and Verification Body (VVB) (Third-party auditing organizations that are experts in their sector and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric prior to conducting validation and verification.) must consider following requisite components:
The threshold for Materiality (An acceptable difference between reported Removals/emissions or Reductions/emissions and what an auditor determines is the actual Removal/emissions or Reduction/emissions.), considering the totality of all omissions, errors and mis-statements, is 5%, in accordance with Section 4.3 of the Isometric Standard.
Verifiers (Third-party auditing organizations that are experts in their sector and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric prior to conducting validation and verification.) should also verify the documentation of uncertainty (A lack of knowledge of the exact amount of CO₂ removed by a particular process, Uncertainty may be quantified using probability distributions, confidence intervals, or variance estimates.) of the GHG Statement (A document submitted alongside Claimed Removals and/or Reductions that details the calculations associated with a Removal or Reduction, including the Project's emissions, Removals, Reductions and Leakages, presented together in net metric tonnes of CO₂e per Removal or Reduction.) as required by Section 2.5.7 of the Isometric Standard. Qualitative Materiality (An acceptable difference between reported Removals/emissions or Reductions/emissions and what an auditor determines is the actual Removal/emissions or Reduction/emissions.) issues may also be identified and documented, such as:12
Project validation (A systematic and independent process for evaluating the reasonableness of the assumptions, limitations and methods that support a Project and assessing whether the Project conforms to the criteria set forth in the Isometric Standard and the Protocol by which the Project is governed. Validation must be completed by an Isometric approved third-party (VVB).) and verification (A process for evaluating and confirming the net Removals and Reductions for a Project, using data and information collected from the Project and assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).) must incorporate site visits to project facilities in accordance with the requirements of ISO 14064-3, 6.1.4.2, including, at minimum, site visits during validation and initial verification to the capture and storage site. Verifiers (Third-party auditing organizations that are experts in their sector and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric prior to conducting validation and verification.) should whenever possible observe operation of the capture and storage processes to ensure full documentation of process inputs and outputs through visual observation and validation of instrumentation, measurements, and required data quality measures.
A site visit must thereafter occur at least once every 2 years at each location.
VVBs (Third-party auditing organizations that are experts in their sector and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric prior to conducting validation and verification.) must comply with the requirements defined in Section 4 of the Isometric Standard. In addition, teams should maintain and demonstrate expertise associated with the specific technologies of interest, including solvent/sorbent chemistry, electricity procurement and heat/power generation and the relevant CO2 storage technology.
Competency must be demonstrated in accordance with Isometric's VVB policy, for example through the relevant sectoral scope accreditations in IAF MD 14.
CDR (Activities that remove carbon dioxide (CO₂) from the atmosphere and store it in products or geological, terrestrial, and oceanic Reservoirs. CDR includes the enhancement of biological or geochemical sinks and direct air capture (DAC) and storage, but excludes natural CO₂ uptake not directly caused by human intervention.) via Bio-CCS and subsequent storage (Describes the addition of carbon dioxide removed from the atmosphere to a reservoir, which serves as its ultimate destination. This is also referred to as “sequestration”.) is often a result of a multi-step process (such as capture, desorption, CO2 transport, CO2 temporary holding, the CO2 injection process, etc.), with activities in each step sometimes managed and operated by different operators, companies, or owners. When there are multiple parties involved in the process (e.g., if capture and storage are undertaken by different entities), and to avoid double counting (Improperly allocating the same Removal or Reduction from a Project Proponent more than once to multiple Buyers.) of CO2e removals, a single Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) must be specified contractually as the sole owner of the Credits (A publicly visible uniquely identifiable Credit Certificate Issued by a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocol.). Contracts must comply with all requirements defined in Section 3.1 of the Isometric Standard.
The Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) must be able to demonstrate additionality (An evaluation of the likelihood that an intervention—for example, a CDR Project—causes a climate benefit above and beyond what would have happened in a no-intervention Baseline scenario.) through compliance with Section 2.5.3 of the Isometric Standard. The baseline (A set of data describing pre-intervention or control conditions to be used as a reference scenario for comparison.) scenario and counterfactual (An assessment of what would have happened in the absence of a particular intervention – i.e., assuming the Baseline scenario.) utilized to assess additionality must be project-specific, and are described in Section 7.4 of this Protocol.
Additionality determinations should be reviewed and completed every five years (aligned with the Crediting Period (The period of time over which a Project Design Document is valid, and over which Removals or Reductions may be Verified, resulting in Issued Credits.)), at a minimum, or whenever project operating conditions change significantly, such as the following:
Any review and change in the determination of additionality (An evaluation of the likelihood that an intervention—for example, a CDR Project—causes a climate benefit above and beyond what would have happened in a no-intervention Baseline scenario.) should not affect the availability of Carbon Finance and Verified Credits (A publicly visible uniquely identifiable Credit Certificate Issued by a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocol.) for the current or past Crediting Periods (The period of time over which a Project Design Document is valid, and over which Removals or Reductions may be Verified, resulting in Issued Credits.), but if the review indicates The Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) has become non-additional, this will make The Project ineligible for future Credits.13
The uncertainty (A lack of knowledge of the exact amount of CO₂ removed by a particular process, Uncertainty may be quantified using probability distributions, confidence intervals, or variance estimates.) in the overall estimate of the net CO2e removal as a result of The Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) must be calculated and transparently presented. The total net CO2e removed over a Reporting Period ([math: RP]; see Section 7.5) for a Project, [math: CO_2e_{Removal,\ RP}], must be conservatively (Purposefully erring on the side of caution under conditions of Uncertainty by choosing input parameter values that will result in a lower net CO₂ Removal or GHG Reduction than if using the median input values. This is done to increase the likelihood that a given Removal or Reduction calculation is an underestimation rather than an overestimation.) determined, based on the requirements outlined in Section 2.5.7 of the Isometric Standard.
Projects (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) must report a list of all input variables used in the net CO2e removal calculation and their uncertainties, including:
The uncertainty information should at least include the minimum and maximum values of a variable. More detailed uncertainty information should be provided if available, as outlined in Section 2.5.7 of the Isometric Standard.
In addition, a sensitivity analysis (An analysis of how much different components in a Model contribute to the overall Uncertainty.) that demonstrates the impact of each input parameter’s uncertainty on the final net CO2e uncertainty must be provided. Details of the sensitivity analysis method must be provided so that the results can be re-created. Parameters may be omitted from a full uncertainty analysis if a Sensitivity Analysis can demonstrate that the parameter contributes to <1% change in removal (The term used to represent the CO₂ taken out of the atmosphere as a result of a CDR process.). For all other parameters, information about Uncertainty must be specified.
In accordance with Section 3.8 of the Isometric Standard, all evidence and data related to the underlying quantification of the net CO₂e removal will be available to the public through Isometric's platform. This includes:
The Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) can request certain information to be restricted (only available to authorized Buyers (An entity that purchases Removals or Reductions, often with the purpose of Retiring Credits to make a Removal or Reduction claim.), the Registry (A database that holds information on Verified Removals and Reductions based on Protocols. Registries Issue Credits, and track their ownership and Retirement.), and VVB (Third-party auditing organizations that are experts in their sector and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric prior to conducting validation and verification.)) where it is subject to confidentiality. This includes emission factors from licensed databases. However, all other numerical data produced or used as part of the quantification of net CO2e removal will be made available.
Bio-CCS systems are typically operated continuously, with captured CO2 being transported and durably stored using a variety of potential processes. Due to the continuous nature of Bio-CCS systems, the equations used to calculate removals will pertain to all net emissions occurring over an interval of time. This unit of time is defined as the Reporting Period, [math: RP], which is the time period during which net CO2e removals are claimed by the Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) and submitted for verification (A process for evaluating and confirming the net Removals and Reductions for a Project, using data and information collected from the Project and assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).). The total net CO2e removal is written hereafter as [math: CO_2e_{Removal}].
GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emission calculations must include all emissions related to the project activities that occur within the Reporting Period. This includes:
(i) any emissions associated with project establishment allocated to the Reporting Period (See Section 7.6.3.1),
(ii) any emissions that occur within the Reporting Period (See Section 7.6.3.2),
(iii) any anticipated emissions that would occur after the Reporting Period that have been allocated to the Reporting Period (See Section 7.6.3.3), and
(iv) leakage (The increase in GHG emissions outside the geographic or temporal boundary of a project that results from that project's activities.) emissions that occur outside of the system boundary that are associated with the Reporting Period (See Section 7.6.3.4).
In line with the Isometric Standard, this Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) requires that removal Credits (A publicly visible uniquely identifiable Credit Certificate Issued by a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocol.) are issued ex-post (Issuance of Credits after removal or reduction took place. This is the manner in which Isometric Delivers Credits.) (after net removal from the atmosphere via Bio-CCS has been achieved). Credits may be issued once CO₂ has been permanently stored in the identified storage reservoir.
The scope of this Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) includes GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).)sources (Any process or activity that releases a greenhouse gas, an aerosol, or a precursor of a greenhouse gas into the atmosphere.), sinks (Any process, activity, or mechanism that removes a greenhouse gas, a precursor to a greenhouse gas, or an aerosol from the atmosphere.) and reservoirs (A location where carbon is stored. This can be via physical barriers (such as geological formations) or through partitioning based on chemical or biological processes (such as mineralization or photosynthesis).) (SSRs) associated with a Bio-CCS Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.).
A cradle-to-grave (Considering impacts at each stage of a product's life cycle, from the time natural resources are extracted from the ground and processed through each subsequent stage of manufacturing, transportation, product use, and ultimately, disposal.)GHG Statement (A document submitted alongside Claimed Removals and/or Reductions that details the calculations associated with a Removal or Reduction, including the Project's emissions, Removals, Reductions and Leakages, presented together in net metric tonnes of CO₂e per Removal or Reduction.) must be prepared encompassing the GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions relating to the activities outlined within the system boundary (GHG sources, sinks and reservoirs (SSRs) associated with the project boundary and included in the GHG Statement.).
GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions and removals associated with The Project may be as direct emissions (Emissions that are produced by a specific CDR process and are directly controllable.) from a process or storage system, or as indirect emissions from combustion of fuels, electricity generation, or other sources. Emissions for processes within the system boundary must include all GHG SSRs from the construction or manufacturing of any project-specific physical site and associated equipment, closure and disposal of each site and associated equipment, and operation of each process, including embodied emissions (Life cycle GHG emissions associated with production of materials, transportation, and construction or other processes for goods or buildings.) of consumables in the process.
Any emissions from sub-processes or process changes that would not have taken place without the CDR (Activities that remove carbon dioxide (CO₂) from the atmosphere and store it in products or geological, terrestrial, and oceanic Reservoirs. CDR includes the enhancement of biological or geochemical sinks and direct air capture (DAC) and storage, but excludes natural CO₂ uptake not directly caused by human intervention.) Project must be fully considered in the system boundary. Biomass feedstock (Raw material which is used for CO₂ Removal or GHG Reduction.) emissions must be calculated as outlined in the Biomass Feedstock Accounting Module. This allows for accurate consideration of additional, incremental emissions induced by the carbon removal process.
The system boundary must include all SSRs controlled by and related to The Project, including but not limited to the SSRs in Figure 1 and Table 1. If any GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) SSRs within Table 1 are deemed not appropriate to include in the system boundary, they may be excluded provided that robust justification and appropriate evidence is provided.
Figure 1. Process flow diagram showing system boundary for Bio-CCS projects[Image: Figure 1]
Table 1. Scope of activities to be included in the system boundary for Bio-CCS projects
| Activity | GHG Source, Sink or Reservoir | GHG | Scope | Timescale of emissions and accounting allocation |
|---|---|---|---|---|
| Establishment of Project | Construction and installation | All GHGs | Equipment and materials manufacture, transport to site and construction site emissions. To include:
| Before project activities start - must be accounted for in the first Reporting Period or amortized in line with allocation rules (Section 7.6.3.1 |
| Initial surveys and feasibility studies | All GHGs | To include any embodied, energy use and transport emissions associated with surveys required for establishment of the project site. | ||
| Misc. | All GHGs | Any SSRs not captured by categories above. | ||
| Operations | Energy use | All GHGs | Energy consumption associated with The Project, for example through electricity or fuel use. | Over each Reporting Period - must be accounted for in the relevant Reporting Period (See Section 7.6.3.2) |
| Biomass feedstock sourcing and transport | All GHGs | Biomass feedstock sourcing, transport and processing. | ||
| Consumables (other than feedstock) | All GHGs | Embodied emissions associated with consumables required for operation of the project site (excluding feedstock). | ||
| Waste processing | All GHGs | Waste processing and end-of-life disposal of components used within the process. | ||
| Sampling required for MRV | All GHGs | Sampling required for MRV, including transportation to collect samples, shipping of samples for laboratory analysis and sample processing. | ||
| Staff travel | All GHGs | Flight, car, train or other travel required for the project operations, including contractors and suppliers required on site. | ||
| Surveys | All GHGs | Equipment, energy use and transport associated with surveys e.g. ecological surveys. | ||
| CO₂ stored | CO₂ only | The gross amount of CO₂ removed and durably stored over a Reporting Period. | ||
| Maintenance of project site | All GHGs | To include actual or anticipated maintenance (lifecycle modules B2), repair (B3), replacement (B4) and refurbishment (B5) activities associated with project-specific site, equipment, vehicles, buildings or infrastructure over the project lifetime. | ||
| Misc. | All GHGs | Any SSRs not captured by categories above. | ||
| End-of-Life | End-of-life emissions | All GHGs | To include anticipated end-of-life emissions (lifecycle modules C1-4). | After Reporting Period - must be accounted for in the first Reporting Period or amortized in line with allocation rules (See Section 7.6.3.3) |
| Sampling required long term monitoring for MRV | All GHGs | Ongoing monitoring, including transportation to collect samples, shipping of samples for laboratory analysis and sample processing. | ||
| Long term ongoing monitoring and surveys | All GHGs | Anticipated equipment, energy use and transport associated with ongoing monitoring and surveys e.g. ecological surveys. | ||
| Misc. | All GHGs | Any emissions source, sink or reservoir not captured by categories above. |
The Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) must consider all GHGs associated with SSRs, in alignment with the United States EPA’s (A United States Government agency that protects human health and the environment.) definition of GHGs, which includes: CO2, methane (CH4), nitrous oxide (N2O) and fluorinated gasses such as hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), sulfur hexafluoride (SF6) and nitrogen trifluoride (NF3). For CO₂ stored, only CO₂ shall be included as part of the quantification. For all other activities all GHGs must be considered. For example, the release of CO2, CH4, and N2O is expected during diesel consumption.
All GHGs must be quantified and converted to CO2e in the GHG Statement using the 100-yr Global Warming Potential (GWP) for the GHG of interest, based on the most recent volume of the IPCC Assessment Report (currently the Sixth Assessment Report).
Miscellaneous GHG emissions are those that cannot be categorized by the GHG SSR categories provided in Table 1. The Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) is responsible for identifying all sources of emissions directly or indirectly related to project activities and must report any outside of the SSR categories identified as miscellaneous emissions.
Emissions associated with a Project's (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) impact on activities that fall outside of the system boundary of a Project must also be considered. This is covered under Leakage in Section 7.6.3.4.
Bio-CCS facilities will typically produce marketable co-products, e.g. energy, in addition to conducting CO2 capture activities. The system boundary of a Bio-CCS Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) must include the full system as set out in Section 7.2, unless Eligibility Criteria are met which allow a more narrow system boundary to be drawn. Projects that meet at least one of the following Eligibility Criteria in Table 2 may draw a more narrow system boundary which only considers activities related to CCS.
Table 2. Eligibility Criteria for allowing a narrow system boundary for a Bio-CCS project
| Description | Documentation required | |
|---|---|---|
| EC1 | The Bio-CCS process is a retrofit to an existing facility that has been operational for at least 3 years prior to the introduction of the Bio-CCS process. | Records of existing facility activities dating back 3 years. The GHG system boundary in this case is limited to materials and processes necessary for the retrofit and processes that directly contribute to the Bio-CCS process, this includes existing processes at the facility that are operated at increased capacity to provide for Bio-CCS (e.g., a steam boiler). |
| EC2 | The Bio-CCS process is a component of a new facility. The facility can establish that the co-product facility alone is financially viable without the sale of carbon Credits (A publicly visible uniquely identifiable Credit Certificate Issued by a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocol.). | Documentation that the proposed facility has a positive Internal Rate of Return (IRR) even in the absence of carbon financing. Project Proponents (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) must also provide documentation that CO2 removal is not required by law or common practice for similar new facilities. The GHG system boundary in this case is limited to processes that directly contribute to the Bio-CCS process, this includes existing processes at the facility that are operated at increased capacity to provide for Bio-CCS (e.g., a steam boiler). |
| EC3 | The Bio-CCS process is a retrofit to an existing facility that produces an energy co-product, where the energy produced at the facility is sold into a grid that is regulated under a sufficiently rigorous cap-and-trade program. | Detailed analysis showing the expected reduction in grid emissions intensity. The GHG system boundary in this case is limited to materials and processes necessary for the retrofit and processes that directly contribute to the Bio-CCS process, this includes existing processes at the facility that are operated at increased capacity to provide for Bio-CCS (e.g., a steam boiler). |
Emissions associated with activities, consumables, and equipment related to the CO2 capture, transportation and storage processes must always be included in the system boundary. In cases where The Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) has demonstrated that the co-product facility is non-additional, universal equipment may be excluded from the system boundary if The Project meets at least one eligibility criteria to qualify for a narrow system boundary (see Table 2). However, additional load imposed on any universal equipment by the operations of the CCS process must be proportionally attributed within the system boundary.
Any energy use within the system boundary must be accounted for through the requirements set out in the Energy Use Accounting Module v1.2. In cases where projects exclude emissions associated with the production of an energy co-product, any reduction in the efficiency of the energy production as a result of the CDR process must be counted towards energy use of the CDR process.
Refer to Energy Use Accounting Module for the calculation guidelines.
Ancillary activities, such as supplementary research and development activities and corporate administrative activities, that are associated with a Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) but are not directly or indirectly related to the issuance of Credits (A publicly visible uniquely identifiable Credit Certificate Issued by a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocol.) can be excluded from the system boundary (GHG sources, sinks and reservoirs (SSRs) associated with the project boundary and included in the GHG Statement.).
Bio-CCS may have additional impacts on GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions beyond the scope of this Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.), that are not already associated with marketable co-products. For example, providing a source of secondary low carbon heat or electricity, avoiding landfill emissions and reducing waste transport emissions. These potential impacts are not included in this conservative GHG accounting framework.
The baseline (A set of data describing pre-intervention or control conditions to be used as a reference scenario for comparison.) scenario for a Bio-CCS Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) is dependent on whether the CCS aspect of The Project is part of a new-build facility, or a retrofit to an existing facility:
The counterfactual (An assessment of what would have happened in the absence of a particular intervention – i.e., assuming the Baseline scenario.) is any CO2 stored in the biomass feedstock (Raw material which is used for CO₂ Removal or GHG Reduction.) that would have remained durably stored in the biomass feedstock in the absence of The Project, in addition to any CO2 that would have been durably stored by the selected storage technology.
See Section 2.2 of Biomass Feedstock Accounting Module for biomass counterfactual eligibility.
The following sections outline the process for calculating the net CO2e removed for each Reporting Period based on total mass stored during that period, written hereafter as [math: CO_2e_{Removal,\ RP}].
Net CO2e removal (The term used to represent the CO₂ taken out of the atmosphere as a result of a CDR process.) for a process utilizing Bio-CCS must be calculated as follows for a Reporting Period, [math: RP]:
[math: CO_2e_{Removal} = CO_2e_{Stored}\ –\ CO_2e_{Counterfactual} -\ CO_2e_{Emissions}]
(Equation 1)
Where;
It should be noted that any potential reversals (The escape of CO₂ to the atmosphere after it has been stored, and after a Credit has been Issued. A Reversal is classified as avoidable if a Project Proponent has influence or control over it and it likely could have been averted through application of reasonable risk mitigation measures. Any other Reversals will be classified as unavoidable.) of CO2 storage in the final storage location occur after Credits (A publicly visible uniquely identifiable Credit Certificate Issued by a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocol.) have been issued so are not included in this equation. See Section 5.6 of the Isometric Standard for further information. Risk of reversal information is given in Appendix 1: Risk of Reversal Questionnaire, with further information provided within the relevant storage module storage module.
Quantification of [math: CO_2e_{Stored}], measurements, and monitoring requirements for the different conversion and storage (Describes the addition of carbon dioxide removed from the atmosphere to a reservoir, which serves as its ultimate destination. This is also referred to as “sequestration”.) pathwaysoptions areis detailed within the respective Modules.
See Section 3.4 for calculation of [math: CO_2e_{Stored}] in saline aquifers.
See Section 3.4 for calculation of [math: CO_2e_{Stored}] in depleted hydrocarbon reservoirs.
DurabilitySee andSection monitoring requirements3.4 for storagecalculation of [math: CO_2e_{Stored}] via in-situ mafic and ultramafic formationsmineralization.
See Section 4.2.1 for calculation of [math: CO_2e_{Stored}] via ex-situ mineralization in closed engineered systems. This is the authoritative source for calculating [math: CO_2e_{Stored}] via carbonation in the built environment.
See Section 5.24.1 for calculation of [math: CO_2e_{Stored}] via carbonationenhanced weathering in theclosed builtengineered environmentsystems.
Type: Counterfactual
As outlined in Section 7.4, Refer to both the Biomass Feedstock Accounting Module and the relevant storage module for calculation of counterfactual (An assessment of what would have happened in the absence of a particular intervention – i.e., assuming the Baseline scenario.) storage.
See Section 3.1 of the Biomass Feedstock Accounting Module for calculation requirements.
Type: Emissions
[math: CO_2e_{Emissions}] is is the total quantity of GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions associated with the Reporting Period, [math: RP]. This can be calculated as:
[math: {CO}_{2}^{}e_{Emissions}^{}\ = \ {CO}_{2}^{}e_{Establishment}^{}\ + \ {CO}_{2}^{}e_{Operations}^{} + \ {CO}_{2}^{}e_{End-of-life}^{}+ \ {CO}_{2}^{}e_{Leakage}^{}]
(Equation 2)
Where
The following sections set out specific quantification requirements for each variable.
GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions associated with project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) establishment should include all historic emissions incurred as a result of project establishment, including but not limited to the SSRs set out in Table 1.
Project establishment emissions occur from the point of project inception up until the first Reporting Period. Establishment emissions may be accounted for in the following ways, with the allocation method selected and justified by the Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.):
The anticipated lifetime of The Project should be based on reasonable justification and should be included in the Project Design Document (PDD) (The document that clearly outlines how a Project will generate rigorously quantifiable Additional high-quality Removals or Reductions.) to be assessed as part of project validation.
Allocation of project establishment emissions to removals must be reviewed at each Crediting Period (The period of time over which a Project Design Document is valid, and over which Removals or Reductions may be Verified, resulting in Issued Credits.) renewal and any adjustments made. If the Project Proponent is not able to comply with the allocation schedule described in the PDD (The document that clearly outlines how a Project will generate rigorously quantifiable Additional high-quality Removals or Reductions.), e.g. due to changes in delivered volume or anticipated project lifetime, the Project Proponent must notify Isometric as early as possible in order to adjust the allocation schedule for future removals. If that is not possible, the reversal (The escape of CO₂ to the atmosphere after it has been stored, and after a Credit has been Issued. A Reversal is classified as avoidable if a Project Proponent has influence or control over it and it likely could have been averted through application of reasonable risk mitigation measures. Any other Reversals will be classified as unavoidable.) process will be triggered in accordance with the Isometric Standard, to account for any remaining emissions.
GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions associated with [math: CO_2e_{Operations}] must include all emissions associated with operational activities, including but not limited to the SSRs set out in Table 1.
[math: CO_2e_{Operations}] emissions occur over the Reporting Period for the deployment being Credited (A publicly visible uniquely identifiable Credit Certificate Issued by a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocol.) and are applicable to the current deployment only. [math: CO_2e_{Operations}] emissions must be attributed to the Reporting Period in which they occur. Allocation may be permitted in certain instances, on a case by case basis in agreement with Isometric.
[math: CO_2e_{End-of-Life}] includes all emissions associated with activities that are anticipated to occur after the Reporting Period, but are directly or indirectly related to the Reporting Period. For example, this could include ongoing sampling activities for MRV (The multi-step process to monitor the Removals or Reductions and impacts of a Project, report the findings to an accredited third party, and have this third party Verify the report so that the results can be Certified.) for the specific deployment (directly related), or end-of-life emissions for the project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) facility (indirectly related to all deployments).
GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions associated with [math: CO_2e_{End-of-Life}] may occur from the end of the Reporting Period onward, and typically through to completion of project site deconstruction and any other end-of-life activities.
GHG emissions associated with activities that are directly related to each deployment must be quantified as part of that Reporting Period. GHG emissions associated with activities that are indirectly related to all deployments may be allocated in the same ways as set out in [math: CO_2e_{Establishment}].
Given the uncertain nature of [math: CO_2e_{End-of-Life}] emissions, assumptions must be revisited at each Crediting Period (The period of time over which a Project Design Document is valid, and over which Removals or Reductions may be Verified, resulting in Issued Credits.) and any necessary adjustments made. Furthermore, if there are unexpected [math: CO_2e_{End-of-Life}] emissions associated with a Reporting Period, or The Project as a whole, that occur after The Project has ended, then the reversal (The escape of CO₂ to the atmosphere after it has been stored, and after a Credit has been Issued. A Reversal is classified as avoidable if a Project Proponent has influence or control over it and it likely could have been averted through application of reasonable risk mitigation measures. Any other Reversals will be classified as unavoidable.) process will be triggered to compensate for any emissions not accounted for.
[math: CO_2e_{Leakage}] includes emissions associated with a project's impact on activities that fall outside of the system boundary of a Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.).
It includes increases in GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions as a result of The Project displacing emissions or causing a knock on effect that increases emissions elsewhere. This includes emissions associated with activity-shifting, market leakage and ecological leakage.
It is the Project Proponent's (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) responsibility to identify potential sources of leakage (The increase in GHG emissions outside the geographic or temporal boundary of a project that results from that project's activities.) emissions. As a minimum Bio-CCS projects must account for market leakage emissions in accordance with the Biomass Feedstock Accounting Module and the relevant storage modules.
[math: CO_2e_{Leakage}] emissions must be attributed to the Reporting Period in which they occur. Allocation may be permitted in certain instances, on a case by case basis in agreement with Isometric.
This section of the Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) outlines requirements for emissions accounting relating to energy use, transportation, and embodied emissions (Life cycle GHG emissions associated with production of materials, transportation, and construction or other processes for goods or buildings.) associated with a CDR Project.
Emissions associated with energy usage, whether through electricity or fuel use, must be accounted for throughout all phases of the process.
Energy related emissions may include, but are not limited to:
Process emissions associated with The Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) will be calculated by totaling the energy use (thermal and electrical) of all equipment within the project boundary. To determine the energy use, the following measurements must be provided:
Electricity:
When the electricity is provided to the CCS processes via the output of a Bio-CCS facility which produces electricity, the cradle-to-grave (Considering impacts at each stage of a product's life cycle, from the time natural resources are extracted from the ground and processed through each subsequent stage of manufacturing, transportation, product use, and ultimately, disposal.)emissions factor for the bioenergy facility shall be used as the primary emissions factor for calculation of electricity related emissions for the CDR process.
Electricity metering and record keeping must be performed in accordance with the Energy Use Accounting Module v1.2.
Refer to the Energy Use Accounting Module for requirements.
Thermal Energy
Any thermal energy used by the CDR (Activities that remove carbon dioxide (CO₂) from the atmosphere and store it in products or geological, terrestrial, and oceanic Reservoirs. CDR includes the enhancement of biological or geochemical sinks and direct air capture (DAC) and storage, but excludes natural CO₂ uptake not directly caused by human intervention.) process must be monitored, including steam use, direct combustion of fuels within the CDR process to provide heat, and use of waste heat.
In the case of steam, waste heat, or other thermal inputs to the CDR Process, measurements must be made of the total thermal energy supplied to the CDR Process. Total thermal energy must be measured using the following methods:
Emissions associated with thermal energy and its production, and record keeping, must be performed in accordance with the Energy Use Accounting Module v1.2.
The Energy Use Accounting Module v1.2 provides requirements on how energy-related emissions must be calculated so that they can be subtracted in the net CO2e removal calculation. It sets out the calculation approach to be followed for intensive facilities and non-intensive facilities and acceptable emissions factors.
Refer to Energy Use Accounting Module for the calculation guidelines.
Emissions related to transportation via freight transportation services, such as rail, truck, or maritime transport must be accounted for, including:
The Transportation Emissions Accounting Module v1.1 provides requirements on how transportation-related emissions must be calculated so that they can be subtracted in the net CO2e removal calculation. It sets out the calculation approach to be followed and acceptable emissions factors.
Refer to Transportation Emissions Accounting Module for the calculation guidelines.
Embodied GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions associated with the manufacturing, delivery, and installation of all equipment and consumables that lie within the system boundary (GHG sources, sinks and reservoirs (SSRs) associated with the project boundary and included in the GHG Statement.) must be accounted for in each Reporting Period. Embodied emissions (Life cycle GHG emissions associated with production of materials, transportation, and construction or other processes for goods or buildings.) are those related to the life cycle impact of equipment and consumables.
Examples of project-specific materials, equipment and consumables that must be considered as part of the embodied emission calculation include but are not limited to:
Equipment, including:
Equipment and infrastructure for processes relating to the wider facility, for example energy generation or product manufacturing.
CO2 Capture Process:
CO2 transportation:
CO2 storage:
Monitoring:
Universal equipment for all processes:
Consumables, including:
Consumables for processes relating to the wider facility, for example energy generation or product manufacturing.
Capture Process:
CO2 storage:
Monitoring:
Universal consumables for all processes:
Embodied emissions for equipment used in the wider facility processes, CO2 capture process, CO2 transportation, or CO2 storage must be included the the system boundary. In some cases universal equipment may be excluded from the system boundary if The Project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) meets the eligibility criteria for a narrow system boundary outlined in Table 2.
The Embodied Emissions Accounting Module v1.0 sets out the calculation approach to be followed including allocation of embodied emissions, life cycle stages to be considered, data sources and emission factors.
Refer to Embodied Emissions Accounting Module for the calculation guidelines.
Miscellaneous GHG (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) emissions for emissions associated with a given Reporting Period are those not included in the SSR categories provided in Table 1. The Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) is responsible for identifying all sources of emissions directly or indirectly related to project (An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.) activities.
Miscellaneous GHG emissions must consider direct emissions (Emissions that are produced by a specific CDR process and are directly controllable.) of non-CO2 GHGs due to process leaks or fugitive emissions, releases, or GHG containing tailgas from:
Quantification of emissions associated with direct emissions (Emissions that are produced by a specific CDR process and are directly controllable.) of non-CO2GHGs (Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).) requires two primary measurements, the measurement of the total quantity of emissions and the analysis of emissions for CO2 and other GHG content. This can be calculated as follows:
[math: CO_{2}e_{MiscProject} = \sum_{t=1}^{T} m_{em,t} \cdot\ C_{GHG,t} \cdot\ GWP_{GHG}]
(Equation 3)
Where:
The total quantity of direct emissions can be measured by various acceptable methods, including:
The concentration of GHGs in direct emissions must be measured directly via one of the following methods:
The Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) must maintain the following records as evidence supporting calculation of direct emissions (Emissions that are produced by a specific CDR process and are directly controllable.):
Records of all data and analyses must be maintained by the Project Proponent and provided for verification purposes for a period of five years.
This Protocol (A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.) provides multiple options for conversion and durable storage (Describes the addition of carbon dioxide removed from the atmosphere to a reservoir, which serves as its ultimate destination. This is also referred to as “sequestration”.) of CO2. The Project Proponent (The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.) can choose from available options when submitting their Project for verification (A process for evaluating and confirming the net Removals and Reductions for a Project, using data and information collected from the Project and assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).):
Durability and monitoring requirements forCO2 storage in saline aquifers.
CO2 storage in depleted hydrocarbon reservoirs.
Durability and monitoring requirements forCO2 storage in mafic and ultramafic formations.
DurabilityMust andbe monitoringused requirementswith forthe carbonation in the built environment storage via ex-situ mineralization in closed engineered systemsmodule.
DurabilityMust andbe monitoringused requirementswith forthe ex-situ mineralization in closed engineered systems conversion module.
Must be used with the dissolved inorganic carbon in oceans storage viamodule.
Must be used with the enhanced weathering in theclosed builtengineered environmentsystems conversion module.
This risk assessment identifies the pathway specific risk factors relevant to a carbon removal project. The relevant risk factors identified as part of a risk assessment are included in the monitoring plan requirements for the project, with details included in the Project Design Document. Project specific risk factors inform the required duration of monitoring along with the monitoring requirements set out in the Protocol and the requirements set out in the Monitoring Section of the Isometric Standard.
The risk score, as determined by the Risk of Reversal Questionnaire, will determine a project’s buffer pool contribution. Projects must re-assess their reversal risk at the renewal of each crediting period, or if monitoring identifies a reversal-related risk, or if an actual reversal event takes place. In any event, projects should reassess their reversal risk at a minimum every 5 years.
The Risk of Reversal Questionnaire questions that pertain to this protocol, drawn from the programme-level Risk of Reversal Questionnaire defined in Appendix B: Risk Reversal Questionnaire of the Isometric Standard, include the following:
| # in Isometric Standard Questionnaire | Question | If answered “Yes” | If answered “No” |
|---|---|---|---|
| 1 | Is a reversal directly observable with a physical or chemical measurement as opposed to a modeled result? | Proceed to questions 2-9 | Proceed to questions 8-9 |
| 2 | Is the carbon being stored in an impermeable geologic system? (e.g., salt cavern) | Proceed to questions 8-9 | Add 1 to Risk Score and proceed to questions 3-9 |
| 5 | Does this approach have a material risk of reversal due to natural disasters including, but not limited to, floods, storms, earthquakes, fires, etc.? | Add 1 to Risk Score | |
| 6 | Does this approach have a material risk of reversal due to human-induced events from outside actors, such as change in farming practices, change in ownership and management of project sites, or similar? | Add up to 2 to Risk Score | |
| 7 | Applicable only for subsurface storage: Is the carbon being stored with trapping mechanisms preventing reversals? (e.g., multiple confining layers, CO₂ dissolves or solidifies) | Minus 1 to Risk Score (unless 0) | |
| 8 | Is there 10+ years of monitoring and/or lab data demonstrating low project risk? | Minus up to 2 to Risk Score | |
| 9 | Does this pathway have a documented history of reversals? | Add 2 to Risk Score | |
| 10 | Is there one or more project-specific factors that merit a high risk level? | Add up to 2 to Risk Score |
Risk Score Categories
Project specific risk factors will depend on the form of carbon being stored (i.e., organic vs. inorganic), the method of storage (e.g., mineralization, encapsulation), the location of carbon storage (e.g., subsurface, ocean), and the proximity of that carbon to potential agents of reversal.
For projects with carbon storage as inorganic carbon, the presence the following risk factors must be reflected in the risk score corresponding to question 10:
For projects with any form of subsurface carbon storage, the presence of the following risk factors must be reflected in the risk score corresponding to question 10:
Isometric would like to thank following contributors to this Protocol and relevant Modules:
California Air Resources Board. (2022). Carbon Sequestration: Carbon Capture, Removal, Utilization, and Storage. https://ww2.arb.ca.gov/our-work/programs/carbon-sequestration-carbon-capture-removal-utilization-and-storage
Environment and Climate Change Canada. Clean Fuel Regulations: Quantification Method for CO2 Capture and Permanent Storage Version 1.0. (2022) https://publications.gc.ca/collections/collection_2022/eccc/En4-474-2022-eng.pdf
Intergovernmental Panel on Climate Change. (2005). IPCC Special Report on CO2 Capture and Storagehttps://www.ipcc.ch/site/assets/uploads/2018/03/srccs_wholereport-1.pdf
International Organization for Standardization. (2008). Evaluation of measurement data — Guide to the expression of uncertainty in measurement (ISO JGCM GUM). https://www.iso.org/sites/JCGM/GUM/JCGM100/C045315e-html/C045315e.html?csnumber=50461
International Organization for Standardization. (2006). ISO 14040:2006 Environmental management — Life cycle assessment — Principles and framework. https://www.iso.org/standard/37456.html
International Organization for Standardization. (2006). ISO 14044:2006 Environmental management — Life cycle assessment — Requirements and guidelines. https://www.iso.org/standard/38498.html
International Organization for Standardization. (2011). ISO 14066:2011 Greenhouse gases — Competence requirements for greenhouse gas validation teams and verification teams. https://www.iso.org/standard/43277.html
International Organization for Standardization. (2017). ISO/IEC 17025:2017 General requirements for the competence of testing and calibration laboratories. https://www.iso.org/standard/66912.html
International Organization for Standardization. (2019). ISO 14064-2:2019. Greenhouse Gases - Part 2: Specification With Guidance At The Project Level For Quantification, Monitoring And Reporting Of Greenhouse Gas Emission s Or Removal Enhancements. ISO. https://www.iso.org/standard/66454.html
International Organization for Standardization. (2019). ISO 14064-3:2019. Greenhouse gases — Part 3: Specification with guidance for the verification and validation of greenhouse gas statements. ISO. https://www.iso.org/standard/66455.html
International Organization for Standardization. (2022). ISO 9300:2022 Measurement of gas flow by means of critical flow nozzles. https://www.iso.org/standard/77401.html
Matthews, J.B.R. (Ed.). (2018). IPCC, 2018: Annex I: Glossary [Matthews, J.B.R. (ed.)]. In: Global Warming of 1.5°C. An IPCC Special Report on the impacts of global warming of 1.5°C above pre-industrial levels and related global greenhouse gas emission pathways, in the context of... Cambridge University Press. https://doi.org/10.1017/9781009157940.008
Methodology for assessing the quality of carbon Credits, Version 3.0. (2022, May). https://carbonCreditquality.org/methodology.html
NIST (2015, April 20). Overview of ASTM D7036: A Quality Management Standard for Emission Testing. https://www.nist.gov/system/files/documents/2017/10/31/overview-astm-d7036.pdf
NIST. (2023). Specifications, Tolerances, and Other Technical Requirements for Weighing and Measuring Devices - 2023 Edition. NIST. https://www.nist.gov/pml/owm/publications/nist-handbooks/handbook-44-current-edition
US Department of Energy. (2022) Best Practices for Life Cycle Assessment (LCA) of Direct Air Capture with Storage (DACS). https://www.energy.gov/sites/default/files/2022-06/FECM%20DACS%20LCA%20Best%20Practices.pdf
U.S. Environmental Protection Agency. (2023, April 18). Understanding Global Warming Potentials | US EPA. Environmental Protection Agency. Retrieved June 14, 2023, from https://www.epa.gov/ghgemissions/understanding-global-warming-potentials
California Air Resources Board (2018). CCS Protocol under the Low Carbon Fuel Standard (LCFS). https://ww2.arb.ca.gov/sites/default/files/2020-03/CCS_Protocol_Under_LCFS_8-13-18_ada.pdf
Terlouw, T., Bauer, C., Rosa, L., Mazzotti, M. (2021). Life cycle assessment of CO2 removal technologies: a critical review. Energy & Environmental Science. https://doi.org/10.1039/D0EE03757E
Shi, X., Xiao, H., Azarabadi, H., Song, J., Wu, X., Chen, X., and Lackner, K. S. (2020). Sorbents for the Direct Capture of CO2 from Ambient Air. Angewandte Chemie International Edition, 59, 6984–7006. https://doi.org/10.1002/anie.201906756↩
Custelcean, R. (2022). Direct Air Capture of CO2 Using Solvents. Annual Review of Chemical and Biomolecular Engineering, 13, 217–234. https://doi.org/10.1146/annurev-chembioeng-092120-023936↩
Fujikawa, S., and Selyanchyn, R. (2022). Direct air capture by membranes. MRS Bulletin, 47, 416–423. https://doi.org/10.1557/s43577-022-00313-6↩
Renfrew, S. E., Starr, D. E., and Strasser, P. (2020). Electrochemical Approaches toward CO2 Capture and Concentration. ACS Catalysis, 10, 13058–13074. https://doi.org/10.1021/acscatal.0c03639↩
Al Hameli, F., Belhaj, H., and Al Dhuhoori, M. (2022). CO2 Sequestration Overview in Geological Formations: Trapping Mechanisms Matrix Assessment. Energies, 15, Article 20. https://doi.org/10.3390/en15207805↩
Rochelle, C. A., Czernichowski-Lauriol, I., and Milodowski, A. E. (2004). The impact of chemical reactions on CO2 storage in geological formations: A brief review. Geological Society, London, Special Publications, 233, 87–106. https://doi.org/10.1144/GSL.SP.2004.233.01.07↩
Terlouw, T., Treyer, K., Bauer, C., and Mazzotti, M. (2021). Life Cycle Assessment of Direct Air Carbon Capture and Storage with Low-Carbon Energy Sources. Environmental Science & Technology, 55, 11397–11411. https://doi.org/10.1021/acs.est.1c03263↩
Ricks, W., Xu, Q., and Jenkins, J. D. (2023). Minimizing emissions from grid-based hydrogen production in the United States. Environmental Research Letters, 18, 014025. https://doi.org/10.1088/1748-9326/acacb5↩
Erans, M., Sanz-Pérez, E. S., Hanak, D. P., Clulow, Z., Reiner, D. M., and Mutch, G. A. (2022). Direct air capture: Process technology, techno-economic and socio-political challenges. Energy & Environmental Science, 15, 1360–1405. https://doi.org/10.1039/D1EE03523A↩
For example, 49 CFR §195.402 - Transportation of Hazardous Liquids via Pipeline: Procedural manual for operations, maintenance, and emergencies, and 40 CFR §146.94 - Class VI Wells: Emergency and remedial response. ↩↩2
Water neutrality is defined as: the total demand for water should be the same after new development is built, as it was before. That is, the new demand for water should be offset in the existing community by making existing infrastructure and homes in the area more water efficient. ↩
ISO 14064-3: 2019, Section 5.1.7 ↩
Carbon Credit Quality Initiative. Methodology for assessing the quality of carbon credits, Version 3.0 (May 2022). https://carboncreditquality.org/methodology.html↩
Lyons, L., Kavvadias, K. and Carlsson, J., (2021). Defining and accounting for waste heat and cold. EUR 30869 EN, Publications Office of the European Union, Luxembourg. doi:10.2760/73253. https://publications.jrc.ec.europa.eu/repository/handle/JRC126383↩
Flow meters must be calibrated to national traceable standards by an ISO 17025 accredited metrology laboratory. Flow meters may include critical nozzle flow meters (i.e. ISO 9300:2022 compliant meters), coriolis mass flow meters, and other applicable meters for mixed gas flows, as long as properly calibrated and maintained. ↩
Dinh, T.-V., Choi, I.-Y., Son, Y.-S., and Kim, J.-C. (2016). A review on non-dispersive infrared gas sensors: Improvement of sensor detection limit and interference correction. Sensors and Actuators B: Chemical, 231, 529–538. https://doi.org/10.1016/j.snb.2016.03.040↩
Sandoval-Bohorquez, V. S., Rozo, E. A. V., and Baldovino-Medrano, V. G. (2020). A method for the highly accurate quantification of gas streams by on-line chromatography. Journal of Chromatography A, 1626, 461355. https://doi.org/10.1016/j.chroma.2020.461355↩