1.0 Summary
This Protocol provides the requirements and procedures for the calculation of net carbon dioxide equivalent (CO2e)removals from the atmosphere via Direct Air Capture (DAC). This Protocol is developed for application to DAC processes (e.g., solid-sorbent processes,1 liquid-solvent processes,2 membrane processes,3 electro-chemical processes,4 etc.), or combinations of processes, in which a cradle-to-gravegreenhouse gas (GHG) Statement can be accurately applied and in which the CO2 captured is stored via physical5 or chemical6 trapping mechanisms for >1000 years.
The Protocol was developed in line with latest scientific understanding7,8,9 and industry best-practices10,11 which inform the quantification of gross CO2 durably captured and stored via DAC, as well as the accounting of GHG emissions associated with DAC processes. Additionally, the Protocol ensures:
- Consistent procedures are used to measure and monitor all aspects of the process required to enable accurate accounting of net CO2e removal;
- Consistent system boundaries and calculations are utilized to quantify net CO2e removal;
- Requirements are met to ensure the CO2 removals are additional; and
- Evidence is provided and verified by independent third parties to support all net CO2e removal claims.
2.0 Sources and Reference Standards and Methodologies
Specific standards and protocols which are utilized as the foundation of this Protocol, and which this Protocol is intended to be fully compliant with, are as follows:
- Isometric Standard; and
- ISO 14064-2: 2019 – Greenhouse Gases – Part 2: Specification with guidance at the project level for quantification, monitoring, and reporting of greenhouse gas emission reductions or removal enhancements.
Additional reference standards that inform the requirements and overall practices incorporated in this Protocol include:
- ISO 14064-3: 2019 – Greenhouse Gases – Part 3: Specification with Guidance for the verification and validation of greenhouse gas statements;
- ISO 14040: 2006 - Environmental Management - Life Cycle Assessment - Principles & Framework; and
- ISO 14044: 2006 - Environmental Management - Life Cycle Assessment - Requirements & Guidelines.
3.0 Future Versions
This Protocol was developed based on the current state of the art and publicly available science regarding DAC and CO2storage. Because DAC is still a developing approach to carbon dioxide removal (CDR), with ever-expanding published literature, the Protocol incorporates requirements that may be more stringent than some current regulations or other protocols related to DAC and CO2 storage. The approach taken here may be altered in future versions of the Protocol as DAC and CO2 storage technology and research advance.
4.0 Applicability
This Protocol applies to projects that chemically or physically capture atmospheric CO2 from ambient air, and store it durably according to the requirements established in the storage Modules associated with this Protocol (see Section 89). A cradle-to-graveGHG Statement must also be able to be accurately applied to all processes within the scope of the Project.
[R-YMGW-0, Projects located within 1km of an industrial point source of CO2 must outline the method they will use to determine relative difference between local CO2 concentrations and background atmospheric CO2 concentrations.]
Projects that co-capture CO2 from on-site point sources do not qualify for the generation of CreditsCertificates under this Protocol, as this constitutes avoided emissions - not emissions removal. DAC projects that are co-located with industrial point sources of CO2, defined here as being within 1km distance, are only eligible if the Project appropriately discounts measured gross CO2 removals in an amount corresponding to the relative difference between local atmospheric CO2 concentrations, and background atmospheric CO2 concentrations - to ensure that only the captured fraction corresponding to non-fossil emissions is included in claimed removals. In practice, this should be achieved by measuring the concentration of CO2 in the ambient air at the inlet to the DAC process, and discounting gross removals by an amount corresponding to the relative excess of this measurement compared to a background reading at a distance greater than 1km from the co-located industrial point source.
[/R-YMGW-0]
Only DAC projects which meet a zero emissions baseline scenario (see Section 7.2) are eligible under this Protocol. A Project may qualify for this distinction by meeting one of the following conditions:
- No capture facility existed at the capture facility location prior to the start of the project activity (greenfield capture facilities);
- New capture facilities or expanded capture facilities are installed at an existing capture facility location (expansion of existing capture facilities); or
- An existing capture facility would be decommissioned prior to the start of the project activity (refurbishment of an existing capture facility).
5.0 Environmental and Social Safeguarding
[R-JSHX-0, Project must provide evidences that the Project will not lead to negative environmental and social impacts.]The Project must consider environmental and social impacts, and the Project Proponent must provide evidence that The Project will do no net environmental or social harm by complying with the Environmental and Social Impacts Section of the Isometric Standard as well as the following requirements:
[/R-5Y86JSHX-0]
- [G-XR1V-0,
ProjectsProject must outlinehave monitoring systems in place to detect and identify potential CO₂CO2 leaks] to protect personnel.[/G-XR1V-0]CO2storage and pipelines must have monitoring systems in place to detect and identify potential CO2 leaks, including audible alarms and regular monitoring or remote access to alarm notifications by Project Proponent staff following national/international regulations12 (see Section 7.4.18 and the relevant storage modules for more information).
[/RG-5Y86-0] [R-SK3VHCXG-0,
ProjectsProject must outlineprovide a CO2 leak response plan
] that complies with local or national requirements and covers the Project area.[/G-HCXG-0]
- The Project Proponent must have a CO2 leak response plan in place that complies with local or national requirements12 and covers the Area of Review (AOR). This plan must be shared with local communities and first responders in temporary holding, pipeline, and storage locations.
[/RG-SK3V-0][R-D7ZG51S5-0,
ProjectsProject must
documentprovide documentation of all emissions of solvents and/or sorbents
from the DAC Project and demonstrate that emissions
of the following types are below regulatory limits
where applicable based on solvent and/or sorbent chemistry.]
- [/G-51S5-0]The Project Proponent must document emissions of solvents and/or sorbents from the DAC Project and demonstrate that emissions of the following types are below regulatory limits where applicable based on solvent and/or sorbent chemistry:
- Amines (volatilized or in aerosol form);
- Ammonia;
- Volatile organic compounds (VOCs);
- Nitrosamines and nitramines;
- Particulate matter, and
- Other hazardous substances (as defined by the authority of the geography where the Project is located or the most stringent of relevant standards worldwide, for example by the EPA) that may be released as a result of sorbent or solvent degradation, volatilization, or aerosolization.
[G-RPMT-0, Project must demonstrate emission level of solvents and/or sorbents by using, where possible and reasonable, national or international standard test and sampling methods (i.e., NIST, ASTM, EPA), and should be completed by a qualified testing organization.] [/RG-D7ZGRPMT-0]- Emission levels of solvents and/or sorbents must be demonstrated by using, where possible and reasonable, national or international standard test and sampling methods (i.e., NIST, ASTM, EPA), and should be completed by a qualified testing organization. Project Proponents must keep such records on file and must repeat testing when substantial changes to solvent or sorbent formulations occur or substantial changes in operating conditions occur that may impact emissions.
[RG-0WV5CBGF-0, ProjectsProject must demonstrate thatall theyall havehealth addressedand anysafety specificprocedures hazardsas associatedrequired withby the useauthority of the proposedgeography sorbentwhere the Project is located or solvent,the andmost with high concentrationsstringent of CO2relevant standards worldwide is complied.]Project Proponents must comply with all health and safety procedures as required by the authority of the geography where the Project is located or the most stringent of relevant standards worldwide. Proponents must demonstrate that they have addressed any specific hazards associated with the use of the proposed sorbent or solvent, and with high concentrations of CO2.[G-00C4-0, Project must provide results of a social risk assessment.] [/RG-0WV500C4-0] - Demonstrate that a social risk assessment has been conducted. This must consider environmental and social justice issues for the selected storage site, including a robust Stakeholder Input Process and considerations of any direct or indirect impacts on local communities or indigenous people, including livelihoods, ancestral knowledge, and cultural heritage in line with the applicable human rights laws and United Nations declarations.
- [G-KN7S-0, Project must provide a risk assessment and mitigation plan for safe handling and transportation of solvents/sorbents and workers operating at the capture and storage facility.] [/G-KN7S-0]Demonstrate a risk assessment and mitigation plan for safeguarding working conditions, especially regarding safe handling and transportation of solvents/sorbents as well as workers operating the capture and storage facility.
[RG-MHPT7A3E-0, ProjectsProject must outlineprovide areport plan/ torecords monitorof water consumption and water stress, and implement any necessary mitigation activities to ensure water neutralitymonitoring.]The Project Proponent must monitor water consumption and water stress, in addition to implementing necessary mitigation activities to ensure water neutrality.13[/R-MHPT-0] 6.0 Relation to the Isometric Standard
The following topics are covered briefly in this Protocol due to their inclusion in the Isometric Standard, which governs all Isometric Protocols. See in-text references to the Isometric Standard for further guidance.
6.1 Project Design Document
[R-86JF-
01,
ProjectsProject must
documentprovide anyall arrangedproject Powercharacteristics Purchasein Agreementsthe Project Design Document (
PPAsPDD),
Renewableinformation Energyunique Certificatesto (RECs)DAC orsuch otheras: directinformation longon termpower offtakespurchase foragreement, theGHG procurementemissions associated with solvent/sorbent use and safe disposal and Purity/concentration of
energy.CO2, must also be included]
For each specific Project to be evaluated under this Protocol, the Project Proponent must document project characteristics in a Project Design Document (PDD), as outlined in SectionDocumentation 3.2section of the Isometric Standard.. The PDD will form the basis for Project Verification and evaluation in accordance with this Protocol, and must include consideration of processes unique to DAC, for example:
- Information on power purchase agreements (PPAs) or other direct long term offtake agreements for the procurement of energy (if applicable);
- GHG emissions associated with solvent/sorbent use and safe disposal; and
[/R-86JF-0][R-VVE4-0, Projects must document the purity/concentration of CO2 to be stored.]- Purity/concentration of CO2 to be stored.
[/R-
VVE486JF-
01]
6.2 Validation and Verification
Projects must be validated and Project net CO2e removals verified by an independent third party, consistent with the requirements described in this Protocol, as well as in the Validation and Verification Section 4 of the Isometric Standard.
The Validation and Verification Body (VVB) must consider following requisite components:
- Verify that storage sites adhere to the requirements listed in the relevant storage module;
- Verify that the quantification approach and monitoring plan adheres to requirements of Section
78, including demonstration of required records; - Verify that the Environmental & Social Safeguards outlined in Section 5 are met; and
- Verify that the Project is compliant with requirements outlined in the Isometric Standard.
6.2.1 Verification Materiality
The threshold for Materiality, considering the totality of all omissions, errors, and mis-statements, is 5%, in accordance with the Materiality Section 4.3 of the Isometric Standard..
Verifiers should also verify the documentation of uncertainty of the GHG Statement, as required by the Uncertainty Accounting Section 2.5.7 of the Isometric Standard.. Qualitative Materiality issues may also be identified and documented, such as:14
- Data and document control issues that erode the verifier’s confidence in the reported data;
- Poorly managed documented information;
- Difficulty in locating requested information; and
- Noncompliance with regulations indirectly related to GHG emissions, removals or storage.
6.2.2 Site Visits
Project validation and verification must incorporate site visits to project facilities in accordance with the requirements of ISO 14064-3, 6.1.4.2, including, at minimum, site visits during validation and initial verification, to the DAC Project and (if applicable) storage site. Verifiers should, whenever possible, observe operation of the capture and storage processes to ensure full documentation of process inputs and outputs through visual observation and validation of instrumentation, measurements, and required data quality measures.
A site visit must thereafter occur at least once every 2 years at each location.
6.2.3 Verifier Qualifications &and Requirements
VVBs must comply with the requirements defined in Validation and Verification Requirements Section 4 of the Isometric Standard.. In addition, teams should maintain and demonstrate expertise associated with the specific technologies of interest, including solvent/sorbent chemistry, electricity procurement, heat/power generation and the relevant CO2 storage technology.
Competency must be demonstrated in accordance with Isometric's VVB policy, for example throughbased on the relevant sectoral scope accreditations in IAF MD 14, or another demonstration of relevant expertise for this protocol and the selected storage module(s).
6.3 Ownership
CDR via DAC and subsequent storage is often a result of a multi-step process (such as capture, desorption, CO2 transport, CO2 temporary holding, CO2 injection or reaction, etc.), with activities in each step sometimes managed and operated by different operators, companies, or owners. When there are multiple parties involved in the process (e.g. if capture and storage are undertaken by different entities), and to avoid double counting of net CO2e removals, a single Project Proponent must be specified contractually as the sole owner of the CreditsCertificates. Contracts must comply with all requirements defined in the Ownership Section 3.1 of the Isometric Standard..
6.4 Additionality
The Project Proponent must be able to demonstrate additionality through compliance with the Additionality Section 2.5.3 of the Isometric Standard.. The baseline scenario and counterfactual utilized to assess additionality must be project-specific, and are described in Section 7.2 of this Protocol.
Additionality determinations should be reviewed and completed every five years (aligned with the Crediting Period), at a minimum, or whenever project operating conditions change significantly, such as the following:
- Regulatory requirements or other legal obligations for project implementation change or new requirements are implemented;
- Project financials indicate Carbon Finance is no longer required, potentially due to, for example:
- Sale of co-products that make the business viable without Carbon Finance; or
- Reduced rates for capital access.
Any review and change in the determination of additionality should not affect the availability of Carbon Finance and Verified CreditsCertificates for the current or past Crediting Periods, but if the review indicates Thethe Project has become non-additional, this should make Thethe Project ineligible for future CreditsCertificates.15
6.5 Uncertainty
The uncertainty in the overall estimate of the net CO2e removal as a result of the Project must be calculated and transparently presented. The total net CO2e removed over a Reporting Period ([math: RP]; see Section 78.3.12) for a Project, [math: CO_2e_{Removal,\ RP}], must be conservatively determined, based on the requirements outlined in the Uncertainty Accounting Section 2.5.7 of the Isometric Standard..
6.5.1 Reporting of Uncertainty
Projects must report a list of all input variables used in the net CO2e removal calculation and their uncertainties, including:
- Emission factors utilized, as published in public and other databases used;
- Values of measured parameters from process instrumentation, such as metered heat and electricity usage, sorbent/solvent replacement periods and other equipment considerations;
- Laboratory analyses, including that required by selected storage module(s), which could include analysis of carbon content and purity of CO2, CO2-containing injectants or carbonated minerals; and
- Summary of data handling, processing, and error propagation approach.
The uncertainty information should at least include the minimum and maximum values of a variable. More detailed uncertainty information should be provided if available, as outlined in the Uncertainty Accounting Section 2.5.7 of the Isometric Standard.
In addition, a sensitivity analysis that demonstrates the impact of each input parameter’s uncertainty on the final net CO2e uncertainty must be provided. Details of the sensitivity analysis method must be provided so that the results can be re-created. Parameters may be omitted from a full uncertainty analysis if a sensitivity analysis can demonstrate that the parameter contributes to 1% change in removal. For all other parameters, information about Uncertainty must be specified.
6.6 Data sharing
In accordance with the Data Sharing Section 3.8 of the Isometric Standard, all evidence and data related to the underlying quantification of the net CO₂e removal will be available to the public through Isometric's platform. This includes:
- Project Design Document;
- GHG Statement;
- Measurements taken;
- Emission factors used; and
- Scientific literature used.
The Project Proponent can request certain information to be restricted (only available to authorized Buyers, the Registry, and VVB) where it is subject to confidentiality. This includes emission factors from licensed databases. However, all other numerical data produced or used as part of the quantification of net CO2e removal will be made available.
7.0 QuantificationSystem ofBoundary CO2eand removalProject Baseline
7.1 System Boundary and GHG Emission Scope
The scope of this Protocol includes the GHGsources, sinks, and reservoirs (SSRs) associated with a DAC Project.
A cradle-to-graveGHG Statement must be prepared encompassing the GHG emissions relating to the activities associatedoutlined withwithin athe DACsystem boundary.
GHG emissions and storage Project for net CO2e removal, as summarized in Figure 1 and described below:
DAC process: All activities that take placeremovals associated with capturingThe atmosphericProject CO2;CO2may transportation:be Alldirect activities associated with transporting CO2emissions from thea DACprocess plant to theor storage location;CO2system, storage:or Allindirect activitiesemissions thatfrom take place associated with the permanent storagecombustion of CO2fuels, atelectricity thegeneration, storageor location;other andCO2sources. monitoring: All activities related to monitoring CO2 storage.
Emissions formust processesinclude all GHG SSRs within the system boundary should include all GHG SSRs, from the construction or manufacturing of each Projectphysical site and associated equipment, closure of each Project and disposal of each site and associated equipment, and operation of each process (DAC process, CO2 transportation, CO2 storage, and CO2 monitoring).
Ancillary, activitiesincluding (suchembodied asemissions supplementaryof researchequipment and developmentconsumables activitiesused andin corporatethe administrativeproject. activities) that are associated with aThe Project butProponent areis notresponsible for identifying all sources of emissions directly or indirectly related to project activities.
Any emissions from sub-processes or process changes that would not have taken place without the CDR Project must be fully considered in the system boundary. Any activity that ultimately leads to the issuance of CreditsCertificates canshould be included in the system boundary. This allows for accurate consideration of additional, incremental emissions induced by the carbon removal process.
The system boundary must include all relevant GHG SSRs controlled and related to The Project, including but not limited to the SSRs set out in Table 1. If any GHG SSRs within Table 1 are deemed not appropriate to include in the system boundary, they may be excluded fromprovided that robust justification and appropriate evidence is provided in the PDD.
Figure 1. Process flow diagram showing system boundary. for DAC projects
[Image: System boundary diagrams (10)]
Table 1. Scope of activities to be included in the system boundary for DAC projects
Activity | GHG emissionsSource, sink or reservoir | GHG | Scope | Timescale |
|---|
Project establishment | Equipment and removalsmaterials manufacture | All GHGs | Embodied emissions associated with theequipment Projectand maymaterials manufacture for project establishment (lifecycle modules A1-3). To include product manufacture emissions for equipment, buildings, infrastructure and temporary structures. | Before project operations start - must be accounted for in the first Reporting Period or amortized in line with allocation rules (See Section 8.5.1) |
Equipment and materials transport to site | All GHGs | Transport emissions associated with transporting materials and equipment to the project site(s) (lifecycle module A4). |
Construction and installation | All GHGs | Emissions related to construction and installation of the project site(s) (lifecycle module A5). To include energy use for construction, installation and groundworks, as directwell as waste processing activities and emissions associated with land use change. |
Initial surveys and feasibility studies | All GHGs | Any embodied, energy and transport emissions associated with surveys or feasibility studies required for establishment of the project site. |
Misc. | All GHGs | Any SSRs not captured by categories above, for example staff transport. |
Operations | DAC Process | All GHGs | Emissions associated with DAC processes including: - use of consumables (e.g. sorbents, solvents, and heat transfer fluids)
- energy use through electricity, heat, fuel consumption and cryogenic processes
- maintenance of the DAC site(s), equipment, vehicles, buildings and infrastructure including maintenance, repair, replacement and refurbishment
- waste processing
| Over each Reporting Period - must be accounted for in the relevant Reporting Period (See Section 8.5.2) |
CO2 transportation | All GHGs | Emissions associated with CO2 transportation including: - electricity or fuel used for operation of a pipeline or similar non-mobile CO2 transportation process
- maintenance of transportation infrastructure including maintenance, repair, replacement and refurbishment
|
CO2 Storage process | All GHGs | Emissions associated with CO2 storage including: - use of consumables (e.g. feedstock, reactants, dilutants and additives)
- energy use through electricity or fuel consumption
- maintenance of the storage site(s), equipment, vehicles, buildings and infrastructure including maintenance, repair, replacement and refurbishment
- waste processing
|
Direct emissions | All GHGs | Any intentional or unintentional release of emissions due to maintenance, emergency shutdown of equipment, faulty equipment, etc. occurred during DAC process, CO2 transportation, or storage process. |
CO2 Stored | CO2 | The gross amount of CO2 removed and durably stored from a DAC project over a Reporting Period. |
Monitoring process | All GHGs | Emissions associated with monitoring, including: - use of consumables
- energy use through electricity or
storagefuel systemconsumption - maintenance of the monitoring site(s),
orequipment, asvehicles, indirectbuildings and infrastructure including maintenance, repair, replacement and refurbishment - waste processing
|
Sampling required for MRV | All GHGs | Any embodied, energy and transport emissions fromassociated combustionwith sampling for MRV purposes, including transportation to collect samples, shipping of fuelssamples for laboratory analysis and sample processing. |
Staff travel | All GHGs | Flight, electricitycar, generation,train or other sourcestravel required for the project operations, including contractors and suppliers required on site. |
Surveys | All GHGs | Equipment, energy use and transport associated with surveys e.g. ecological surveys. |
Misc. | All GHGs | Any SSRs not captured by categories above. |
End-of-life | End-of-life of project facilities | All GHGs | Anticipated end-of-life emissions (lifecycle modules C1-4). To include deconstruction and disposal of the project site(s), equipment, vehicles, buildings or infrastructure. | After Reporting Period - must be accounted for in the first Reporting Period or amortized in line with allocation rules (See Section 8.5.3) |
Misc. | All GHGs | Anticipated end-of-life emissions (lifecycle modules C1-4). To include deconstruction and disposal of the project site(s), equipment, vehicles, buildings or infrastructure. |
Miscellaneous GHG emissions are those that cannot be categorized by the GHG SSR categories provided in Table 1. The Project Proponent is responsible for identifying all sources of emissions directly or indirectly related to project activities and must considerreport any outside of the SSR categories identified as miscellaneous emissions.
Emissions associated with The Project's impact on activities that fall outside of the system boundary of The Project must also be considered. This is covered under Leakage in Section 8.5.4.
In line with the GHG Accounting Module v1.1, the Project must:
- Consider all GHGs associated with
the relevant SSRs, in alignment with the United States EPAEnvironmental Protection Agency’s definition of GHGs, which includes: carbon dioxide (CO2₂), methane (CH4CH4), nitrous oxide (N2ON20), and fluorinated gasses such as hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), sulfur hexafluoride (SF6SF6), and nitrogen trifluoride (NF3NF3).All For CO2 stored, only CO2 shall be included as part of the quantification. For all other activities all GHGs must be quantifiedconsidered. For example, the release of CO2, CH4, and convertedN2O tois CO2eexpected during diesel consumption;
- Quantify emissions in
thetonnes GHGCO₂ Statementequivalent (t CO₂e) using the 100-yryear Global Warming Potential (GWP) for the GHG of interest, based on the most recent volume of the IPCC Assessment Report (currently the Sixth Assessment Report).[Image:; diagram-2]
Figureand
- Consider
1
Themateriality aboveof greenhouse gases must be includedSSRs in emissionline calculationswith forIsometric each calculation term identified in Figure 1, according to the following guidelines:requirements.
[
ImageModule:
Exampleghg-accounting blue shaded termv1.1]
Calculation terms shaded in blue must account for potential emissions of CO2 and other GHGs (e.g., CH4, and N2O) via use of appropriate emission factors and conversion to CO2e.
[Image: Example green shaded term]
Calculation terms shaded in green must account for potential emissions of CO2 only, as no other GHG emissions are expected from these types of sources.
7.2 Baseline
The baseline scenario for a DAC Project assumes the activities associated with The Project do not take place and any associated infrastructure is not built.
[R-J9CH-0, Projects must demonstrate a zero emissions baseline scenario.]
The counterfactual for DAC projects considers quantification of the CO2 that would have been removed from ambient air via a DAC process and durably stored over the same period in the absence of the Project. As established in Section 4, the counterfactual of qualifying projects is typically considered to be zero, unless a counterfactual scenario is required in the applicable storage module.
[/R-J9CH-0]
78.30 Net CO2eRemovalCDR Calculation
7.38.1 Calculation Approach
and Reporting PeriodDAC systems are typically operated continuously, with captured CO2 being transported and durably stored using a variety of potential processes. Due to the continuous nature of DAC systems, the equations below used to calculate net CO2e removals will pertain to all CO2 removals and GHG emissions that occur over an interval of time. This unit of time is defined as the Reporting Period, [math: RP], which represents an interval of time over which net CO2e removals are calculated and reported for verification.
TheGHG followingemission sectionscalculations outlinemust include all emissions related to the processproject foractivities calculatingthat occur within the Reporting Period. This includes:
- any emissions associated with project establishment allocated to the Reporting Period (See Section 8.5.1);
- any emissions that occur within the Reporting Period (See Section 8.5.2);
- any anticipated emissions that would occur after the Reporting Period that have been allocated to the Reporting Period (See Section 8.5.3); and
- leakage emissions that occur outside of the system boundary that are associated with the Reporting Period (See Section 8.5.4).
Total net CO2eCO2e removedremoval is calculated for each Reporting Period, and is written hereafter as [math: CO_2e_{Removal,\ RP}]. The final net CO2e removal quantification must be conservatively determined, giving high confidence that at a minimum, the estimated amount of CO2e was removed.
In line with the Isometric Standard, this Protocol requires that Removal Certificates are issued ex-post. Certificates may be issued once CO₂ has been durably stored in the identified storage reservoir.
78.42 Calculation of CO2eRemovaleRemoval, RP
Net CO2e removal for a process utilizing DAC must be calculated as follows for a Reporting Period, [math: RP]:
[math: CO_2e_{Removal,\ RP} = CO_2e_{Stored,\ RP}\ –\ CO_2e_{Counterfactual,\ RP}\ -\ CO_2e_{Emissions,\ RP}]
(Equation 1)
Where;
- [math: CO_2e_{Removal,\ RP}] = the total net CO2e removed for a given [math: RP], in tonnes of CO2e.
- [math: CO_2e_{Stored,\ RP}] = the total CO2 removed from the atmosphere and durably stored over the [math: RP], in tonnes of CO2e. See Section
78.4.13. - [math: CO_2e_{Counterfactual,\ RP}] = the total counterfactual CO2 removed from the atmosphere and durably stored in the absence of The Project over the [math: RP], in tonnes of CO2e. Note, unless otherwise specified in the applicable storage module, the counterfactual for DAC projects is typically zero. See Section
78.4.2. - [math: CO_2e_{Emissions,\ RP}] = the total GHG emissions associated with the [math: RP], in tonnes of CO2e. See Section
78.4.35.
It should be noted that any potential reversals of CO2 storage in the final storage location occur after CreditsCertificates have been issued so are not included in this equation. See the Reversal and Buffer Pool Section 5.6 of the Isometric Standard for further information. Risk of reversal information is given in Appendix 21: Risk of Reversal Questionnaire, with further information provided within the relevant storage module storage module.
78.4.13 Calculation of CO2eStored, RP
[math: CO_2e_{Stored,\ RP}] represents the cumulative total CO2 sequestered in all durable storage reservoirs over a Reporting Period. It is calculated as:
[math: CO_2e_{Stored,\ RP} = \sum_{i}^{N} CO_{2}e_{Storage,i}]
(Equation 2)
- [math: CO_{2}e_{Storage,i}] is the total amount of [math: CO_{2}] sequestered in a durable storage reservoir, i, following an applicable storage Module, over the Reporting Period, RP, in tonnes [math: CO_{2}e
Stored]. This term must be measured following the requirements in the respective storage Module. - [math: N] is the total number of durable storage reservoirs used for storage of captured [math: CO_{2}].
Quantification of [math: CO_2e_{StoredStorage,\ RP}] measurements, and monitoring requirements for the different conversion and storagepathways options isare detailed within the respective Modules.
[Module: saline-aquifer-storage v1.
12]
See Section 35.40 for calculation of [math: CO_2e_{StoredStorage}] in saline aquifers.
[Module: depleted-hydrocarbon-reservoirs v1.
01]
See Section 35.40 for calculation of [math: CO_2e_{StoredStorage}] in depleted hydrocarbon reservoirs.
[Module: in-situ-mineralization v1.
12]
See Section 35.40 for calculation of [math: CO_2e_{StoredStorage}] in via in-situ mineralization.
[Module: ex-situ-mineralization-in-closed-engineered-systems v1.1]
See Section 4.2.1 for calculation of [math: CO_2e_{StoredStorage}] via ex-situ mineralization in closed engineered systems. This is the authoritative source for calculating [math: CO_2e_{StoredStorage}] via carbonation in the built environment or carbonated materials.
[Module: enhanced-weathering-closed-engineered-systems v1.0]
See Section 4.1 for calculation of [math: CO_2e_{StoredStorage}] via enhanced weathering in closed engineered systems.
78.4.2 Calculation of CO2eCounterfactual
Type:eCounterfactual, Counterfactual
RPUnless otherwise specified in the applicable storage module, the counterfactual ([math: CO_2e_{Counterfactual,\ RP}]) for eligible projects is considered to be zero, as outlined in Section 4 and Section 7.2.
78.4.35 Calculation of CO2eEmissions
Type:eEmissions, Emissions
RP[math: CO_2e_{Emissions,\ RP}] is is the total quantity of GHG emissions associated with a given Reporting Period, [math: RP]. This can be calculated as:
[math: CO_{2}e_{ Emissions,\ RP} = CO_{2}e_{EnergyEstablishment,\ RP} + CO_{2}e_{TransportationOperations,\ RP} \\ + CO_{2}e_{EmbodiedEnd-of-life,\ RP} + CO_{2}e_{Misc.}Leakage, CO_{2}e_{LeakageRP}]
(Equation 23)
Where:
- [math:
CO_2e_CO_{2}e_{ Emissions,\ RP}] = the total GHG emissions for athe givenReporting Period, [math: RP], in tonnes of CO2e. - [math:
CO_2e_CO_{Energy2}e_{Establishment,\ RP}] = the total GHG emissions associated with energyproject consumptionestablishment for the [math: RP], in tonnes of CO2e, , see Section 8.5.1 - [math: CO_{2}e_{Operations,\ RP}] = the total GHG emissions associated with operational processes for the [math: RP], in tonnes of CO2e, see Section 8.5.2
- [math: CO_{2}e_{End-of-life,\ RP}] = the total GHG emissions that occur after the [math: RP] and are allocated to the [math: RP], in tonnes of CO2e, see Section 8.5.3
- [math: CO_{2}e_{Leakage,\ RP}] = the GHG emissions associated with the Project’s impact on activities that fall outside of the system boundary of a Project, over a given [math: RP], in tonnes of CO2e, see Section
78.5.4.3.2. [math:
The CO_2e_{Transportation}]following =sections theprovide totalan GHG emissions associated with transportationoverview for aeach given [math: RP], in tonnes of CO2e, see Section 7.4.3.3.
[math: CO_2e_{Embodied}] = the total embodied GHG emissions allocated to a given [math: RP], in tonnes of CO2e, see Section 7.4.3.4.[math: CO_2e_{Misc.}] = the total miscellaneous GHG emissions for a given [math: RP], that cannot be categorized by [math: CO_2e_{Energy}], [math: CO_2e_{Transportation}], or [math: CO_2e_{Embodied}], in tonnes CO2e, see Section 7.4.3.5.[math: CO_2e_{Leakage,\ n}]= the total GHG emissions associated with the Project’s impact on activities that fall outside of the system boundary of a Project, allocated to a given [math: RP], in tonnes of CO2e, see Section 7.4.3.6.7.4.3.1 Emissions allocation to Reporting Periods
Emissions that occur during a Reporting Period, [math: RP], must be included directly and fully in that Reporting Period, and not allocated across multiple Reporting Periods.
Embodied emissions which relate to multiple Reporting Periods may be allocated to removals in line with the allocation rules set out in the Embodied Emissions Accounting Module v1.0.
When the Project Proponent is planning to cease operations within a given storage site, they must project any emissions associated with activities required for post-closure monitoring, and allocate them to the remaining removals taking place at the storage site. If that is not possible, the Project Proponent should allocate those emissions to other projects and/or storage sites they conduct removal operations at, in agreement with Isometric. If for any reason emissions are not appropriately allocated, the Reversal process will be triggered in accordance with Isometric Standard to account for any remaining monitoring emissions.
In instances where monitoring activities are shared between entities, for example if multiple DAC companies use the same storage infrastructure and share monitoring activities, the emissions associated with these activities must be allocated proportionally between the entitiesvariable.
78.45.3.21 Calculation of CO2eEnergy
eEstablishment, RPGHG emissions associated with [math: CO_2e_CO_{Energy2}e_{Establishment,\ RP}] should include all historic emissions incurred as a result of project establishment, including but not limited to the SSRs set out in Table 1.
Project establishment emissions occur from the point of project inception through to before the first removal activity takes place. GHG emissions associated with project establishment may be amortized over the anticipated project lifetime, or per output of product. Rules on amortization are outlined in Section 7 of the GHG Accounting module .
[Module: ghg-accounting v1.1]See Section 7 of the GHG Accounting Module
8.5.2 Calculation of CO2eOperations, RP
GHG emissions associated with [math: CO_{2}e_{Operations,\ RP}] should include all emissions associated with operational activities including but not limited to the SSRs set out in Table 1.
[math: CO_{2}e_{Operations,\ RP}] emissions must be attributed to the Reporting Period in which they occur. Allocation may be permitted in certain instances, on a case by case basis, in agreement with Isometric.
8.5.3 Calculation of CO2eEnd-of-life, RP
[math: CO_2e_{End-of-Life,\ RP}] includes all emissions associated with activities that are anticipated to occur after the Crediting Period until the end of the Project Commitment Period. This includes activities related to ongoing monitoring for Reversals.
[math: CO_2e_{End-of-Life,\ RP}] must be estimated upfront and allocated in the same way as set out for calculation of [math: CO_2e_{Establishment,\ RP}].
Given the uncertain nature of [math: CO_2e_{End-of-Life,\ RP}] emissions, assumptions must be revisited at each Reporting Period and any necessary adjustments made.
8.5.4 Calculation of CO2eLeakage, RP
[math: CO_2e_{Leakage,\ RP}] includes emissions associated with a Project's impact on activities outside the system boundary of The Project. This includes instances where The Project causes an increase in GHG emissions by diverting material from other uses or incentivizing increased production activity.
It is the Project Proponent's responsibility to identify potential sources of leakage emissions. For a DAC Project, market leakage emissions associated with the replacement of consumables used must be considered as a minimum. Project Proponents may also consider the impact of project operations on potential increased use of rare-earth materials for the production of sorbents, land use change, and increased strain on existing CO2 transportation and storage infrastructure.
8.5.5 Emissions Accounting Requirements
[R-GH7M-0, Project must quantify and report all GHG emissions (i.e., energy, embodied, transportation emissions) between projects and approaches. ]GHG accounting must be undertaken in alignment with the GHG Accounting Accounting Module v1.1, which ensures a consistently rigorous standard in how GHG emissions are quantified and reported between different CDR Projects and approaches. This includes:
- Requirements for data quality, including a detailed data quality hierarchy for activity data and emission factors;
- Consideration of materiality in emissions accounting;
- Emissions amortization requirements;
- Co-product allocation requirements;
- By-product accounting relating to inputs to the process that are by-products; and
- Waste input accounting relating to inputs to the process that are wastes.
[/R-GH7M-0] [Module: ghg-accounting v1.1]Refer to GHG Accounting Module for emissions accounting guidelines.
The Energy Use Accounting Module v1.3 provides requirements on how energy-related emissions must be calculated for The Project so that they can be subtracted in the net CO₂e removal calculation. It sets out the calculation approach to be followed for intensive facilities and non-intensive facilities and acceptable emission factors.
Energy emissions are those related to electricity usage or fuel combustionusage.
Energy related emissionsThey may include, but are not limited to:
- DAC Process:
- Electricity used in process operations, including renewable energy, such as:
- Sorbent/solvent or other regeneration process (electrically heated, electrochemical, or other);
- electricity for pumps, motors, drives, etc;
- electricity for instrumentation and controls; and
- electricity for building operation and management for DAC process buildings and direct support buildings (noting that research and development and administrative facilities are not included).
- Fuel combustion for thermal energy generation (heat/steam) such as:
- Sorbent/solvent or other regeneration process (thermal); and
- Heat for DAC process buildings and operations.
- Heat utilization for thermal processes;
1615 and - Cryogenic processes for CO2 purification or liquefaction.
- CO2 Transportation:
- Electricity or fuel used for operation of a pipeline or similar non-mobile CO2 transportation process.
- CO2 Storage:
- Electricity used for operation of any CO2 conversion processes, such as ex-situ carbonate production and handling;
- Electricity used for injection operations, including any pumps, compressors (including for compression into supercritical CO2), or related equipment inside the injection facility gate; and
- Fuel used for heat generation or other purposes at the conversion or injection sites.
- CO2 Monitoring:
- Electricity used for monitoring equipment operation, including analyzers, instrumentation, on-site laboratories specifically for monitoring activities;
- Electricity used for sampling pumps, sampling systems, or other similar monitoring activities;
- Electricity used for off site analytical laboratory operation and sample analysis;
- Electricity used for monitoring system installation (if not accounted for in Project embodied emissions) and operation, such as electricity used for temperature control of monitoring systems (heat trace);
- Electricity for building operation & management for monitoring facility buildings;
- Fuel used for sampling system operation, such as any pumps or heating systems;
- Fuel used for any handling equipment, such as fork trucks or loaders, which are used during sample collection and processing; and
- Fuel used during monitoring system installation, operation or closure, such as that used by drill rigs.
The GHG Accounting Module v1.21 provides requirements on how energy-relatedtransportation and embodied emissions must be calculated for The Project so that they can be subtracted in the net CO2₂e removal calculation.
Embodied Itemissions setsare out the calculation approach to be followed for intensive facilities and non-intensive facilities and acceptable emission factors.
[Module: energy-use-accounting v1.2]Refer to Energy Use Accounting Module for the calculation guidelines.
7.4.3.3 Calculation of CO2eTransportation
Emissionsthose related to transportationthe life cycle impact of CO2 or injectants for all injections during a Reporting Period must be accounted for, including the following:
Emissions associated with transportation of captured CO2 from the DAC process to the injection site via pipeline;Emissions associated with transportation of compressed gaseous or liquid CO2, or CO2 containing injectant (such as a carbonate slurry), or carbonated minerals via freight transportation services, such as rail, truck, or maritime transport; andTransportation of samples for lab analysis.
The Transportation Emissions Accounting Module v1.1 provides requirements on how transportation-related emissions must be calculated so that they can be subtracted in the net CO2e removal calculation. It sets out the calculation scope, approach to be followed, and acceptable emissions factors.
[Module: transportation v1.1]Refer to Transportation Emissions Accounting Module for the calculation guidelines.
7.4.3.4 Calculation of CO2eEmbodied
Embodied GHG emissions associated with the manufacturing, delivery, and installation of all equipment and consumables used in the DAC process must be accounted for in each [math: RP]. TheThey Projectmay Proponent must identify all equipment and consumables used in the DAC processinclude, identifybut appropriate cradle-to-grave emission factors, and allocate the emissions to removals appropriately in line with the Embodied Emissions Accounting Module v1.0.
Project Proponents must account for all embodied emissions in equipment and facilities, including butare not limited to, the following:
- Equipment, including:
- DAC Process:
- DAC Process equipment, including fans, scrubbers, adsorbers, or other contact and/or sorbent regeneration equipment;
- Sorbent, solvent, or other material handling systems, such as pumps, conveyors, augers, feed bins, and related equipment;
- Heat transfer equipment;
- Captured CO2 purification equipment;
- CO2 compression and storage equipment (on-site); and
- Preparation or mixing equipment for sorbents, solvents, or other materials.
- CO2 transportation:
- Equipment used for transportation of CO2, including pipelines, and any pumps or compressors.
- CO2 storage:
- Ex-situ CO2 conversion or reaction equipment (i.e. for carbonate production), including all vessels, pumps, storage, and other process equipment;
- Closed-system temporary holding of CO2 at the injection site; and
- CO2 injection equipment, including compressors, pumps, and all wellbore equipment and materials.
- Monitoring:
- Monitoring wells and all associated materials (steel casing, concrete, etc.);
- On-line analyzers, measurement equipment, or other such devices; and
- Buildings and associated equipment utilized for monitoring purposes (e.g., on-site laboratories).
- General equipment used along the value chain:
- Pumps, piping, and related equipment;
- Storage tanks;
- Support structures, facilities, and infrastructure, including steel platforms, framing, supports, concrete footings, building structures, offshore rigs where applicable etc.; and
- Instrumentation, controls, and other process management equipment.
HeatTransportation generationemissions equipmentare those related to transportation of products and heatequipment. transferThey equipmentmay must be accounted forinclude, but embodied emissions may already be accounted for by emission factors used for fuel combustion - which are often reported from cradle-to-gate. Project Proponents should evaluate whether embodied emissions from equipment such as boilers are included in the energy emissions calculations, and if not, account for the embodied emissions here.
Project Proponents must account for all embodied emissions in DAC process consumables including but not limited to the following:
DAC Process:
Sorbents or solvents, including emissionsEmissions associated with:
Sorbent productiontransportation includingof anycompressed gaseous or liquid CO2 emissions released directly from sorbent production, such as emissions of CO2 from calcination of limestone; andProper disposal of used sorbents.
Heat transfer fluids such as thermal oils or refrigerants.
CO2 storage:
Feedstock or reactants used in the conversion of CO2 to other products for storage; andDilutents or additives used to support or improve injection of CO2 or CO2- containing product.
Monitoring:
Gases,injectant reagents(such as a carbonate slurry), or othercarbonated materialsminerals usedvia forfreight operationtransportation of monitoring equipment, analytical testing, calibration of monitoring equipment and on-site analyzers; andConsumable sampling equipment or supplies that are used in significant quantities.
General consumables used along the value chain:
Gasses such as nitrogen used for process operations, instrumentation, purges, or other operations;Water, including full cradle-to-grave emissions associated with:
Delivery of process water (including cooling water), including embodied emissions associated with water production equipmentservices, such as new wellboresrail, pumpstruck, andor piping,maritime and all energy usage for deliverytransport; andDisposal or treatmentTransportation of usedsamples orfor wastelab process water (including cooling water), including emissions associated with wastewater treatmentanalysis.
Water treatment chemicals used in cooling or process water.
In instances where infrastructure or equipment is shared between entities, for example if multiple DAC companies use the same storage infrastructure and associated activities, the emissions associated with these activities must be allocated proportionally between the entities.
The Embodied Emissions Accounting Module v1.0 sets out the calculation approach to be followed including allocation of embodied emissions, life cycle stages to be considered, and requirements for data sources and emission factors.
[Module:
embodiedghg-
emissionsaccounting v1.
01]
Refer to EmbodiedSection Emissions4.1 and Section 4.2 of the GHG Accounting Module for theguidance calculationon guidelinesembodied and transportation emissions calculations.
7.4.38.5.6 CalculationDirect Emissions Accounting
[R-QTYY-0, Project must provide quantification for all sources of
CO2eMisc.GHG emissions associated with [math: CO_2e_{Misc.}] should include all Project emissions that cannot be categorized by [math: CO_2e_{Energy}], [math: CO_2e_{Transportation}],directly or [math:indirectly CO_2e_{Embodied}]related to Project activities. ]
The Project Proponent is responsible for identifying all sources of emissions directly or indirectly related to Project activities, including those associated with any activities additional to those set out in Section 7.1. The Project Proponent must report such
These emissions as [math: CO_2e_{Misc.}].
Examples include, but are not limited to:
Direct, direct emissions of non-CO2 GHGs due to process leaks or fugitive emissions, releases, or GHG containing tailgas from:
- Conversion processes;
- Degradation of sorbents or solvents; and
- Any other source of potential GHG emissions not of the CO2 collected from the ambient air or not addressed in [math: CO_2e_{Energy}], [math: CO_2e_{Transportation}], or [math: CO_2e_{Embodied}] terms.
Waste processing associated with all aspects of the DAC process, CO2 transport, CO2 storage and monitoring; andStaff travel associated with the Project.
[/R-QTYY-0]
7.4.38.5.6.1 Measurement - CO2eMisc.Direct Project
EmissionsQuantification of [math:these CO_2e_{Misc.emission Project}]sources in a given [math: RP] should be undertaken in line with the requirements set out in the GHG Accounting Module v1.1 and the Energy Use Accounting Module, the Transportation Emissions Accounting Module, and the Embodied Emissions Accounting Modulev1.3, where appropriate.
[G-VFQJ-0, Project must quantify direct emissions of non-CO2 GHGs through two methods; 1) the measurement of the total quantity of emissions and 2) the analysis of emissions for CO2 and other GHG content. ]Quantification of emissions associated with direct emissions of non-CO2 GHGs requires two primary measurements, the measurement of the total quantity of emissions and the analysis of emissions for CO2 and other GHG content. This can be calculated as follows:
[/G-VFQJ-0] [math: CO_{2}e_{MiscProjectDirectEmissions} = \sum_{t=1}^{T} m_{em,t} \cdot\ C_{GHG,t} \cdot\ GWP_{GHG}]
(Equation 34)
Where:
- [math: m_{em,t}] = the mass of
miscellaneousdirect emission(s) (in tonnes) during period [math: t]. - [math: C_{GHG,t}] = the measured concentration as weight percent (%wt) of the relevant GHGs in
thedirect miscellaneous emission(s)emissions. - [math: GWP_{GHG}] = the global warming potential of the relevant GHGs for a 100-year time interval.
- [math: t] = the time index, ranging from 1 to [math: T].
- [math: T] = [math: RP/Δt], the number of time units in Reporting Period, [math: RP].
- [math: Δt] = the time interval the average is taken over.
The total quantity of direct emissions can be measured by various acceptable methods, including:
- Use of calibrated flow meters to provide continuous volumetric or mass flow measurement of a release from a process. Any flow meter must be calibrated for the composition and density of tail gas, or use appropriate conversion factors;
1716 - Use of flow data and curves from tail gas emissions testing and pressure drop measurement (i.e. pitot tubes) in the tail gas stream. Such testing data should be produced by a qualified emissions testing company, accredited to the Stack Testing Accreditation Council for ASTM D7036, ISO 17025, or approved by the authority of the geography where the Project is located or the most stringent of relevant standards worldwide. Testing should be completed under representative process operating conditions;
- Calculation of tail gas amount by a carbon material balance calculated based on direct measurement of other process streams;
- Measurement of a storage vessel pressure and temperature at beginning and end of a defined period within the Reporting Period, [math: RP]. Calculation of total mass of gas can be completed based on gas composition data and temperature and pressure data to determine if release has occurred; and
- Weight of a storage vessel as determined by calibrated weigh scale or load sensor at beginning and end of a defined period within the Reporting Period, [math: RP].
[G-F4K7-0, Project must measure concentration of CO2 or other GHGs in emissions directly via one of the methods specified in the Protocol.]The concentration of CO2 or other GHGs in emissions must be measured directly via one of the following methods:
- On-line analyzer measurement of CO2 or GHG concentration, such as on-line gas chromatography, non-dispersive infrared (NDIR) detector, or similar. Analyzers must be calibrated regularly using NIST-traceable certified gas standards with concentrations of CO2 and GHGs within +/- 30% of expected average tail gas concentration;
1817,1918 - Use of concentration data from process stream tail gas emissions testing. Such testing data should be produced by a qualified emissions testing company, accredited to the Stack Testing Accreditation Council for ASTM D7036, ISO 17025, or approved by the authority of the geography where the Project is located or the most stringent of relevant standards worldwide. Emissions data should only be used when process operating conditions during Reporting Period are similar to the conditions under which testing was completed; and
- Measurement of stream composition by approved test methods, including national and international standards, such as NIST, ASTM, or other, which target the GHG of concern and are completed by a qualified laboratory;
- Analyses must be completed at least quarterly.
[/G-F4K7-0] In instances where direct measurement of concentration is not appropriate (e.g. pressure relief valve actuation), Projects may estimate the quantity of emissions according to best available knowledge, for example based on actuation duration, system pressure change, valve sizing, and typical concentrations of the system being depressurised.
7.4.38.5.6.2 Required Records and Documentation - CO2eMisc.Direct Emissions
[G-2SEW-0, Project
must provide records as evidence supporting calculation of emissions from the DAC or CO2 conversion process]The Project Proponent must maintain the following records as evidence supporting calculation of emissions from the DAC or CO2 conversion process:
- All raw data and data processing or calculation records for measurements and calculations of emissions;
- Results of any emissions tests used to determine emission rates of GHGs from process streams or flow measurements of gas flow from DAC or related processes, including signed report from accredited emissions testing entity;
- Flow rate data from flow meters (including pitot tubes) for each period of interest, including flow meter data recorded in data acquisition systems, manual operation logs, or other records indicating date, time, and flow rate, as well as meter identification number or ID; and
- Documentation of any known evidence of releases, such as:
- pressure relief valve activation (open/close position, or safety valve failure and replacement record);
- observed change in weight of storage vessels; and
- visual observation of release records with followup measurements and documentation of release.
Records of all data and analyses must be maintained by the Project Proponent and provided for verification purposes for a period of five years.
7.4.3.6 Calculationafter the end of CO2eLeakage
[math: CO_2e_{Leakage,\ n}] includes emissions associated with a Project's impact on activities outside the systemmonitoring boundary of The Project. This includes instances where The Project causes an increase in GHG emissions by diverting material from other uses or incentivizing increased production activityperiod.
It is the Project Proponent's responsibility to identify potential sources of leakage emissions. For a DAC Project, market leakage emissions associated with the replacement of consumables used must be considered as a minimum. Project Proponents may also consider the impact of project operations on potential increased use of rare[/G-earth materials for the production of sorbents, land use change, and increased strain on existing CO2 transportation and storage infrastructure.
2SEW-0]
89.0 Storage
This Protocol provides multiple options for conversion and durable storage of CO2. The Project Proponent can choose from available options when submitting their Project for verification:
9.1 Geologic Storage
[Module: saline-aquifer-storage v1.
12]
CO2Durability and monitoring requirements for storage in saline aquifers.
[Module: depleted-hydrocarbon-reservoirs v1.
01]
CO2Durability and monitoring requirements for storage in depleted hydrocarbon reservoirs.
[Module: in-situ-mineralization v1.
12]
CO2Durability and monitoring requirements for storage in mafic and ultramafic formations.
9.2 Mineralization Reactors
9.2.1 Feedstock Characterization
[Module: rock-and-mineral-feedstock-characterization v1.2]Projects which mineralize CO2 must use the Rock & Mineral Feedstock module to characterize their feedstocks, according to the guidance on which tests are relevant in the relevant Capture & Conversion Module.
9.2.2 Ex-situ Mineralization
[Module: ex-situ-mineralization-in-closed-engineered-systems v1.1]
Must be used with the carbonation in the built environment or the carbonated materials storage modulemodules.
[Module: built-materials-storage v1.
01]
Must be used with the ex-situ mineralization in closed engineered systems conversion moduleModule.
[Module: carbonated-material-storage v1.2]Must be used with the ex-situ mineralization in closed engineered systems conversion Module.
9.2.3 Engineered Enhanced Weathering
[Module: enhanced-weathering-closed-engineered-systems v1.0]
Must be used with the dissolved inorganic carbon in oceans storage module.
[Module: dic-storage-in-oceans v1.0]
Must be used with the enhanced weathering in closed engineered systems conversion moduleModule.
910.0 Acknowledgements
Isometric would like to thank following contributors to this Protocol and relevant Modules, or previous versions:
- Tim Hansen (350 Solutions); Direct Air Capture Protocol and Energy Use Accounting, Transportation Emissions Accounting and Embodied Emissions Accounting Modules.
- Chris Holdsworth, PhD (University of Edinburgh); CO2 Storage in Saline Aquifers and CO2 Storage via In-Situ Mineralization in Mafic and Ultramafic Formations Modules.
- Wilson Ricks (Princeton University); Energy Use Accounting Module.
- Grant Faber (Carbon Based Consulting); Transportation Emissions Accounting Module.
Isometric would like to thank following reviewers of this Protocol and relevant Modules, or previous versions:
- James Campbell, PhD (Herriot Watt University); Direct Air Capture Protocol and CO2 Storage via In-Situ Mineralization in Mafic and Ultramafic Formations Module.
- Grant Faber (Carbon Based Consulting); Energy Use Accounting and Embodied Emissions Accounting Modules.
1011.0 Definitions and Acronyms
- A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.
- The amount of CO₂ emissions that would cause the same integrated radiative forcing or temperature change, over a given time horizon, as an emitted amount of GHG or a mixture of GHGs. One common metric of CO₂e is the 100-year Global Warming Potential.
- The term used to represent the CO₂ taken out of the atmosphere as a result of a CDR process.
- Considering impacts at each stage of a product's life cycle, from the time natural resources are extracted from the ground and processed through each subsequent stage of manufacturing, transportation, product use, and ultimately, disposal.
- A document submitted alongside Claimed Removals and/or Reductions that details the calculations associated with a Removal or Reduction, including the Project's emissions, Removals, Reductions and Leakages, presented together in net metric tonnes of CO₂e per Removal or Reduction.
- Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).
- The term used to describe greenhouse gas emissions to the atmosphere as a result of Project activities.
- A process for evaluating and confirming the net Removals and Reductions for a Project, using data and information collected from the Project and assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).
- Standard physical constants as well as standard values set forth by bodies such as the National Institute of Standards and Technology (NIST) or others.
- Describes the addition of carbon dioxide removed from the atmosphere to a reservoir, which serves as its ultimate destination. This is also referred to as “sequestration”.
- Activities that remove carbon dioxide (CO₂) from the atmosphere and store it in products or geological, terrestrial, and oceanic Reservoirs. CDR includes the enhancement of biological or geochemical sinks and direct air capture (DAC) and storage, but excludes natural CO₂ uptake not directly caused by human intervention.
- Independent components of Isometric Certified Protocols which are transferable between and applicable to different Protocols.
- An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.
- A publicly visible, uniquely identifiable,
CreditVerified instrument Issued on the Isometric Registry. Isometric Issues three Certificate IssuedTypes: byCarbon a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂eDioxide Removal or Reduction. In the case of this StandardCertificates, the net tonne of CO₂e Removal orEmission Reduction comesCertificates fromand aEnvironmental ProjectAttribute Validated against a Certified ProtocolCertificates. - A Removal which has been submitted by a Project Proponent, but which has not yet been Verified.
- A set of data describing pre-intervention or control conditions to be used as a reference scenario for comparison.
- An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.
- The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.
- The area surrounding an injection well described according to the criteria set forth in the U.S. Code of Federal Regulations § 40 CFR.146.06, which, in some cases, such as Class II wells, the project area plus a circumscribing area the width of which is either 1⁄4 of a mile or a number calculated according to the criteria set forth in § 146.06.
- A United States Government agency that protects human health and the environment.
- A standards organization that develops and publishes voluntary consensus international standards.
- Any person or entity who can potentially affect or be affected by Isometric or an individual Project activity.
- The document, written by a Project Proponent, which records key characteristics of a Project and which forms the basis for Project Validation and evaluation in accordance with the relevant Certified Protocol. (Also known as “PDD”).
- A contract in which a Buyer agrees to purchase a set Removal and/or Reduction at a set price.
- A systematic and independent process for evaluating the reasonableness of the assumptions, limitations and methods that support a Project and assessing whether the Project conforms to the criteria set forth in the Isometric Standard and the Protocol by which the Project is governed. Validation must be completed by an Isometric approved third-party (VVB).
- Third-party auditing organizations that are experts in their sector and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric prior to conducting validation and verification.
- An acceptable difference between reported Removals/emissions or Reductions/emissions and what an auditor determines is the actual Removal/emissions or Reduction/emissions.
- A lack of knowledge of the exact amount of CO₂ removed by a particular process, Uncertainty may be quantified using probability distributions, confidence intervals, or variance estimates.
- Improperly allocating the same Removal or Reduction from a Project Proponent more than once to multiple Buyers.
- An evaluation of the likelihood that an intervention—for example, a CDR Project—causes a climate benefit above and beyond what would have happened in a no-intervention Baseline scenario.
- An assessment of what would have happened in the absence of a particular intervention – i.e., assuming the Baseline scenario.
- Resources provided to projects that are generating, or are expected to generate, greenhouse gas (GHG) Emission Reductions or Removals.
- Products that have a significant market value and are planned for as part of production.
- The period of time over which a Project Design Document is valid, and over which Removals, Reductions or Environmental Attributes may be Verified, resulting in Issued Certificates
. Resources provided to projects that are generating, or are expected to generate, greenhouse gas (GHG) Emission Reductions or Removals.- Purposefully erring on the side of caution under conditions of Uncertainty by choosing input parameter values that will result in a lower net CO₂ Removal or GHG Reduction than if using the median input values. This is done to increase the likelihood that a given Removal or Reduction calculation is an underestimation rather than an overestimation.
- An estimate of the emissions intensity per unit of an activity.
- An analysis of how much different components in a Model contribute to the overall Uncertainty.
- The document that clearly outlines how a Project will generate rigorously quantifiable Additional high-quality Removals or Reductions.
- An entity that purchases Removals, Reductions, or Environmental Attributes, often with the purpose of Retiring Certificates to make a Removal, Reduction, or Environmental Attribute claim.
- A database that holds information on Verified Removals and Reductions, and reviewed EACs, based on Protocols. Registries Issue Certificates, and track their ownership and Retirement.
- Any process or activity that releases a greenhouse gas, an aerosol, or a precursor of a greenhouse gas into the atmosphere.
- Any process, activity, or mechanism that removes a greenhouse gas, a precursor to a greenhouse gas, or an aerosol from the atmosphere.
- A location where carbon is stored. This can be via physical barriers (such as geological formations) or through partitioning based on chemical or biological processes (such as mineralization or photosynthesis).
- Emissions that are produced by a specific CDR process and are directly controllable.
- GHG sources, sinks and reservoirs (SSRs) associated with the project boundary and included in the GHG Statement.
CertificatesLife arecycle issuedGHG toemissions theassociated Certificatewith Accountproduction of amaterials, Projecttransportation, Proponentand withconstruction whomor Isometricother has a Validated Protocol after an Orderprocesses for Verification and Certificate Issuance services from a Buyer and once a Verified Removalgoods or Reduction has taken place.A measure of how much energy the emissions of 1 tonne of a GHG will absorb over a given period of time, relative to the emissions of 1 ton of CO₂buildings.- The escape of CO₂ to the atmosphere after it has been stored, and after a Certificate has been Issued. A Reversal is classified as avoidable if a Project Proponent has influence or control over it and it likely could have been averted through application of reasonable risk mitigation measures. Any other Reversals will be classified as unavoidable.
RawReporting materialPeriod- A
whichcollection is used for CO₂of Removal or GHGReduction Reductionprocesses that have mechanisms in common. AnA analysismeasure of how much energy the balanceemissions of positive1 andtonne negativeof a GHG will absorb over a given period of time, relative to the emissions associated with a certain process, which includes all of the1 flowston of CO₂ and other GHGs, along with other environmental or social impacts of concern.
11.0 Appendix 1: Monitoring Plan Requirements
This appendix details how the Project Proponent must monitor, document and report all metrics identified within this Protocol. Following this guidance will ensure the Project Proponent measures and confirms carbon removed and long-term storage compliance, and will enable quantification of the emissions removal resulting from the Project activity during The Project Crediting Period, prior to each verification.
This methodology utilizes a comprehensive monitoring and documentation framework that captures the GHG impact in each stage of a Project. Monitoring and detailed accounting practices must be conducted throughout to ensure the continuous integrity of Crediting.
The Project Proponent must develop and apply a monitoring plan according to ISO 14064-2 principles of transparency and accuracy that allows the quantification and evidencing of GHG emissions and CO2 removals.
11.1 Storage Module Requirements
The conversion and durable storage modules associated with this Protocol have their own set of required parameters that need to be monitored. Please refer to the following requirements Sections of the relevant Modules to see a complete list of all requirements:
[Module: saline-aquifer-storage v1.1]See Section 6 for monitoring requirements for storage in saline aquifers.
[Module: depleted-hydrocarbon-reservoirs v1.0]See Section 6 for monitoring requirements for storage in depleted hydrocarbon reservoirs.
[Module: in-situ-mineralization v1.1]See Section 7 for monitoring requirements for storage in mafic and ultramafic formations.
[Module: ex-situ-mineralization-in-closed-engineered-systems v1.1]See Section 9 for monitoring requirements for conversion via ex-situ mineralization in closed engineered systems.
[Module: built-materials-storage v1.0]See Section 6 for monitoring requirements for storage via carbonation in the built environment.
[Module: enhanced-weathering-closed-engineered-systems v1.0]See Section 11 for monitoring requirements for conversion via enhanced weathering in closed engineered systems.
11.2 Net CDR Calculation Requirements
These parameters must be monitored for the purpose of Carbon Emissions Calculation and Embodied Carbon Emissions Calculation.
Parameter
| Parameter Description
| Required
| Equation
| Parameter Type
| Units
| Data Source
| Measurement Method
| Monitoring Frequency
| QA/QC Procedures
| Required Evidence
| Reference
|
|---|
[math: kwh_{L}]
| Electricity usage for DAC process
| Always
| Eq. 4 (Energy Use Accounting Module)
| Measured
| kwh
| Electricity usage records
| Electricity meters ORIndependent power meter readings for metering equipment
| Each Reporting Period
| Appropriate calibration and maintenance of meters
| Operator logs, plant data systems, or plant records
| 7.4.3.1 (Direct Air Capture); 3.2.2.2 (Energy Use Accounting Module)
|
[math: m_{p}]
| Derating factor
| Always
| Eq. 4 (Energy Use Accounting Module)
| Measured or estimated
| N/A
| Electricity power output
| Averaged metered A/C power output per hour, OR estimated
| If measured, continuous for a Reporting Period
| Appropriate calibration and maintenance of meters
| Operator logs, plant data systems, or plant records
| 7.4.3.1 (Direct Air Capture); 3.2.2.2 (Energy Use Accounting Module)
|
[math: EF_{G}]
| Hourly short-run marginal emissions rate of the facility's local electricity grid
| Always, unless all electricity is qualified
| Eq. 4 (Energy Use Accounting Module)
| Estimated
| CO2e/unit (tonnes)
| Short run marginal emissions data
| N/A
| Hourly
| N/A
| Choice and rationale for EF choice
| 7.4.3.1 (Direct Air Capture); 3.2.2.2 (Energy Use Accounting Module)
|
[math: EF_{P}]
| Hourly average electricity emission factor for a specific generator
| Always
| Eq. 4 (Energy Use Accounting Module)
| Estimated
| CO2e/unit (tonnes)
| Argonne National Laboratory GREET Model, California Air Resources Board modified GREET model (CA-GREET), Ecoinvent database, US Federal Life Cycle Inventory database or LCA Commons, or from similar databases used in common LCA practices or tools
| N/A
| Hourly
| N/A
| Choice and rationale for EF choice
| 7.4.3.1 (Direct Air Capture); 3.2.2.2 (Energy Use Accounting Module)
|
[math: m_{Fuel,\ DAC}]
| Mass of fuel used in DAC process
| Always
| Eq. 5 (Energy Use Accounting Module)
| Measured
| gal
| Fuel usage records
| Fuel meters, Fuel container weight,Fuel purchases or utility billsEquipment hours of operation (handling equipment only)
| Each Reporting Period
| Appropriate calibration and maintenance of scales or meters
| Operator logs, plant data systems, or plant records
| 7.4.3.1 (Direct Air Capture); 3.3 (Energy Use Accounting Module)
|
[math: EF_{Fuel, DAC}]
| Fuel emission factor for the DAC process
| Always
| Eq. 5 (Energy Use Accounting Module)
| Estimated
| CO2e/unit (tonnes)
| Argonne National Laboratory GREET Model, California Air Resources Board modified GREET model (CA-GREET), Ecoinvent database, US Federal Life Cycle Inventory database or LCA Commons, or from similar databases used in common LCA practices or tools
| N/A
| Each Reporting Period
| N/A
| Choice and rationale for EF choice
| 7.4.3.1 (Direct Air Capture); 3.3 (Energy Use Accounting Module)
|
[math: m_{Fuel,\ Postprocessing}]
| Mass of fuel used in postprocessing
| Always
| Eq. 5 (Energy Use Accounting Module)
| Measured
| gal
| Fuel usage records
| Fuel meters, Fuel container weight,Fuel purchases or utility billsEquipment hours of operation (handling equipment only)
| Each Reporting Period
| Appropriate calibration and maintenance of scales or meters
| Operator logs, plant data systems, or plant records
| 7.4.3.1 (Direct Air Capture); 3.3 (Energy Use Accounting Module)
|
[math: EF_{Fuel, Postprocessing}]
| Fuel emission factor for postprocessing
| Always
| Eq. 5 (Energy Use Accounting Module)
| Estimated
| CO2e/unit (tonnes)
| Argonne National Laboratory GREET Model, California Air Resources Board modified GREET model (CA-GREET), Ecoinvent database, US Federal Life Cycle Inventory database or LCA Commons, or from similar databases used in common LCA practices or tools
| N/A
| Each Reporting Period
| N/A
| Choice and rationale for EF choice
| 7.4.3.1 (Direct Air Capture); 3.3 (Energy Use Accounting Module)
|
[math: m_{Fuel,\ Conversion}]
| Mass of fuel used in injectate conversion process & non-mobile transportation
| Always
| Eq. 5 (Energy Use Accounting Module)
| Measured
| gal
| Fuel usage records
| Fuel meters, Fuel container weight,Fuel purchases or utility billsEquipment hours of operation (handling equipment only)
| Each Reporting Period
| Appropriate calibration and maintenance of scales or meters
| Operator logs, plant data systems, or plant records
| 7.4.3.1 (Direct Air Capture); 3.3 (Energy Use Accounting Module)
|
[math: EF_{Fuel, Conversion}]
| Fuel emission factor for injectate conversion process & non-mobile transportation
| Always
| Eq. 5 (Energy Use Accounting Module)
| Estimated
| CO2e/unit (tonnes)
| Argonne National Laboratory GREET Model, California Air Resources Board modified GREET model (CA-GREET), Ecoinvent database, US Federal Life Cycle Inventory database or LCA Commons, or from similar databases used in common LCA practices or tools
| N/A
| Each Reporting Period
| N/A
| Choice and rationale for EF choice
| 7.4.3.1 (Direct Air Capture); 3.3 (Energy Use Accounting Module)
|
[math: F_{Transportation}]
| Quantity of fuel used in mobile transportation
| Under certain conditions
| Eq. 2 (Transportation Emissions Accounting Module)
| Measured or estimated
| gal
| Vehicle or fleet management records
| Fuel flow meters, fleet management system data, vehicle on board diagnostics, or similar
| Each Reporting Period
| Verify instrument calibrations as appropriate
| Meter, management system, OBD or other data records or logs, shipping documents
| 7.4.3.2 (Direct Air Capture); 3.2 (Transportation Emissions Accounting Module)
|
[math: EF_{Fuel, Transportation}]
| Fuel emission factor for mobile transportation
| Under certain conditions
| Eq. 2 (Transportation Emissions Accounting Module)
| Estimated
| CO2e/unit (tonnes)
| Argonne National Laboratory GREET Model, California Air Resources Board modified GREET model (CA-GREET), Ecoinvent database, US Federal Life Cycle Inventory database or LCA Commons, or from similar databases used in common LCA practices or tools
| N/A
| Each Reporting Period
| N/A
| Choice and rationale for EF choice
| 7.4.3.2 (Direct Air Capture); 3.2 (Transportation Emissions Accounting Module)
|
[math: D_{Transportation}]
| Transportation distance traveled (mobile transportation)
| Under certain conditions
| Eq. 2 (Transportation Emissions Accounting Module)
| Measured or estimated
| mi or km
| Shipping records (bill of lading) ORFleet management records ORWeighscale tickets
| On-line mapping systems using origin and departure from shipping documents, odometer readings
| Each Reporting Period
| Review and check of shipping records and origin/destination
| Shipping records
| 7.4.3.2 (Direct Air Capture); 3.2 (Transportation Emissions Accounting Module)
|
[math: W_{Transportation}]
| Mass transported (mobile transportation)
| Under certain conditions
| Eq. 2 (Transportation Emissions Accounting Module)
| Measured
| kg, tonne, lb
| Shipping records (bill of lading) ORFleet management records ORWeighscale tickets
| Calibrated weigh scale
| Each Reporting Period
| Review weigh scale calibration certificate
| Shipping records, weigh scale ticket
| 7.4.3.2 (Direct Air Capture); 3.2 (Transportation Emissions Accounting Module)
|
[math: EF_{Transportation, j}]
| The weight- and distance-based emission factor for mobile transportation
| Under certain conditions
| Eq. 2 (Transportation Emissions Accounting Module)
| Estimated
| CO2e/unit (tonnes)
| Argonne National Laboratory GREET Model, California Air Resources Board modified GREET model (CA-GREET), Ecoinvent database, US Federal Life Cycle Inventory database or LCA Commons, or from similar databases used in common LCA practices or tools
| N/A
| Each Reporting Period
| N/A
| Choice and rationale for EF choice
| 7.4.3.2 (Direct Air Capture); 3.3 (Transportation Emissions Accounting Module)
|
[math: m_{em,\ t}]
| the mass of miscellaneous emission(s) (in tonnes) during [math: t]
| Under certain conditions
| Eq. 3 (Direct Air Capture)
| Measured
| kg
| Direct mass measurement or analytical determination
| Calibrated mass flow meter or volumetric flow meter and density measurements over a defined time interval ΔtUse of flow data and curves from tail gas emissions testing and pressure drop measurement in the tail gas streamcalculation of tail gas amount by a carbon material balance calculated based on direct measurement of other process streamsmeasurement of a storage vessel pressure and temperature at beginning and end of a defined periodweight of a storage vessel as determined by calibrated weigh scale or load sensor at the beginning and end of a defined period
| Continuous if occurring
| Scales must be calibrated annually by certified entity
| Weigh scale tickets for each injection (arrival and departure weights); Calibration records for scales
| 7.4.3.4.1 (Direct Air Capture)
|
[math: C_{GHG,\ t}]
| the measured concentration as weight percent (%wt) of the relevant GHGs in the miscellaneous emission(s)
| Under certain conditions
| Eq. 3 (Direct Air Capture)
| Measured
| wt%
| Analytical determination
| Continuous inline analyzer for CO₂ or GHG concentration such as NDIR, TDL, or equivalent.Use of concentration data from process stream tail gas emission testing
| Continuous if occurring
| Appropriate calibration and maintenance of sensors or ISO 10694 accredited laboratory
| Data logs/Data Acquisition System Output or Analytical reports from qualified laboratory for audited samples, including supporting lab QA/QC results
| 7.4.3.4.1 (Direct Air Capture)
|
Product Stage Emissions
| Includes raw material sourcing, transport to facility and manufacturing
| Always
| | Measured
| tonnes
| Independently verified LCAs for the material or product completed; an environmental product declaration (EPD) for a material or product completed and independently verified
| Number/weight of each product or material used in the project facility and a corresponding EPD-based embodied carbon emission factor, OR emission factors from LCA life cycle databases, including USLCI database, Ecoinvent, ICE Database, and other published and peer-reviewed databases of embodied emissions factors and the number or weight (depending on emission factor units) of each product or material at the facility, OR overall total cost of equipment and facilities for The Project and cost based embodied emission factors
| Each site
| ISO 14040 or similar guidelines; ISO 14025, ISO 21930, EN 15804 or equivalent standards including product EPDs as well as industry-wide EPDs
| Operator logs, plant data systems, or plant records
| 7.4.3.3 (Direct Air Capture); 3.0 & 3.2 (Embodied Emissions Accounting Module)
|
Construction Stage Emissions
| Includes transport to site and installation at site
| Always
| | Measured
| tonnes
| Independently verified LCAs for the material or product completed; or an environmental product declaration (EPD) for a material or product completed and independently verified
| Number/weight of each product or material used in the project facility and a corresponding EPD-based embodied carbon emission factor, OR emission factors from LCA life cycle databases, including USLCI database, Ecoinvent, ICE Database, and other published and peer-reviewed databases of embodied emissions factors and the number or weight (depending on emission factor units) of each product or material at the facility, OR overall total cost of equipment and facilities for The Project and cost based embodied emission factors
| Each site
| ISO 14040 or similar guidelines; ISO 14025, ISO 21930, EN 15804 or equivalent standards including product EPDs as well as industry-wide EPDs
| Operator logs, plant data systems, or plant records
| 7.4.3.3 (Direct Air Capture); 3.0 & 3.2 (Embodied Emissions Accounting Module)
|
End of Life Stage Emissions
| Includes demolition of building, transport to end of life, waste processing and final disposal or scenarios for these life cycle stages
| Always
| | Measured
| tonnes
| Independently verified LCAs for the material or product completed; an environmental product declaration (EPD) for a material or product completed and independently verified
| Number/weight of each product or material used in the project facility and a corresponding EPD-based embodied carbon emission factor, OR emission factors from LCA life cycle databases, including USLCI database, Ecoinvent, ICE Database, and other published and peer-reviewed databases of embodied emissions factors and the number or weight (depending on emission factor units) of each product or material at the facility, OR overall total cost of equipment and facilities for The Project and cost based embodied emission factors
| Each site
| ISO 14040 or similar guidelines; ISO 14025, ISO 21930, EN 15804 or equivalent standards including product EPDs as well as industry-wide EPDs
| Operator logs, plant data systems, or plant records
| 7.4.3.3 (Direct Air Capture); 3.0 & 3.2 (Embodied Emissions Accounting Module)
|
Storage and Monitoring Emissions
| The total quantity of GHG emissions associated with storage monitoring operations allocated to a removal
| Always
| | Measured
| tonnes
| Electricity and fuel usage records; independently verified LCAs for the material or product completed; an environmental product declaration (EPD) for a material or product completed and independently verified
| Electricity meters OR utility bills OR equipment time of use and power rating; fuel meters fuel container weight fuel purchases or utility bills equipment hours of operation (handling equipment only)
| Each site
| Appropriate calibration and maintenance of scales or meters
| Operator logs, plant data systems, or plant records
| 7.4.3.3 (Direct Air Capture); 3.4 of applicable Storage Modules
|
12.0 Appendix 21: Risk of Reversal Questionnaire
This risk assessment identifies the pathway specific risk factors relevant to a carbon removal project. The relevant risk factors identified as part of a risk assessment are included in the monitoring plan requirements for the project, with details included in the Project Design Document. Project specific risk factors inform the required duration of monitoring along with the monitoring requirements set out in the Protocol and the requirements set out in the Monitoring Section of the Isometric Standard.
Projects using this Protocol have the option of a number of storage modules. The typical buffer pool contributions and the rationale are indicated in the relevant storage module: typically, geologic storage is considered Very Low Risk Level (leading to a 1% buffer pool).
If Reversals are not directly observable (i.e., all storage is as carbonated materials in the built environment and/or DIC in an open system), the Project's Risk of Reversal is automatically "No observable risk." Such Projects do not need to complete this questionnaire, but must still maintain a monitoring plan in accordance with the requirements of the relevant Protocol. Please note storage as carbonated materials in the built environment also requires a Project-specific calculation of reversal risk and uncertainty discount.
The risk score, as determined by the Risk of Reversal Questionnaire, will determine a project’s buffer pool contribution. Projects must re-assess their reversal risk at the renewal of each creditingCrediting periodPeriod, or if monitoring identifies a reversal-related risk, or if an actual reversal event takes place. In any event, projects should reassess their reversal risk at a minimum every 5 years.
The Risk of Reversal Questionnaire questions that pertain to this protocol, drawn from the programme-level Risk of Reversal Questionnaire defined in Appendix B: Risk Reversal Questionnaire of the Isometric Standard, include the following:
#No. in Isometric Standard Questionnaire
| Question | If answered “Yes” | If answered “No” |
|---|
1 | Is a reversal directly observable with a physical or chemical measurement as opposed to a modeled result? | Proceed to questions 2-910 | Proceed to questions 8-910 |
2 | Is the carbon being stored in an impermeable geologic system? (e.g., salt cavern) | Proceed to questions 8-910 | Add 1 to Risk Score and proceed to questions 3-910 |
5 | Does this approach have a material risk of reversal due to natural disasters including, but not limited to, floods, storms, earthquakes, fires, etc.? | Add 1 to Risk Score | |
6 | Does this approach have a material risk of reversal due to human-induced events from outside actors, such as change in farming practices, change in ownership and management of project sites, or similar? | Add up to 2 to Risk Score | |
7 | Applicable only for subsurface storage:: Is the carbon being stored with trapping mechanisms preventing reversals? (e.g., multiple confining layers, CO₂ dissolves or solidifies) | Minus 1 to Risk Score (unless 0) | |
8 | Is there 10+ years of monitoring and/or lab data demonstrating low project risk? | Minus up to 2 to Risk Score | |
9 | Does this pathway have a documented history of reversals in excess of proposed buffer pool size? | Add 2 to Risk Score | |
10 | Is there one or more project-specific factors that merit a high risk level? | Add up to 2 to Risk Score | |
Note the Risk Score at any step cannot be negative.
Risk Score Categories:
- 0: Very Low Risk Level (
21% buffer) - 1-2: Low Risk Level (5% buffer)
- 3-4: Medium Risk Level (7% buffer)
- 5+: High Risk Level (10-20% buffer)
Project specific risk factors will depend on the form of carbon being stored (i.e., organic vs. inorganic), the method of storage (e.g., mineralization, encapsulation), the location of carbon storage (e.g., subsurface, ocean), and the proximity of that carbon to potential agents of reversal.
For projects with carbon storage as inorganic carbon, the presence of the following risk factors must be reflected in the risk score corresponding to question 10:
- Acidic fluid
- Alkaline fluid (if stored as dissolved inorganic carbon)
- Temperatures in excess of 800 degrees celsius
For projects with any form of subsurface carbon storage, the presence of the following risk factors must be reflected in the risk score corresponding to question 10:
- Seismicity
- Subsurface migration
13.0 Relevant Works
California Air Resources Board. (2022). Carbon Sequestration: Carbon Capture, Removal, Utilization, and Storage. https://ww2.arb.ca.gov/our-work/programs/carbon-sequestration-carbon-capture-removal-utilization-and-storage
Environment and Climate Change Canada. Clean Fuel Regulations: Quantification Method for CO2 Capture and Permanent Storage Version 1.0. (2022) https://publications.gc.ca/collections/collection_2022/eccc/En4-474-2022-eng.pdf
Intergovernmental Panel on Climate Change. (2005). IPCC Special Report on Carbon Dioxide Capture and Storagehttps://www.ipcc.ch/site/assets/uploads/2018/03/srccs_wholereport-1.pdf
International Organization for Standardization. (2008). Evaluation of measurement data — Guide to the expression of uncertainty in measurement (ISO JGCM GUM). https://www.iso.org/sites/JCGM/GUM/JCGM100/C045315e-html/C045315e.html?csnumber=50461
International Organization for Standardization. (2006). ISO 14040:2006 Environmental management — Life cycle assessment — Principles and framework. https://www.iso.org/standard/37456.html
International Organization for Standardization. (2006). ISO 14044:2006 Environmental management — Life cycle assessment — Requirements and guidelines. https://www.iso.org/standard/38498.html
International Organization for Standardization. (2011). ISO 14066:2011 Greenhouse gases — Competence requirements for greenhouse gas validation teams and verification teams. https://www.iso.org/standard/43277.html
International Organization for Standardization. (2017). ISO/IEC 17025:2017 General requirements for the competence of testing and calibration laboratories. https://www.iso.org/standard/66912.html
International Organization for Standardization. (2019). ISO 14064-2:2019. Greenhouse Gases - Part 2: Specification With Guidance At The Project Level For Quantification, Monitoring And Reporting Of Greenhouse Gas Emission
s Or Removal Enhancements. ISO. https://www.iso.org/standard/66454.html
International Organization for Standardization. (2019). ISO 14064-3:2019. Greenhouse gases — Part 3: Specification with guidance for the verification and validation of greenhouse gas statements. ISO. https://www.iso.org/standard/66455.html
International Organization for Standardization. (2022). ISO 9300:2022 Measurement of gas flow by means of critical flow nozzles. https://www.iso.org/standard/77401.html
Matthews, J.B.R. (Ed.). (2018). IPCC, 2018: Annex I: Glossary [Matthews, J.B.R. (ed.)]. In: Global Warming of 1.5°C. An IPCC Special Report on the impacts of global warming of 1.5°C above pre-industrial levels and related global greenhouse gas emission pathways, in the context of... Cambridge University Press. https://doi.org/10.1017/9781009157940.008
Carbon Credit Quality Initiative (CCQI) Methodology for assessing the quality of carbon credits, Version 3.0. (2022, May). https://carboncreditquality.org/methodology.html
NIST (2015, April 20). Overview of ASTM D7036: A Quality Management Standard for Emission Testing. https://www.nist.gov/system/files/documents/2017/10/31/overview-astm-d7036.pdf
NIST Handbook 44 (2025). Specifications, Tolerances, and Other Technical Requirements for Weighing and Measuring Devices - 2025 Edition. NIST. https://www.nist.gov/pml/owm/publications/nist-handbooks/handbook-44-current-edition
US Department of Energy (DoE) (2022) Best Practices for Life Cycle Assessment (LCA) of Direct Air Capture with Storage (DACS). https://www.energy.gov/sites/default/files/2022-06/FECM%20DACS%20LCA%20Best%20Practices.pdf
U.S. Environmental Protection Agency. (2023, April 18). Understanding Global Warming Potentials | US EPA. Environmental Protection Agency. Retrieved June 14, 2023, from https://www.epa.gov/ghgemissions/understanding-global-warming-potentials
U.S. DoE. (2022). Best Practices for Life Cycle Assessment (LCA) of Direct Air Capture with Storage (DACS). U.S. Department of Energy, Office of Fossil Energy and Carbon Management. https://www.energy.gov/fecm/best-practices-LCA-DACS
California Air Resources Board (2018). CCS protocol under the Low Carbon Fuel Standard (LCFS). https://ww2.arb.ca.gov/sites/default/files/2020-03/CCS_Protocol_Under_LCFS_8-13-18_ada.pdf
Terlouw, T., Bauer, C., Rosa, L., and Mazzotti, M. (2021). Life cycle assessment of carbon dioxide removal technologies: a critical review. Energy & Environmental Science, 14, 1701–1721. https://doi.org/10.1039/D0EE03757E