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Biochar Production and Storage

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1213.0 Acknowledgements

Isometric would like to thank the following contributorsexternal toreviewers of this Protocol:

Isometric would like to thank following contributors to this Protocol/Module:

1314.0 Definitions and Acronyms

A document that describes how to quantitatively assess the net amount of CO₂ removed by a process. To Isometric, a Protocol is specific to a Project Proponent's process and comprised of Modules representing the Carbon Fluxes involved in the CDR process. A Protocol measures the full carbon impact of a process against the Baseline of it not occurring.
The amount of CO₂ emissions that would cause the same integrated radiative forcing or temperature change, over a given time horizon, as an emitted amount of GHG or a mixture of GHGs. One common metric of CO₂e is the 100-year Global Warming Potential.
The term used to represent the CO₂ taken out of the atmosphere as a result of a CDR process.
Describes the addition of carbon dioxide removed from the atmosphere to a reservoir, which serves as its ultimate destination. This is also referred to as “sequestration”.
Raw material which is used for CO₂ Removal or GHG Reduction.
The amount of time carbon removed from the atmosphere by an intervention – for example, a CDR project – is expected to reside in a given Reservoir, taking into account both physical risks and socioeconomic constructs (such as contracts) to protect the Reservoir in question.
Purposefully erring on the side of caution under conditions of Uncertainty by choosing input parameter values that will result in a lower net CO₂ Removal or GHG Reduction than if using the median input values. This is done to increase the likelihood that a given Removal or Reduction calculation is an underestimation rather than an overestimation.
A publicly visible uniquely identifiable Credit Certificate Issued by a Registry that gives the owner of the Credit the right to account for one net metric tonne of Verified CO₂e Removal or Reduction. In the case of this Standard, the net tonne of CO₂e Removal or Reduction comes from a Project Validated against a Certified Protocol.
A measurement which correlates with but is not a direct measurement of the variable of interest.
Independent components of Isometric Certified Protocols which are transferable between and applicable to different Protocols.
​​Considering impacts at each stage of a product's life cycle, from the time natural resources are extracted from the ground and processed through each subsequent stage of manufacturing, transportation, product use, and ultimately, disposal.
Those gaseous constituents of the atmosphere, both natural and anthropogenic (human-caused), that absorb and emit radiation at specific wavelengths within the spectrum of terrestrial radiation emitted by the Earth’s surface, by the atmosphere itself, and by clouds. This property causes the greenhouse effect, whereby heat is trapped in Earth’s atmosphere (CDR Primer, 2022).
The term used to describe greenhouse gas emissions to the atmosphere as a result of Project activities.
A worldwide federation (NGO) of national standards bodies from more than 160 countries, one from each member country.
An activity or process or group of activities or processes that alter the condition of a Baseline and leads to Removals or Reductions.
RawLowering material which is used for CO₂ Removal orfuture GHG Reductionreleases from a specific entity.
ActivitiesGHG that remove carbon dioxide (CO₂) from the atmosphere and store it in products or geologicalsources, terrestrial, and oceanic Reservoirs. CDR includes the enhancement of biological or geochemical sinks and direct air capturereservoirs (DACSSRs) and storage, but excludes natural CO₂ uptake not directly caused by human intervention.
The amount of time carbon removed from the atmosphere by an intervention – for example, a CDR project – is expected to reside in a given Reservoir, taking into account both physical risks and socioeconomic constructs (such as contracts) to protect the Reservoir in question.
A document submitted alongside Claimed Removals and/or Reductions that details the calculations associated with athe Removalproject orboundary Reduction,and includingincluded in the Project'sGHG emissions, Removals, Reductions and Leakages, presented together in net metric tonnes of CO₂e per Removal or ReductionStatement.
A process for evaluating and confirming the net Removals and Reductions for a Project, using data and information collected from the Project and assessing conformity with the criteria set forth in the Isometric Standard and the Protocol by which it is governed. Verification must be completed by an Isometric approved third-party (VVB).
A systematic and independent process for evaluating the reasonableness of the assumptions, limitations and methods that support a Project and assessing whether the Project conforms to the criteria set forth in the Isometric Standard and the Protocol by which the Project is governed. Validation must be completed by an Isometric approved third-party (VVB).
The Isometric process which involves expert review and Public Consultation in order to arrive at an approved version of a Protocol, against which Projects will be Validated and Removals or Reductions will be Verified.
Any process, activity, or mechanism that removes a greenhouse gas, a precursor to a greenhouse gas, or an aerosol from the atmosphere.
Activities that remove carbon dioxide (CO₂) from the atmosphere and store it in products or geological, terrestrial, and oceanic Reservoirs. CDR includes the enhancement of biological or geochemical sinks and direct air capture (DAC) and storage, but excludes natural CO₂ uptake not directly caused by human intervention.
A document submitted alongside Claimed Removals and/or Reductions that details the calculations associated with a Removal or Reduction, including the Project's emissions, Removals, Reductions and Leakages, presented together in net metric tonnes of CO₂e per Removal or Reduction.
Credits are issued to the Credit Account of a Project Proponent with whom Isometric has a Validated Protocol after an Order for Verification and Credit Issuance services from a Buyer and once a Verified Removal or Reduction has taken place.
Any person or entity who can potentially affect or be affected by Isometric or an individual Project activity.
The organization that develops and/or has overall legal ownership or control of a Removal or Reduction Project.
The steps of a Project Proponent’s Removal or Reduction process that result in carbon fluxes. The carbon flux associated with an activity is a component of the Project Proponent’s Protocol.
The document, written by a Project Proponent, which records key characteristics of a Project and which forms the basis for Project Validation and evaluation in accordance with the relevant Certified Protocol. (Also known as “PDD”).
The diversity of life across taxonomic and spatial scales. Biodiversity can be measured within species (i.e. genetic diversity and variations in allele frequencies across populations), between species (i.e. the total number and abundance of species within and across defined regions), within ecosystems (i.e. the variation in functional diversity, such as guilds, life-history traits, and food-webs), and between ecosystems (variation in the services of abiotic and biotic communities across large, landscape-level scales) that support ecoregions and biomes.
TheAny documentprocess or activity that clearly outlines howreleases a Projectgreenhouse willgas, generatean rigorously quantifiable Additional high-quality Removalsaerosol, or Reductionsa precursor of a greenhouse gas into the atmosphere.
A systematicUnited andStates independentGovernment process for evaluating the reasonableness of the assumptions, limitations and methodsagency that supportprotects ahuman Project and assessing whether the Project conforms to the criteria set forth in the Isometric Standardhealth and the Protocolenvironment.
A bycontract in which thea Buyer agrees to purchase a set Removal and/or Reduction at a set price.
The defined temporal and geographical boundary of a Project is governed. Validation must be completed by an Isometric approved third-party (VVB).
A calculation, series of calculations or simulations that use input variables in order to generate values for variables of interest that are not directly measured.
IndependentThird-party componentsauditing oforganizations that are experts in their sector and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric Certifiedprior Protocolsto whichconducting are transferable betweenvalidation and applicable to different Protocolsverification.
An acceptable difference between reported Removals/emissions or Reductions/emissions and what an auditor determines is the actual Removal/emissions or Reduction/emissions.
A lack of knowledge of the exact amount of CO₂ removed by a particular process, Uncertainty may be quantified using probability distributions, confidence intervals, or variance estimates.
Improperly allocating the same Removal or Reduction from a Project Proponent more than once to multiple Buyers.
An evaluation of the likelihood that an intervention—for example, a CDR Project—causes a climate benefit above and beyond what would have happened in a no-intervention Baseline scenario.
A set of data describing pre-intervention or control conditions to be used as a reference scenario for comparison.
An assessment of what would have happened in the absence of a particular intervention – i.e., assuming the Baseline scenario.
Resources provided to projects that are generating, or are expected to generate, greenhouse gas (GHG) Emission Reductions or Removals.
Products that have a significant market value and are planned for as part of production.
The period of time over which a Project Design Document is valid, and over which Removals or Reductions may be Verified, resulting in Issued Credits.
Reporting Period
An estimate of the emissions intensity per unit of an activity.
An analysis of how much different components in a Model contribute to the overall Uncertainty.
An entity that purchases Removals or Reductions, often with the purpose of Retiring Credits to make a Removal or Reduction claim.
A database that holds information on Verified Removals and Reductions based on Protocols. Registries Issue Credits, and track their ownership and Retirement.
Third-partySources, auditing organizations that are experts in their sectorSinks and used to determine if a project conforms to the rules, regulations, and standards set out by a governing body. A VVB must be approved by Isometric prior to conducting validation and verification.
Any process or activity that releases a greenhouse gas, an aerosol, or a precursor of a greenhouse gas into the atmosphere.
Any process, activity, or mechanism that removes a greenhouse gas, a precursor to a greenhouse gas, or an aerosol from the atmosphere.
A location where carbon is stored. This can be via physical barriers (such as geological formations) or through partitioning based on chemical or biological processes (such as mineralization or photosynthesis).Reservoirs
Emissions that are produced by a specific CDR process and are directly controllable.
Life cycle GHG emissions associated with production of materials, transportation, and construction or other processes for goods or buildings.
A product that is not an economic driver of the process it is produced in.
The multi-step process to monitor the Removals or Reductions and impacts of a Project, report the findings to an accredited third party, and have this third party Verify the report so that the results can be Certified.
The increase in GHG emissions outside the geographic or temporal boundary of a project that results from that project's activities.
A measure of how much energy the emissions of 1 tonne of a GHG will absorb over a given period of time, relative to the emissions of 1 ton of CO₂.
TheA increase in GHG emissions outside the geographic or temporal boundarycollection of a project that results from that project's activities.
Any emissions that occur to compensate for biomass that was previously serving another purpose and is now being used for carbon removal or GHG reduction. For example, if agricultural waste was previously left on a field to decompose - fertilizer production to replace those nutrients need to be accounted for.
The steps of a Project Proponent’s Removal or Reduction processprocesses that resulthave mechanisms in carbon fluxes. The carbon flux associated with an activity is a component of the Project Proponent’s Protocol.
A mixture of water, organic acids, aldehydes, ketones, sugars, phenols, and other organic compounds derived from the thermal breakdown of biomass. Thermal breakdown of biomass is achieved via thermochemical processes, such as pyrolysis, which heat biomass in low- or no-oxygen environments to high temperatures (~e.g. 350-650°C). Bio-oil is often also referred to as pyrolysis oil or bio-crude.
A source that would be widely considered trustworthy based on the process undertaken (e.g., peer review) or origin of the information (e.g., government body)common.
Issuance of Credits after removal or reduction took place. This is the manner in which Isometric Delivers Credits.
The escape of CO₂ to the atmosphere after it has been stored, and after a Credit has been Issued. A Reversal is classified as avoidable if a Project Proponent has influence or control over it and it likely could have been averted through application of reasonable risk mitigation measures. Any other Reversals will be classified as unavoidable.
A common and recognized insurance mechanism among Registries allowing Credits to be set aside (in this case by Isometric) to compensate for Reversals which may occur in the future.
for open systems, biogeochemical and/or physical interactions which occur during the removal process that decrease the CO₂ removal .
A standards organization that develops and publishes voluntary consensus international standards.
The term used to describe allocation of Project emissions to multiple Removals or Reductions.
An output of a process that has no intended value to the producer.
A composite material composed of aggregate, cement, sand and water that cures to a solid over time.

1415.0 Appendix A: Risk of Reversal Questionnaire

This risk assessment identifies the pathway specific risk factors relevant to a carbon removal project. The relevant risk factors identified as part of a risk assessment are included in the monitoring plan requirements for The Project, with details included in the PDD. Project specific risk factors inform the required duration of monitoring along with the monitoring requirements set out in the Protocol and the requirements set out in the Monitoring Section of the Isometric Standard.

The risk score, as determined by the Risk of Reversal Questionnaire, will determine a project’s buffer pool contribution. Projects must re-assess their reversal risk at the renewal of each crediting period, or if monitoring identifies a reversal-related risk, or if an actual reversal event takes place. In any event, projects should reassess their reversal risk at a minimum every 5 years.

The Risk of Reversal Questionnaire questions that pertain to this Protocol, drawn from the programme-level Risk of Reversal Questionnaire defined in Appendix B: Risk Reversal Questionnaire of the Isometric Standard, include the following:

# in Isometric Standard Questionnaire

Question

If answered “Yes”

If answered “No”

1

Is a reversal directly observable with a physical or chemical measurement as opposed to a modeled result?

Proceed to questions 2-9

Proceed to questions 8-9

2

Is the carbon being stored in an impermeable geologic system? (e.g., salt cavern)

Proceed to questions 8-9

Add 1 to Risk Score and proceed to questions 3-9

3

Is the carbon being stored organic?

Add 1 to Risk Score

5

Does this approach have a material risk of reversal due to natural disasters including, but not limited to, floods, storms, earthquakes, fires, etc.?

Add 1 to Risk Score

6

Does this approach have a material risk of reversal due to human-induced events from outside actors, such as change in farming practices, change in ownership and management of project sites, or similar?

Add up to 2 to Risk Score

8

Is there 10+ years of monitoring and/or lab data demonstrating low project risk?

Minus up to 2 to Risk Score

9

Does this pathway have a documented history of reversals?

Add 2 to Risk Score

10

Is there one or more project-specific factors that merit a high risk level?

Add up to 2 to Risk Score

Risk Score Categories

Project specific risk factors will depend on the form of carbon being stored (i.e., organic vs. inorganic), the method of storage (e.g., mineralization, encapsulation), the location of carbon storage (e.g., subsurface, ocean), and the proximity of that carbon to potential agents of reversal.

For projects with carbon storage as organic carbon, the presence of the following risk factors must be reflected in the risk score corresponding to question 10:

For projects with any form of subsurface carbon storage, the presence of the following risk factors must be reflected in the risk score corresponding to question 10:

16.0 Relevant Works

Footnotes

  1. Neves, E. G., Petersen, J. B., Bartone, R. N., & Heckenberger, M. J. (2004). The timing of Terra Preta formation in the central Amazon: Archaeological data from three sites. In B. Glaser & W. I. Woods (Eds.), Amazonian dark earths: Explorations in space and time (pp. [page range]). Springer. https://doi.org/10.1007/978-3-662-05683-7_9

  2. Wiedner, K., Schneeweiß, J., Dippold, M. A., & Glaser, B. (2015). Anthropogenic dark earth in northern Germany—The Nordic analogue to terra preta de Índio in Amazonia. CATENA, 132, 114-125. https://doi.org/10.1016/j.catena.2014.10.024

  3. Downie, A. E., Van Zwieten, L., Smernik, R. J., Morris, S., & Munroe, P. R. (2011). Terra Preta Australis: Reassessing the carbon storage capacity of temperate soils. Agriculture, Ecosystems & Environment, 140(1-2), 137-147. https://doi.org/10.1016/j.agee.2010.11.020

  4. Solomon, D., Lehmann, J., Fraser, J. A., Leach, M., Amanor, K., Frausin, V., Kristiansen, S. M., Millimouno, D., & Fairhead, J. (2016). Indigenous African soil enrichment as a climate-smart sustainable agriculture alternative. Frontiers in Ecology and the Environment, 14(2), 71-76. https://doi.org/10.1002/fee.1226

  5. Singh, N., Abiven, S., Torn, M. S., & Schmidt, M. W. I. (2012). Fire-derived organic carbon in soil turns over on a centennial scale. Biogeosciences, 9, 2847-2857. https://doi.org/10.5194/bg-9-2847-2012

  6. Reisser, M., Purves, R. S., Schmidt, M. W. I., & Abiven, S. (2016). Pyrogenic carbon in soils: A literature-based inventory and a global estimation of its content in soil organic carbon and stocks. Frontiers in Earth Science, 4, 80. https://doi.org/10.3389/feart.2016.00080

  7. Schiedung, M., Ascough, P., Bellè, S.-L., Bird, M. I., Bröder, L., Haghipour, N., Hilton, R. G., Lattaud, J., & Abiven, S. (2024). Millennial-aged pyrogenic carbon in high-latitude mineral soils. Communications Earth & Environment, 5, 177. https://doi.org/10.1038/s43247-024-01343-5

  8. Zhang, X., Yang, X., Yuan, X., Cao, Y., Zhang, B., Cao, Y., & Chen, Y. (2022). Effect of pyrolysis temperature on composition, carbon fraction and abiotic stability of straw biochars: Correlation and quantitative analysis. Carbon Research, 1, 17. https://doi.org/10.1007/s44246-022-00017-1

  9. Howell, A., Helmkamp, S., & Belmont, E. (2022). Stable polycyclic aromatic carbon (SPAC) formation in wildfire chars and engineered biochars. Science of The Total Environment, 849, 157610. https://doi.org/10.1016/j.scitotenv.2022.157610

  10. Yao, C., Wang, B., Zhang, J., Faheem, M., Feng, Q., Hassan, M., ... & Wang, S. (2024). Formation mechanisms and degradation methods of polycyclic aromatic hydrocarbons in biochar: A review. Journal of Environmental Management, 357, 120610. 23

  11. Wang, J., Xia, K., Waigi, M. G., Gao, Y., Odinga, E. S., Ling, W., & Liu, J. (2018). Application of biochar to soils may result in plant contamination and human cancer risk due to exposure of polycyclic aromatic hydrocarbons. Environment International, 121, 169-177.

  12. Human health effects of polycyclic aromatic hydrocarbons as ambient air pollutants: report of the Working Group on Polycyclic Aromatic Hydrocarbons of the Joint Task Force on the Health Aspects of Air Pollution. Copenhagen: WHO Regional Office for Europe; 2021. Licence: CC BY-NC-SA 3.0 IGO.

  13. Schneider, L., Schallert, B., & Kizzier, K. (2022). Methodology for assessing the quality of carbon credits (Version 3.0). Carbon Credit Quality Initiative. https://carboncreditquality.org/download/Methodology/CCQI Methodology %20Methodology%20- Version 3%20Version%203.0.pdf ↩︎ ↩︎

  14. LifeBritish cycleStandards modulesInstitution. as described in BS EN 15978:(2011). Sustainability of construction works — Assessment of environmental performance of buildings — Calculation method (BS EN 15978:2011). BSI. 234567

  15. NIST. (2023). Specifications, Tolerances, and Other Technical Requirements for Weighing and Measuring Devices - 2023 Edition. NIST. https://www.nist.gov/pml/owm/publications/nist-handbooks/handbook-44-current-edition

  16. Chatterjee, R., Sajjadi, B., Chen, W. Y., Mattern, D. L., Hammer, N., Raman, V., & Dorris, A. (2020). Effect of pyrolysis temperature on physicochemical properties and acoustic-based amination of biochar for efficient CO2 adsorption. Frontiers in Energy Research, 8, 85.